近2600年神农架大九湖泥炭的气候变化记录

神农架大九湖沼泽泥炭柱状样提供了分辨率为25a的约2600a来的气候变化记录。对样品进行了环境磁学参数测量、X射线荧光分析(XRF)、孢粉鉴定和统计建模，结果表明，大九湖气温的变化曲线与竺可桢中国东部的物候温度曲线以及格陵兰氧同位素变化曲线大体一致，与青藏高原东部希门错湖泊沉积物温度代用指标的变化曲线也十分相似。特别是550—1300AD间的相对温暖期，与竺可桢首次提出来的中国东部隋唐温暖期(约600-1000AD)和欧洲的中世纪暖期(930-1240AD)在时间跨度上大致对应。可划分为4个阶段：(1)600BC—550AD，气候相对冷湿；(2)550—1300AD，气候相对凉干；(3)1300—1900AD，气候又转变为冷湿，其中最冷期1400—1900AD可与欧洲的小冰期对应；(4)1900AD至今，气候又开始转向相对凉干。同时发现低频磁化率χlf与铁元素含量之比(χlf／Fe)的变化曲线与利用孢粉分析数据恢复的大九湖气候变化曲线对应得很好，特别是二者都清晰地显示了500—1300AD为一相对暖期。这预示着χlf／Fe可能是泥炭剖面的一个更好的气候记录代用指标。     

Behavioural Effects of Chemically Dispersed Oil and Subsequent Recovery in Diploria strigosa (Dana)

Abstract. Survival and behaviour of the hermatypic coral Diploria strigosa was studied during 6–24 h doses with water-accomodated fractions of chemically dispersed crude oil, and for a subsequent recovery period of 1 month. Experiments utilized a flow-through laboratory dosing procedure and incorporated petroleum hydrocarbon measurements in order to simulate a major but short-term oil spill in shallow subtidal benthic reef environments. Chemically dispersed oil treatments consisted of Arabian Light Crude oil with Corexit 9527 or BP1100WD at 1–20 ppm concentrations of oil.
In general, effects observed were sub-lethal, temporary, and associated with the highest concentrations tested. Responses to the presence of dispersed oil at 20ppm for 24 h included mesenterial filament extrusion, extreme tissue contraction, tentacle retraction and localized tissue rupture. The nature and severity of reactions during the dosing phase varied between colonies and treatments, but colonies typically resumed normal behaviour within 2 h to 4 d of the recovery period. It therefore seems unlikely that observed biological effects would impair long-term viability.     

GGR Critical Review of Analytical Developments in 2004–2005

In 2005 Geostandards and Geoanalytical Research embarked upon a new initiative for its readers. Key researchers in various fields of geoanalytical technique development and their application were identified and invited to provide reviews pertinent to their expertise. As noted in the first of these publications "…instead of revisiting the historical context or decades of development in each analytical technique, the goal here has been to capture a snapshot of "hot topics" across a range of fields as represented in the… literature" (Hergt et al . 2005). Rather than prepare an annual review, a decision was taken earlier this year to provide a biennial summary of progress and accomplishments, in this case for the years 2004–2005. The principal techniques employed in Earth and environmental sciences are covered here, and include laser ablation and multicollector ICP-MS, ICP-AES, thermal ionisation and secondary ion mass spectrometry, as well as neutron activation analysis, X-ray fluorescence and atomic absorption spectrometry. A comprehensive review of the development of reference materials, often essential to these techniques, is also provided. The contributions assembled serve both to keep readers informed of advances they may be unfamiliar with, but also as a means of showcasing examples of the breadth and depth of work being conducted in these fields.     

Combining two filter paper‐based analytical methods to monitor temporal variations in the geochemical properties of fluvial suspended particulate matter

Many of the commonly used analytical techniques for assessing the properties of fluvial suspended particulate matter (SPM) are neither cost effective nor time efficient, making them prohibitive to long‐term high‐resolution monitoring. We present an in‐depth methodology utilizing two types of spectroscopy which, when combined with automatic water samplers, can generate accurate, high‐temporal resolution SPM geochemistry data, inexpensively and semi‐destructively, directly from sediment covered filter papers. A combined X‐ray fluorescence spectroscopy and diffuse reflectance infrared Fourier transform spectroscopy approach is developed to estimate concentrations for a range of elements (Al, Ca, Ce, Fe, K, Mg, Mn, Na, P, Si, Ti) and compounds (organic carbon, Al_dithionate, Al_oxalate, Fe_dithionate, and Fe_oxalate) within SPM trapped on quartz fibre filters at masses as low as 3 mg. Calibration models with small prediction errors are derived, along with mass correction factor models to account for variations in retained SPM mass. Spectral pre‐processing methods are shown to enhance the reproducibility of results for some compounds, and the importance of filter paper selection and homogeneous sample preparation in minimizing spectral interference is emphasized. The geochemical signal from sediment covered filter papers is demonstrated to be time stable enabling samples to be stored for several weeks prior to analysis. Example results obtained during a heavy precipitation event in October 2012 demonstrate the methodology presented here has considerable potential to be utilized for high‐resolution monitoring of SPM geochemistry under a range of in‐stream hydrological conditions. Copyright © 2013 John Wiley & Sons, Ltd.     

广西岛坪磷氯铅矿的谱学特征

磷氯铅矿(Pyromorphite)在我国比较罕见,2001年在广西岛坪发现的磷氯铅矿结晶较好,运用XRD、XRFI、R和UV/Vis等分析方法对黄色和绿色样品进行了研究。结果表明,二者XRD谱只是峰强有所不同。在它们的红外吸收谱带中,除了标准的PO43-吸收峰外,在670~800 cm-1之间和430 cm-1左右出现的两组肩峰为SiO44-振动峰。黄色样品的振动频率偏高、半峰宽偏窄、透射率与绿色样品相比较高。通过XRF分析发现黄色晶体比绿色晶体含有更多的Fe3 ,而Fe3 常使矿物呈现黄色,同时证实了黄色磷氯铅矿的红外吸收峰频率偏高是因为它的铅含量低于绿色矿。UV/Vis进一步说明在可见光区的吸收不同是使二者颜色差异的主要原因,Fe离子含量较大使磷氯铅矿呈现黄色。     

High‐Arctic climate conditions for the last 7000 years inferred from multi‐proxy analysis of the Bliss Lake record,North Greenland

The Arctic is more vulnerable to climate change than are mid latitudes. Therefore, palaeolimnological studies from the High Arctic are important in providing insights into the dynamics of the climate system. Here we present a multi‐proxy study from one of the world's northernmost lakes: Bliss Lake, Peary Land, Greenland. The early Holocene (10 850–10 480 cal. a BP) is characterized by increased erosion and gradually more marine conditions. Full marine conditions developed from 10 480 cal. a BP until the lake was isolated at 7220 cal. a BP. From its marine isolation at 7220 cal. a BP Bliss Lake becomes a lacustrine environment. Evidence from geochemical proxies (δ¹³C and total organic carbon) suggests that warmer conditions prevailed between 7220 and 6500 cal. a BP, corresponding to the Holocene thermal maximum, and from 3300 until 910 cal. a BP. From 850 to 500 cal. a BP colder climate conditions persisted. The transition from warmer to colder climate conditions taking place around 850 cal. a BP may be associated with the transition from the Medieval Warm Period to the Little Ice Age. Copyright © 2011 John Wiley & Sons, Ltd.     

8680 X荧光光谱仪与长城0520-CH计算机的数据通信

8680X荧光光谱仪采用RSX-11M多用户操作系统。本文将0520计算机作为RSX-11M主机的一个从属终端,设计了相应软件与8680联机。无需修改任何硬件,在0520上可以执行RSX-11M的全部操作指令,并且只要8680主机不关闭,0520计算机即可随时从8680的磁盘上读取数据而不需事先与8680的操作者约定,传送数据快速、准确。     

豫北及其外围地区地壳上地幔结构研究

利用菏泽～长治和郑州～济南深地震测深剖面资料，进行了一维、二维射线追踪走时拟合与合成地震图计算，获得了该区地壳上地幔速度结构。结果表明，地壳上地幔速度结构在纵向和横向上具有明显的不均一性。浅部断裂较发育，对应其地壳深部界面和速度等值线起伏变化较明显。在华北坳陷区南部上地幔隆起的背景上存在两个局部凸起，凸起最高处与浅部的东濮凹陷、汤阴地堑基本对应，Ｍ面埋深分别约３１ｋｍ和３４ｋｍ     

粘滑失稳及其物理场时空分布的实验研究

摩擦滑动的物理场实验研究表明：（１）能量空间分布的差异是失稳的重要条件，单发型大事件常发生于高能量向低能量的突变带或高能量背景区内的相对低能量区；（２）单发型大事件的孕育过程常常经历若干个能量输入输出循环，产生多个前兆阶段，并在失稳前源区常有一个弱化过程。小震或群发型事件失稳前常常只有一个能量积累与强化的过程，失稳前兆阶段性反映较差；（３）粘滑失稳时断层的位错与声发射的大小未见明显关系