Tectonothermal events in the Olympic IOCG Province constrained by apatite and REE-phosphate geochronology

The Olympic iron oxide–copper–gold province in South Australia contains numerous deposits and prospects, including the Olympic Dam Cu–U–Au–Ag deposit and the Acropolis prospect. The Acropolis prospect comprises massive, coarse-grained magnetite–apatite veins partly replaced by a hematite-stable assemblage. The apatite grains in the veins contain zones with abundant inclusions of other minerals (including monazite and xenotime) and low trace-element concentrations relative to the inclusion-free zones. The inclusion-rich apatite zones are interpreted to be formed from the recrystallisation of the inclusion-free apatite and remobilisation of U, Th and rare earth element (REE) from apatite into monazite and xenotime. Apatite, monazite and xenotime are all established U–Th–Pb geochronometers and offer the potential to constrain the alteration history of the Acropolis prospect. The LA-ICPMS U–Pb age of inclusion-free apatite is within error of the age of the host volcanic units (ca 1.59 Ga). Inclusion-rich apatite yields both near-concordant analyses that are within error of the inclusion-free apatite as well as highly disturbed (discordant) analyses. The most concordant analyses of monazite (Th–Pb) inclusions and xenotime (U–Pb) inclusions and rim grains indicate an alteration event occurred at ca 1.37 Ga and possibly also at ca 500 Ma. The disparity in age of the inclusion-rich apatite and the REE-phosphate inclusions (and rim grains) is suggested to be owing to the apatite being initially recrystallised at ca 1.59 Ga and modified again by a later event that also formed (or coarsened) most of the inclusions. Partial resetting of the majority of the monazite inclusions as well as the presence of significant amounts of common Pb has complicated the interpretation of the monazite results. In contrast, xenotime is a more robust geochronometer in this setting. The ages of the two post-1.59 Ga events that appear to have affected the Acropolis prospect do not correspond to any events known to have occurred in the Gawler Craton. The earlier (ca 1.37 Ga) age instead corresponds best with metamorphic–magmatic–hydrothermal activity in Laurentia, consistent with the proximity of Laurentia and the Gawler Craton inferred from palaeogeographic reconstructions. The later (ca 500 Ma) event corresponds to the Delamerian Orogeny and has been shown by prior studies to have also affected the Olympic Dam deposit.     

SHRIMP U–Pb geochronology of authigenic xenotime and its potential for dating sedimentary basins

SHRIMP (Sensitive High‐Resolution Ion MicroProbe) analytical procedures have been developed to enable dating of the small, early diagenetic xenotime overgrowths that commonly occur on zircons in siliciclastic sedimentary rocks. The method will be particularly useful in Precambrian terranes, where diagenetic xenotime dating could play a role equivalent to biostratigraphic dating in the Phanerozoic. Reliable ²⁰⁷Pb/²⁰⁶Pb data are more readily obtained than ²⁰⁶Pb/²³⁸U, which also favours application to the Precambrian. However, it is demonstrated that ²⁰⁶Pb/²³⁸U dating of larger overgrowths (>10 μm) is also viable and applicable to Phanerozoic samples. SHRIMP Pb/Pb geochronology of authigenic xenotime in an unmetamorphosed Palaeoproterozoic sandstone in the Kimberley Basin has constrained diagenesis to a precision of ± 7 Ma. In contrast, greenschist‐facies metasediments of the Archaean Witwatersrand Basin, South Africa, contain both authigenic and alteration xenotime that record a complex history of growth from early diagenesis to the last major thermal event to affect the basin.     

Prograde metamorphic sequence of REE minerals in pelitic rocks of the Central Alps: implications for allanite–monazite–xenotime phase relations from 250 to 610 °C

The distribution of REE minerals in metasedimentary rocks was investigated to gain insight into the stability of allanite, monazite and xenotime in metapelites. Samples were collected in the central Swiss Alps, along a well‐established metamorphic field gradient that record conditions from very low grade metamorphism (250 °C) to the lower amphibolite facies (～600 °C). In the Alpine metapelites investigated, mass balance calculations show that LREE are mainly transferred between monazite and allanite during the course of prograde metamorphism. At very low grade metamorphism, detrital monazite grains (mostly Variscan in age) have two distinct populations in terms of LREE and MREE compositions. Newly formed monazite crystallized during low‐grade metamorphism (<440 °C); these are enriched in La, but depleted in Th and Y, compared with inherited grains. Upon the appearance of chloritoid (～440–450 °C, thermometry based on chlorite–choritoid and carbonaceous material), monazite is consumed, and MREE and LREE are taken up preferentially in two distinct zones of allanite distinguishable by EMPA and X‐ray mapping. Prior to garnet growth, allanite acquires two growth zones of clinozoisite: a first one rich in HREE + Y and a second one containing low REE contents. Following garnet growth, close to the chloritoid–out zone boundary (～556–580 °C, based on phase equilibrium calculations), allanite and its rims are partially to totally replaced by monazite and xenotime, both associated with plagioclase (± biotite ± staurolite ± kyanite ± quartz). In these samples, epidote relics are located in the matrix or as inclusions in garnet, and these preserve their characteristic chemical and textural growth zoning, indicating that they did not experience re‐equilibration following their prograde formation. Hence, the partial breakdown of allanite to monazite offers the attractive possibility to obtain in situ ages, representing two distinct crystallization stages. In addition, the complex REE + Y and Th zoning pattern of allanite and monazite are essential monitors of crystallization conditions at relatively low metamorphic grade.     

Geochemistry and provenance of the Turquoise Bluff Slate,northeastern Tasmania: tectonic significance

The Ordovician Turquoise Bluff Slate in northeastern Tasmania is a 2?km-thick sequence of deep-marine siliceous black slates. It is dominated by meta-siltstones with bimodal grainsize distributions typical of turbidite T_E-1 and T_E-2 facies. The slates have high SiO₂ indicating they are hemipelagites. The high Ba and V indicate they were deposited in an anoxic environment associated with high oceanic productivity. All these features are common in muddy turbidites. U–Th–Pb dating of detrital monazite and authigenic xenotime in the slates supports previous evidence that the dominant cleavage, in this unit, formed during the Benambran Orogeny. The whole-rock composition of the slates is similar to black slates in the Adaminaby Group, NSW. A review of Paleozoic whole-rock compositions from the Lachlan Orogen confirms they all have trace element contents similar to average Australian shale. However, there are subtle differences in composition. The Turquoise Bluff Slate and other Mathinna Supergroup rocks from the Eastern Tasmania Terrane have higher average Cr content than similar age turbidites from Victoria and NSW. This probably reflects a small contribution from Tasmania Cambrian ultramafic rocks in the provenance. If this were correct, northeastern Tasmania was closer to western Tasmania in the Paleozoic than other provinces of the Lachlan Orogen, southeastern Australia. Other subtle features of the whole-rock composition of Paleozoic sedimentary rocks from the Lachlan Orogen indicate it may be possible to recognise provincial variations in composition that will provide new constraints on tectonic models of southeastern Australia.     

Grenvillian-aged orogenesis in the Palaeoproterozoic Gascoyne Complex, Western Australia: 1030–950 Ma reworking of the Proterozoic Capricorn Orogen

In situ SHRIMP U–Pb geochronology of monazite and xenotime in pelitic schists from the central Gascoyne Complex, Western Australia, shows that greenschist to amphibolite facies metamorphism occurred between c. 1030 and c. 990 Ma. Monazite from an undeformed rare‐element pegmatite from the same belt gives a ²⁰⁷Pb/²⁰⁶Pb age of c. 950 Ma, suggesting that peak metamorphism and deformation was followed by pegmatite intrusion and coeval granite magmatism. Metamorphism in the central Gascoyne Complex was previously interpreted as Barrovian, largely based on the identification of kyanite in peak metamorphic assemblages, and has been attributed to intense crustal shortening and substantial tectonic thickening during Palaeoproterozoic continent–continent collision. However, the stable Al₂SiO₅ polymorph has been identified in this study as andalusite rather than kyanite, and the prograde assemblages of staurolite–garnet–andalusite–biotite–muscovite–quartz indicate temperatures of 500–550 °C and pressures of 3–4 kbar. These data show that the Palaeoproterozoic Gascoyne Complex underwent an episode of Grenvillian‐aged intracontinental reworking concentrated in a NW–SE striking corridor, during the Edmundian Orogeny. Until now, the Edmundian Orogeny was thought to have involved only reactivation of structures in the Gascoyne Complex, along with deformation and very low‐ to low‐grade metamorphism of Mesoproterozoic cover rocks some time between 1070 and 755 Ma. However, we suggest that it involved regional amphibolite facies metamorphism and deformation, granite magmatism and pegmatite intrusion between c. 1030 and c. 950 Ma. Therefore, the Capricorn Orogen experienced a major phase of tectonic reworking c. 600 Myr later than previously recognized. Our results emphasize the importance of in situ geochronology integrated with petrological studies in order to link the metamorphic history of a terrane with causally related tectonic events.     

Microtextures, geochemistry and geochronology of authigenic xenotime: constraining the cementation history of a Palaeoproterozoic metasedimentary sequence

An ≈ 26 m thick unit of phosphatic sandstone and black shale (the Phosphatic Unit) in the Palaeoproterozoic Mount Barren Group of south-western Australia contains abundant authigenic xenotime crystals showing well-preserved diagenetic textures. Despite extensive regional deformation and thermal metamorphism, the peak of which occurred at ≈ 1205 Ma, the Phosphatic Unit was preserved as a low-strain envelope because of its pre-compaction carbonate and phosphate cementation. In situ U–Pb geochronology of xenotime reveals four discrete age populations at 1693 ± 4, 1645 ± 3, 1578 ± 10 and 1481 ± 21 Ma. When integrated with petrography, the age data place a timeframe on: (i) sediment deposition; (ii) phosphogenesis; (iii) diagenetic cement infilling; (iv) diagenetic pyrite formation; (v) secondary porosity generation; (vi) hydrocarbon migration; (vii) burial compaction; and (viii) hydrothermal alteration, up until peak thermal metamorphism. Xenotime growth at ≈ 1693 Ma occurred prior to compaction, whereas xenotime growth at ≈ 1645 Ma occurred during burial. Xenotime growth at ≈ 1580 Ma and at ≈ 1480 Ma appears to be the far-field record of thermotectonic events associated with intracontinental extension and magmatism recorded elsewhere in Australia. Geochemical analysis, integrated with geochronology, shows a systematic increase in MREE/HREE in xenotime crystals with decreasing age and with increasing stratigraphic depth. Coupled with a decrease in xenotime abundance and age with depth, it suggests that: (i) the main focus of porosity infilling was at the top of the Phosphatic Unit and progressed downwards over the > 200 Myr period of porosity infilling, and (ii) the changes in xenotime REE chemistry may be due to an influx of MREE from increasing amounts of dissolved apatite or changes, with respect to REE solubility, in the physiochemical nature of the fluids with burial depth.     

稀土磷酸盐矿物合成的一些实验

本文研究了稀土磷酸盐类矿物的形成条件及矿物中各稀土元素相互置换的可能性和物理化学条件。 实验表明,独居石的形成条件范围很宽,它可在压力70—1000bar、温度>130℃、pH=2—10的范围内形成。磷钇矿的形成条件与独居石相似。在不同的温、压及pH条件下,从La—Tb的磷酸盐呈独居石的结构,而Tb—Lu却突变为磷钇矿的结构。     

碎屑沉积岩沉积作用的高精度定年——自生磷钇矿离子探针UPb年龄测定

沉积岩沉积作用准确时间的厘定是目前同位素年代学研究中的一大难题 ,尽管目前可采用多种方法对成岩过程中的自生矿物进行定年 ,但由于技术上的原因 ,这项研究一直发展很慢。文中详细介绍了近年来发展起来的运用高精度离子探针 (SHRIMP)技术确定自生磷钇矿形成年龄 ,进而确定沉积作用年代的新方法。如 ,澳大利亚西北部Kimberley盆地中未变质的古元古代砂岩中自生磷钇矿的SHRIMP定年将成岩作用限定在 7Ma的误差范围之内。相比之下 ,对非洲南部太古宙Witwa tersrand超群和澳大利亚西南部MountBarren群绿片岩相变质砂岩中磷钇矿的研究 ,不仅确定了所研究岩石的成岩作用时代 ,而且恢复了该区后期的复杂热演化历史。研究还表明 ,这种方法同样适用于显生宙岩石。这些实例表明 ,磷钇矿的SHRIMP定年不仅可以测定从太古宙到第四系所有年代碎屑沉积岩的沉积时代 ,而且可以实现极小尺度上的微区定年 ,从而可以研究岩石自沉积成岩以后的演化历史 ,显示这一方法在沉积作用及相关热事件问题研究上的巨大潜力。     

准噶尔盆地北三台凸起新近系含铀砂层分布预测

通过对准噶尔盆地北三台凸起油气钻井的录、测井等资料分析发现,在新近系沙湾组底部发育一套异常高自然伽马砂砾岩,其中B311 井GR值最高达1 732.58 API,预示该区具有良好铀资源勘探前景.为准确预测该区含铀砂岩分布,通过精细的合成记录标定,对该含铀砂层提取地震属性.通过多属性融合与分析,预测含铀砂层平面分布,进而...