Petrology and U-Pb Zircon Geochronology of Amphibole-rich Cumulates with Sanukitic Affinity from Husky Ridge (Northern Victoria Land, Antarctica): Insights into the Role of Amphibole in the Petrogenesis of Subduction-related Magmas

A microanalytical trace element and geochronological study wascarried out on mafic amphibole-rich cumulates (quartz diorites)cropping out in northern Victoria Land (Antarctica). Associatedtonalites and basement rocks were also investigated. Rock texturesand major and trace element mineral compositions reveal thepresence in quartz diorites of two mineral assemblages: (1)clinopyroxene-I + brown amphibole ± dark mica; (2) clinopyroxene-II+ green amphibole + plagioclase + quartz. Both mineral assemblagescontain mafic phases with elevated Mg-number, but their traceelement signatures differ significantly. In situ U–Pbzircon geochronology was carried out to support petrogeneticand geological interpretations. Quartz diorites were emplacedin the mid-crust probably at 516 ± 3 Ma. Parental meltsof quartz diorites were computed by applying solid/liquid partitioncoefficients. The melt in equilibrium with the first mineralassemblage (melt-I) is extremely depleted in heavy rare earthelements (HREE), Y, Ti, Zr and Hf (at about 0·2 timesnormal mid-ocean ridge basalt) and enriched in B, Th, U, thelarge ion lithophile elements and light REE (LREE). It sharesmany similarities with sanukitic melts (e.g. Setouchi andesites),which originated by equilibration of subduction-derived sedimentmelts with a refractory mantle. The melt in equilibrium withthe second mineral assemblage (melt-II) is characterized bya steep LREE enrichment (La_N/Yb_N up to 39), a U-shaped HREEpattern and low Ti, which is depleted relative to HREE. Thetrace element signature of melt-II can be acquired through amphibolecrystallization starting from a sanukitic melt similar to melt-I,probably in a deeper magma chamber. Our results allow us toconstrain that melts from the subducted slab were produced ona regional scale, in accordance with literature data, belowa large sector of the east Gondwana margin during the mid-Cambrian.Implications for the role of amphibole in petrogenesis of subduction-relatedmagmas are also discussed. KEY WORDS: amphibole; sanukite; high-Mg andesites; Ross Orogeny; Antarctica     

Distrubution of Dissolved and Particulate Iron, copper and Manganese in the Shelf waters of the Ross sea (Antarctica)

Abstract. During the austral summer 1997–98, within the framework of the activities of the Climatic Long-term Interaction for the Massbalance in Antarctica (CLIMA) Project of the Italian National Program for Antarctic Research (PNRA) in the Ross Sea, measurements were conducted to focus on the role of dissolved iron, copper and manganese as micronutrients, and on their distribution in suspended particulate matter in different water masses. Sampling was carried out in two selected shelf areas, both important for formation and mixing processes of the water bodies.
Metal data were evaluated together with physical measurements and classical chemical parameters such as oxygen and nutrients.
In both the studied areas, the distribution of dissolved metals along the waste column confirmed their micronutrient behaviour, showing depletion where phytoplanktonic activities occurred.
The trend of particulate metals underlined the scavenging phenomena along the water column and presented an interesting correlation at intermediate depths with the amount and origin of suspended matter.     

Aptian to Coniacian (Early–Late Cretaceous) palynostratigraphy of the Gustav Group, James Ross Basin, Antarctica

The Gustav Group of the James Ross Basin, Antarctic Peninsula, forms part of a major Southern Hemisphere Cretaceous reference section. Palynological data, chiefly from dinoflagellate cysts, integrated with macrofaunal evidence and strontium isotope stratigraphy, indicate that the Gustav Group, which is approximately 2.6 km thick, is Aptian–Coniacian in age. Aptian–Coniacian palynofloras in the James Ross Basin closely resemble coeval associations from Australia and New Zealand, and Australian palynological zonation schemes are applicable to the Gustav Group. The lowermost units, the coeval Pedersen and Lagrelius Point formations, have both yielded early Aptian dinoflagellate cysts. Because the overlying Kotick Point Formation is of early to mid Albian age, the Aptian/Albian boundary is placed, questionably, at the Lagrelius Point Formation–Kotick Point Formation boundary on James Ross Island, and this transition may be unconformable. Although the Kotick Point Formation is largely early Albian on dinoflagellate cyst evidence, the uppermost part of the formation appears to be of mid Albian age. This differentiation of the early and mid Albian has refined the age of the formation, previously considered to be Aptian–Albian, based on macrofaunal evidence. The Whisky Bay Formation is of late Albian to latest Turonian age on dinoflagellate cyst evidence and this supports the macrofaunal ages. Late Albian palynofloras have been recorded from the Gin Cove, lower Tumbledown Cliffs, Bibby Point and the lower–middle Lewis Hill members. However, the Cenomanian age of the upper Tumbledown Cliffs and Rum Cove members, based on molluscan evidence, is not supported by the dinoflagellate cyst floras and further work is required on this succession. The uppermost part of the Whisky Bay Formation in north-west James Ross Island is of mid to late Turonian age and this is confirmed by strontium isotope stratigraphy. The uppermost unit, the Hidden Lake Formation, is Coniacian in age on both palaeontological and strontium isotope evidence. The uppermost part of the formation appears to be early Santonian based on dinoflagellate cysts, but strontium isotope stratigraphy constrains this as being no younger than late Coniacian. This refined palynostratigraphy greatly improves the potential of the James Ross Basin as a major Cretaceous Southern Hemisphere reference section.     

Slump-initiated and controlled syndepositional sandstone remobilization: an example from the Namurian of County Clare, Ireland

Remobilization of sandstones can dramatically reconfigure original depositional geometries and results in very unusually shaped sandstones, which resemble little, if any, of the original geometry. A number of deformational sandstone bodies, dykes and volcanoes from the upper part of the Carboniferous Ross Formation are described, which offer the opportunity to examine a suite of field-scale reconfigured sandstones. These structures are located in close proximity to the Ross Slide, which outcrops along a 2-km section on the northern coast of the Loop Head Peninsula, County Clare, Ireland. Dome- and ridge-shaped deformational sandstone bodies, dykes and volcanoes are interpreted to be the product of remobilization of a turbiditic sandstone. Liquification and remobilization were triggered by translation, cessation and loading of the underlying turbiditic sandstone by the Ross Slide. Deformational sand body, dyke and volcano development occurred in an asynchronous fashion with deformational sand bodies formed during slump translation. Sand dykes and volcanoes developed after the cessation of slump movement. During slump translation, the minimum principal stress (σ₃) was orientated vertically and the slump behaved in a `ductile' manner. After slump arrest, the minimum principal stress was oriented horizontally, and the unit regained shear strength to behave in a `brittle' manner. The relative change in rheological states with changing applied shear stress is indicative of thixotropic-like behaviour within the slump mass. Ridge-shaped deformational sand bodies are aligned parallel to slump folds, and their morphology is inferred to be controlled by compressional slump deformation associated with heterogeneous cessation of slump movement that was initiated by frontal arrest of the translating mass.     

冈瓦纳大陆边缘罗斯运动的岩浆活动时代:来自北维多利亚地松散沉积物锆石年龄的证据

横穿南极大陆中部的横贯南极山脉是早古生代时期古太平洋向东冈瓦纳活动大陆边缘俯冲形成的罗斯造山带,该阶段的地层沉积、变形变质以及花岗质岩浆侵入代表了罗斯运动的演化过程。由于岩浆活动与沉积地层和变形变质在时代上存在明显差异,罗斯运动的时代仍缺乏精确的限定。通过采集北维多利亚地难言岛地区冰碛物和海岸沉积物中的松散砂砾石样品,并进行碎屑锆石U-Pb测年得出:4件不同粒径的冰碛物和海岸沉积样品中的碎屑锆石年龄峰谱具有单一峰谱的特征,年龄区间为2443~323 Ma,主要集中于530~450 Ma之间,峰值年龄约为485 Ma;锆石Th/U比值均大于0.1,而且以＞0.4为主,其CL图像也具有明显的振荡环带,稀土元素特征主体具有岩浆锆石的特征,反映了样品物源区岩浆活动的时代特征。碎屑锆石年龄组成与周缘地区岩浆活动和陆内变形以及沉积地层时代基本一致,表明北维多利亚地及其周缘地区在罗斯运动晚期陆内变形阶段的岩浆活动应持续至450 Ma,这可能代表了罗斯运动结束的时代,该结果为冈瓦纳大陆边缘罗斯运动的构造演化过程提供了新的约束。      

Geometry and architectural associations of co-genetic debrite–turbidite beds in basin-margin strata, Carboniferous Ross Sandstone (Ireland): Applications to reservoirs located on the margins of structurally confined submarine fans

Co-genetic debrite–turbidite beds are most commonly found in distal basin-plain settings and basin margins. This study documents the geometry, architectural association and paleogeographic occurrence of co-genetic debrite–turbidite beds in the Carboniferous Ross Sandstone with the goal of reducing uncertainty in the interpretation of subsurface data in similarly shaped basins where oil and gas is produced.The Ross Sandstone of western Ireland was deposited in a structurally confined submarine basin. Two outcrops contain co-genetic debrite–turbidite beds: Ballybunnion and Inishcorker. Both of the exposures contain strata deposited on the margin of the basin. An integrated dataset was used to characterize the stratigraphy of the Ballybunnion exposure. The exposure is divided into lower, middle, and upper units. The lower unit contains laminated shale with phosphate nodules, structureless siltstone, convolute bedding/slumps, locally contorted shale, and siltstone turbidites. The middle unit contains co-genetic debrite–turbidite beds, siltstone turbidites, and structureless siltstone. Each co-genetic debrite–turbidite bed contains evidence that fluid turbulence and matrix strength operated alternately and possibly simultaneously during deposition by a single sediment-gravity-flow event. The upper unit contains thin-bedded sandy turbidites, amalgamated sandy turbidites, siltstone turbidites, structureless siltstone, and laminated shale. A similar vertical facies pattern is found at Inishcorker.Co-genetic debrite–turbidite beds are only found at the basin-margin. We interpret these distinct beds to have originated as sand-rich, fully turbulent flows that eroded muddy strata on the slope as well as interbedded sandstone and mudstone in axial positions of the basin floor forming channels and associated megaflute erosional surfaces. This erosion caused the axially dispersing flows to laterally evolve to silt- and clay-rich flows suspended by both fluid turbulence and matrix strength due to a relative increase in clay proportions and associated turbulence suppression. The flows were efficient enough to bypass the basin center/floor, physically disconnecting their deposits from coeval lobes, resulting in deposition of co-genetic debrite–turbidite beds on the basin margin. The record of these bypassing flows in axial positions of the basin is erosional surfaces draped by thin siltstone beds with organic debris.A detailed cross-section through the Ross Sandstone reveals a wedge of low net-to-gross, poor reservoir-quality strata that physically separates sandy, basin-floor strata from the basin margin. The wedge of strata is referred to as the transition zone. The transition zone is composed of co-genetic debrite–turbidite beds, structureless siltstone, slumps, locally contorted shale, and laminated shale. Using data from the Ross Sandstone, two equations are defined that predict the size and shape of the transition zone. The equations use three variables (thickness of basin-margin strata, thickness of coeval strata on the basin floor, and angle of the basin margin) to solve for width (w) and trajectory of the basinward side of the low net-to-gross wedge (β). Beta is not a time line, but a facies boundary that separates sandy basin floor strata from silty basin-margin strata. The transition zone is interpreted to exist on lateral and distal margins of the structurally confined basin.Seismic examples from Gulf of Mexico minibasins reveal a wedge of low continuity, low amplitude seismic facies adjacent to the basin margin. Strata in this wedge are interpreted as transition-zone sediments, similar to those in the Ross Sandstone. Besides defining the size and shape of the transition zone, the variables “w” and “β” define two important drilling parameters. The variable “w” corresponds to the minimum distance a well bore should be positioned from the lateral basin margin to intersect sandy strata, and “β” corresponds to the deviation (from horizontal) of the well bore to follow the interface between sandy and low net-to-gross strata. Calculations reveal that “w” and “β” are related to the relative amount of draping, condensed strata on the margin and the angle of the basin margin. Basins with shallowly dipping margins and relatively high proportions of draping, clay-rich strata have wider transition zones compared to basins with steeply dipping margins with little draping strata. These concepts can reduce uncertainty when interpreting subsurface data in other structurally confined basins including those in Gulf of Mexico, offshore West Africa, and Brunei.     

Long-term bottom water warming in the north Ross Sea

We measured potential temperature, salinity, and dissolved oxygen profiles from the surface to the bottom at two locations in the north Ross Sea (65.2°S, 174.2°E and 67.2°S, 172.7°W) in December 2004. Comparison of our data with previous results from the same region reveals an increase in potential temperature and decreases in salinity and dissolved oxygen concentration in the bottom layer (deeper than 3000 m) over the past four decades. The changes were significantly different from the analytical precisions. Detailed investigation of the temperature, salinity, dissolved oxygen and σ ₃ value distributions and the bottom water flow in the north Ross Sea suggests a long-term change in water mass mixing balance. That is to say, it is speculated that the influence of cool, saline, high-oxygen bottom water (high-salinity Ross Sea Bottom Water) formed in the southwestern Ross Sea has possibly been decreased, while the influences of relatively warmer and fresher bottom water (low-salinity Ross Sea Bottom Water) and the Adélie Land Bottom Water coming from the Australia-Antarctic Basin have increased. The possible impact of global warming on ocean circulation needs much more investigation.     

Geochemical and O-isotope constraints on the evolution of lithospheric mantle in the Ross Sea rift area (Antarctica)

Peridotite xenoliths found in Cenozoic alkali basalts of northern Victoria Land, Antarctica, vary from fertile spinel-lherzolite to harzburgite. They often contain glass-bearing pockets formed after primary pyroxenes and spinel. Few samples are composite and consist of depleted spinel lherzolite crosscut by amphibole veins and/or lherzolite in contact with poikilitic wehrlite. Peridotite xenoliths are characterized by negative Al₂O₃–Mg# and TiO₂–Mg# covariations of clino- and orthopyroxenes, low to intermediate HREE concentrations in clinopyroxene, negative Cr–Al trend in spinel, suggesting variable degrees of partial melting. Metasomatic overprint is evidenced by trace element enrichment in clinopyroxene and sporadic increase of Ti–Fe_tot. Preferential Nb, Zr, Sr enrichments in clinopyroxene associated with high Ti–Fe_tot contents constrain the metasomatic agent to be an alkaline basic melt. In composite xenoliths, clinopyroxene REE contents increase next to the veins suggesting metasomatic diffusion of incompatible element. Oxygen isotope data indicate disequilibrium conditions among clinopyroxene, olivine and orthopyroxene. The highest δ¹⁸O values are observed in minerals of the amphibole-bearing xenolith. The δ¹⁸O_cpx correlations with clinopyroxene modal abundance and geochemical parameters (e.g. Mg# and Cr#) suggest a possible influence of partial melting on oxygen isotope composition. Thermobarometric estimates define a geotherm of 80°C/GPa for the refractory lithosphere of NVL, in a pressure range between 1 and 2.5 GPa. Clinopyroxene microlites of melt pockets provide P–T data close to the anhydrous peridotite solidus and confirm that they originated from heating and decompression during transport in the host magma. All these geothermometric data constrain the mantle potential temperature to values of 1250–1350°C, consistent with the occurrence of mantle decompressional melting in a transtensive tectonic regime for the Ross Sea region.     

罗斯海海域大地水准面异常的成因研究

本文利用数值法求解瞬时地幔对流问题以模拟大地水准面异常.利用两个较新的S波速度异常层析模型SEMUCB_WM1和TX2019slab,将其转换为密度异常作为控制方程的浮力驱动项;采取的黏度结构模型中,上下地幔的黏度比为1∶50.为了研究地幔不同结构对罗斯海海域大地水准面异常的影响,分别提取上、下地幔的密度异常正/负值,作为对流控制方程的输入项,计算相应的模拟大地水准面异常.将模拟大地水准面异常与观测值进行对比,发现罗斯海海域的大地水准面异常主要来自下地幔及上地幔的负密度(波速)异常,下地幔正密度异常对该区域大地水准面负异常也有一定的贡献.本文认为,地幔密度负异常在罗斯海海域大地水准面异常的形成中占据主导作用,地幔对流的动力学效应对该区域大地水准面异常的形成影响较弱.     

1979—2015 年罗斯海海冰运动速度变化

基于美国冰雪数据中心的月平均海冰运动和海冰密集度数据, 建立了1979—2015 年罗斯海海冰运动 速度时间变化序列, 揭示了海冰运动速度的年际和季节变化特征, 探讨了海冰运动速度和海冰范围之间可 能存在的联系, 最后对影响海冰运动速度变化的因素进行了分析。结果表明, 1979—2015 年罗斯海海冰运动 速度总体呈现加快趋势, 海冰运动速度增加趋势最快的季节为秋季, 其次是冬季、春季和夏季。冬季海冰平 均运动速度最大, 依次是秋季、春季和夏季。海冰运动速度与海冰范围在37 年间均呈现上升趋势, 海冰范 围变化滞后海冰运动速度1—2 个月, 两者呈显著正相关关系, 海冰运动速度的增加导致罗斯海海冰范围不 断扩张, 进而影响南极整体海冰分布。罗斯海海冰运动速度与风速之间存在显著正相关关系, 风场是影响海 冰运动速度的一个直接因素。除此之外, 海冰运动还受到包括气压场、洋流场以及海洋阻力系数等的影响。