Evolution of 2:1 layered silicates in low-grade metamorphosed Liassic shales of Central Switzerland

White mica from the Liassic black shales and slates in Central Switzerland was analysed by transmission electron microscopy (TEM) and electron microprobe to determine its textural and compositional evolution during very low-grade prograde metamorphism. Samples were studied from the diagenetic zone, anchizone and epizone (T ≈100°–450 °C). Phyllosilicate minerals analysed include illite/smectite (I/S), phengite, muscovite, brammallite, paragonite, margarite and glauconite. Textural evolution primarily is towards larger, more defect-free grains with compositions that approach those of their respective end-members. The smectite-to-illite transformation reduced the amounts of the exchange components SiK_?1Al_?1, MgSiAl_?2, and Fe³⁺Al_?1. These trends continue to a lesser degree in the anchizone and epizone. Correlations between the proportion of smectite in I/S and the composition of I/S indicate that smectite layers may contain a high layer charge. Illite in I/S bears a compositional resemblance to macrocrystalline phengite in some samples, but is different in others. Paragonite first appears in the upper diagenetic zone or lower anchizone as an interlayer-deficient brammallite, and it may be mixed with muscovite on the nanometre scale. Owing to the small calculated structure factor for paragonite-muscovite superstructures, conventional X-ray powder diffraction cannot distinguish between mixed-layer structures and a homogeneous compositionally intermediate solid solutions. However, indirect TEM evidence shows that irregularly shaped domains of Na- and K-rich mica exist below 10 nm. Subsequent coarsening of domains at higher grades produced discrete paragonite grains at the margins of muscovite crystals or in laths parallel to the basal plane of the host muscovite. Margarite appears in the epizone and follows a textural evolution similar to paragonite in that mixtures of margarite, paragonite, and muscovite may initially occur on the nanometre scale. However, no evidence of interlayer-poor margarite has been found.     

Post-solidification cooling and the age of Io's lava flows

The modeling of thermal emission from active lava flows must account for the cooling of the lava after solidification. Models of lava cooling applied to data collected by the Galileo spacecraft have, until now, not taken this into consideration. This is a flaw as lava flows on Io are thought to be relatively thin with a range in thickness from ∼1 to 13 m. Once a flow is completely solidified (a rapid process on a geological time scale), the surface cools faster than the surface of a partially molten flow. Cooling via the base of the lava flow is also important and accelerates the solidification of the flow compared to the rate for the ‘semi-infinite’ approximation (which is only valid for very deep lava bodies). We introduce a new model which incorporates the solidification and basal cooling features. This model gives a superior reproduction of the cooling of the 1997 Pillan lava flows on Io observed by the Galileo spacecraft. We also use the new model to determine what observations are necessary to constrain lava emplacement style at Loki Patera. Flows exhibit different cooling profiles from that expected from a lava lake. We model cooling with a finite-element code and make quantitative predictions for the behavior of lava flows and other lava bodies that can be tested against observations both on Io and Earth. For example, a 10-m-thick ultramafic flow, like those emplaced at Pillan Patera in 1997, solidifies in ∼450 days (at which point the surface temperature has cooled to ∼280 K) and takes another 390 days to cool to 249 K. Observations over a sufficient period of time reveal divergent cooling trends for different lava bodies [examples: lava flows and lava lakes have different cooling trends after the flow has solidified (flows cool faster)]. Thin flows solidify and cool faster than flows of greater thickness. The model can therefore be used as a diagnostic tool for constraining possible emplacement mechanisms and compositions of bodies of lava in remote-sensing data.     

Occurrence and evolution of the Xiaotangshan hot spring in Beijing, China

Thermal groundwater occurs in bedrock aquifers consisting of the dolomite of the Wumishan Group of the Jixianin System and the Cambrian carbonate in the Xiaotangshan geothermal field near the northern margin of the North China Plain, China. The hot water in the geothermal field of basin-type discharges partly in the form of the Xiaotangshan hot spring under natural conditions. The hot water has TDS of less than 600 mg/L and is of Na·Ca-HCO₃ type. The geothermal water receives recharge from precipitation in the mountain area with elevation of about 500 m above sea level to the north of the spring. Thermal groundwater flows slowly south and southeast through a deep circulation with a residence time of 224 years estimated with the Ra–Rn method. The Xiaotangshan hot spring dried up in the middle of the 1980s owing to the increasing withdrawal of the hot water in the geothermal field in the past decades. The water level of the geothermal system still falls continually at an annual average rate of about 2 m, although water temperature changes very little, indicating that the recharge of such a geothermal system of basin-type is limited. Over-exploitation has a dramatic impact on the geothermal system, and reduction in exploitation and reinjection are required for the sustainable usage of the hot water.     

我国海域分等定级指标体系研究

长期以来,海域的无偿使用导致海洋开发活动秩序混乱、海洋环境污染加剧、海洋生物资源枯竭、海洋生态环境遭到破坏,严重阻碍和制约沿海地区的可持续发展.本文试图根据经济学的“地租级差”理论和运筹学中的“层次分析法”并结合我国沿海11个省、市和自治区的社会、经济、基础设施、自然资源等因素进行理论探讨,给出了我国管辖海域的等级.为今后我国制定海域有偿使用金的征收标准奠定基础.     

近海海洋石油平台导管架喷涂金属层防腐

锌、铝及其合金涂层对钢铁的防护，不仅对阴极起保护作用(Gartland，1987)， 对涂层本身也具有良好的抗腐蚀性能。此外，涂层中金属微粒表面形成的致密氧化膜，也起到了防腐蚀的作用。在不同大气环境下，锌、铝有良好的耐蚀性，其腐蚀速率比钢铁要低得多(李言涛，1998)。采用热喷涂锌、铝及其合金涂层对钢铁构件和构筑物进行长效防护早在20世纪20年代就已开始应用，至今仍是普遍采用的防护措施，并在继续发展(李守本等，1989)。20年代初，法国首先用于海水闸门的防腐；40年代美国用于墨西哥湾的海上井架和海上输油管以及舰船的防腐；60年代英、法、德等国海军将这一技术扩大应用到舰船的上部结构和船壳。而金属热喷涂技术在海洋工程中使用非常有限，第一次使用热喷铝涂层防护近海平台的实例是Conoco公司在北海的Murchison结构上的锥形塔，并且已获得了4a良好的使用效能(Fisher et al.，1987；Shaw et al.，1985)。1984年6月，Hutton张力支柱平台(TLP)在北海下水(水深148 m)安装。系链、升降机和锥形塔均采用火焰热喷涂技术喷涂铝涂层进行防护(Tyson，1985)。1992年6月，Hotton平台使用8a后，对升降机绳索进行观察，在飞溅区没有发现腐蚀现象，也没有检测到褐色渗漏效应(Fisher et al.，1995)。     

莱州湾东部滨海水域砂金分布特征

通过对莱州湾东部滨海水域地球物理和地质钻综合调查，业已查明该海区地质的构造和古地理环境特征，并发现区内砂金分布较普遍，本文从砂金分布的地貌单元，沉积物类型，砂金成因类型，物质来源，古气候，构造作用，砂金成因等诸方面，研究了该海域内砂金特征。     

Fault Characteristics in Longmen Mountain Thrust Belt,Western Sichuan Foreland Basin,China

Through field geological survey,the authors found that abundant thrust faults developed in the Longmen (龙门) Mountain thrust belt.These faults can be divided into thrust faults and strike-slip faults according to their formation mechanisms and characteristics.Furthermore,these faults can be graded into primary fault,secondary fault,third-level fault,and fourth-level fault according to their scale and role in the tectonic evolution of Longmen Mountain thrust belt.Each thrust fault is composed of several secondary faults,such as Qingchuan (青川)-Maowen (茂汶) fault zone is composed of Qiaozhuang (乔庄) fault,Qingxi (青溪) fault,Maowen fault,Ganyanggou (赶羊沟) fault,etc..The Longmen Mountain thrust belt experienced early Indosinian movement,Anxian (安县) movement,Yanshan (燕山)movement,and Himalayan movement,and the faults formed gradually from north to south.     

东北大兴安岭多年冻土区工程地质特征及评价

土体在冻结状态具有极高的压缩模量, 具有弹性体的工程地质特征。但是在冻土地温升高过程中, 这种特征急剧衰减, 产生蠕变和流变, 建筑物地基强度降低, 导致建筑物基础破坏。同时土体在冻结过程中产生的冻胀作用也将导致建筑物基础的破坏。东北大兴安岭地区多年冻土为高纬度低海拔多年冻土, 其分布具有明显纬度地带性特点。本文在分析该区多年冻土分布特征及冻土工程地质特点的基础上, 对由于土体的冻胀和融沉导致的建筑物基础的危害进行分类研究, 针对性的提出了用热棒降低土体温度以保证多年冻土稳定及用排水的方法减少水对建筑物地基多年冻土影响的工程病害处理措施。     

Estimates of heat flow and heat production and a thermal model of the São Francisco craton

An updated analysis of geothermal data from the highland area of eastern Brazil has been carried out and the characteristics of regional variations in geothermal gradients and heat flow examined. The database employed includes results of geothermal measurements at 45 localities. The results indicate that the Salvador craton and the adjacent metamorphic fold belts northeastern parts of the study area are characterized by geothermal gradients in the range of 6–17°C/km. The estimated heat flow values fall in the range of 28–53 mW/m², with low values in the cratonic area relative to the fold belts. On the other hand, the São Francisco craton and the intracratonic São Francisco sedimentary basin in the southwestern parts are characterized by relatively higher gradient values, in the range of 14–42°C/km, with the corresponding heat flow values falling in the range of 36–89 mW/m². Maps of regional variations indicate that high heat flow anomaly in the São Francisco craton is limited to areas of sedimentary cover, to the west of the Espinhaço mountain belt. Crustal thermal models have been developed to examine the implications of the observed intracratonic variations in heat flow. The thermal models take into consideration variation of thermal conductivity with temperature as well as change of radiogenic heat generation with depth. Vertical distributions of seismic velocities were used in obtaining estimates of radiogenic heat production in crustal layers. Crustal temperatures are calculated based on a procedure that makes simultaneous use of the Kirchoff and Generalized Integral Transforms, providing thereby analytical solutions in 2D and 3D geometry. The results point to temperature variations of up to 300°C at the Moho depth, between the northern Salvador and southern São Francisco cratons. There are indications that differences in rheological properties, related to thermal field, are responsible for the contrasting styles of deformation patterns in the adjacent metamorphic fold belts.     

高原大地形及海洋热力强迫对东亚及北半球环流和气候变化影响的观测研究

本文总结了“青藏高原大地形及西太平洋暖池势力强迫对东亚及全球气候变化的影响”专题五年来的主要研究工作。其中包括青世故高原东部大气热源的时间演变特征,夏半年高原热源异常对我国降水和北半球环流的影响;西沙海温变化特征及其与我南方降水的关系,北太平洋海温主因子特征及其与华南前汛期降水的变化。