The structure and dynamics of 2-dimensional fluids in swelling clays

The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH₃OD and (CH₂OD)₂ in deuterated clay allows us to measure the diffusion of the CH₃- and CH₂-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution.     

The colonization of periphytic diatom species on artificial substrates in the Ashar canal, Basrah, Iraq

Studies have been conducted between March 1993 and March 1994 in the Ashar canal, a backwater of the Shatt al-Arab River, Iraq. Using artificial substrates, the colonization and development of seventy-five diatom species belonging to twenty genera could be revealed. Taxa apportionment varied seasonally as well as within each season. A few species have been found during all experiments. These are Amphora ovalis, Bacillaria paradoxa, Cocconeis placentula var. euglypta, Cyclotella meneghiniana, Cymbella ventricosa, Navicula tripunctata var. schizonemoides, Rhoicosphenia curvata, and Synedra ulna. The occurrence of B. paradoxa in Experiment 1 (March-April 1993) and Experiment 4 (end of January to beginning of March 1994) was higher than 50%. Similarity of species increased towards the end of each season, and the communities from experiments 1 and 4 were more similar than others. The experiments also suggest that week 4 represents the equilibrium phase while week 6 reflects the increase in biological interactions. The results could also indicate the sequence of primary colonizers and the community development towards the equilibrium.     

A simple test and predictive models for assessing swell potential of Ankara (Turkey) Clay

During the past three decades, damage due to swelling action of Ankara Clay has been observed more clearly in some parts of Ankara where rapid expansion of the city led to the construction of various kinds of structures. In this study, a comprehensive research program has been conducted (i) to investigate the effect of remoulding and desiccation on the swelling behavior of Ankara Clay and its swelling anisotropy, (ii) to estimate depth of active zone, (iii) to develop a simple technique in determining the magnitude of swelling based on water content of the soaked specimen after 24 and 72 h (w_max24,72), and (iv) to produce predictive models which could be used to estimate the swelling potential of Ankara Clay from its mineralogical and simply measured engineering characteristics. A laboratory testing program was carried out using both undisturbed, and remoulded and desiccated samples selected from 20 different locations. Montmorillonite was identified as being the main clay mineral present. Based on the moisture content variation with depth, the active expansive zone was considered to be about 2 m. The test results suggest that swelling pressure of the clay considerably decreases and/or dies out when the water content is greater than 30%. It is also noted that the measured lateral swelling is significantly in excess of the vertical equivalent indicating an anisotropy with respect to swelling. Statistical assessments indicate that a new parameter (w_max24,72) from a simple test, suggested in this study, is a very strong parameter for predicting swelling parameters of Ankara Clay. Based on 60 empirical predictive equations with coefficients of correlation between 0.96 and 0.66 from multiple regression analyses, w_max24,72, methylene blue value, liquid limit, dry unit weight and smectite content are the most important index and mineralogical properties to predict the swelling parameters of Ankara clay with small deviations from the measured values.     

Validation of MODIS Vegetation Continuous Fields for monitoring deforestation and forest degradation: two cases in Mexico

This study assesses whether MODIS Vegetation Continuous Fields percent tree cover (PTC) data can detect deforestation and forest degradation. To assess the usefulness of PTC for detecting deforestation, we used a data set consisting of eight forest and seven non-forest categories. To evaluate forest degradation, we used data from two temperate forest types in three conservation states: primary (dense), secondary (moderately degraded) and open (heavily degraded) forest. Our results show that PTC can differentiate temperate forest from non-forest categories (p = 0.05) and thus suggests PTC can adequately detect deforestation in temperate forests. In contrast, single-date PTC data does not appear to be adequate to detect forest degradation in temperate forests. As for tropical forest, PTC can partially discriminate between forest and non-forest categories.     

近20年京津唐地区不透水面变化的遥感监测

不透水面是衡量城市化程度的重要指标之一,对京津唐城市群的不透水面进行深入研究,可以量化城市群扩张过程及其影响,对该区域多城市协调发展及规划布局具有重要意义。本文结合高分辨遥感影像、生长季及落叶季的Landsat TM遥感影像和夜间灯光数据等,采用分类和回归树（Classification and rRegression Tree, CART）算法,构建了适于京津唐地区不透水面盖度提取的技术方案,获取了京津唐地区1995-2016年共5期地表不透水面盖度专题信息,并分析了地表不透水面的时空演变规律,结论为：① 适于京津唐地区不透水面盖度提取的CART算法的最佳输入变量组合为：生长季和落叶季的Landsat TM图像以及对应的夜间灯光数据;其次为生长季Landsat TM遥感图像和夜间灯光数据组合方案。利用该组合方案,ISP估算输出结果的交叉验证精度R值可以达到约0.85,可以满足地表不透水面纵向对比分析的需要。② 从地表不透水面总面积数量值来看,1995-2016年京津唐主体城市区域整体上呈增长趋势,其中2011-2016年地表不透水面积增加愈加明显;③ 从地表不透水面盖度值的高低来看,1995-2016年京津唐中、高盖度不透水面的占比都是在不断增长的,低盖度不透水面占比存在少量下降现象,且京、津、唐3城市的主体城区各阶段变化差异较大,反映出了各城市扩张具有各自不同的时空演变特征。     

Stabilization of Expansive Clays Using Granulated Blast Furnace Slag (GBFS) and GBFS-Cement

Expansive clays undergo swelling when subjected to water. This can cause damage, especially to light weight structures, water conveyance canals, lined reservoirs, highways, and airport runways unless appropriate measures are taken. In this study, granulated blast furnace slag (GBFS) and GBFS-cement (GBFSC) were utilized to overcome or to limit the expansion of an artificially prepared expansive soil sample (sample A). GBFS and GBFSC were added to sample A in proportions of 5–25% by weight. The effects of these stabilizers on grain size distribution, Atterberg limits, swelling percentage and rate of swell of soil samples were determined. GBFS and GBFSC were shown to successfully decreasing the total amount of swell while increasing the rate of swell.     

Free-Swell and Swelling Pressure of Unsaturated Compacted Clays; Experiments and Neural Networks Modeling

Expansive soils have received attentions of several investigators in the past half of century in the problematic soils context. Volume change behavior of unsaturated compacted soils in presence of water and change of degree of saturation was observed in two form of heave or collapse. Low water content and low density compacted soils in presence of enough surcharge pressure lose stability and collapse, because of their metastable and susceptible structure to change of degree of saturation. Free-swell and swelling pressure of five compacted clays, covering low to high plastic clays have been investigated in respect to compaction states and swelling pressure was compared with collapse pressure threshold. The results of experiments were utilized in two Artificial Neural Networks to predict free-swell percent and swelling pressure of a soil sample based on index properties and compaction state.     

A model for multiphase flow and transport in porous media including a phenomenological approach to account for deformation—a model concept and its validation within a code intercomparison study

Multiphase flow processes in unsaturated cohesive soils are often affected by deformation due to swelling and shrinking as a result of varying water contents. This paper presents a model concept which is denoted ‘phenomenological’ in terms of the processes responsible for soil deformation, since the effects of deformation on flow and transport are only considered by constitutive relations that allow an adaptation of the hydraulic properties. This new model is validated in a detailed intercomparison study with two state-of-the-art models that are capable of explicitly describing the processes relevant for the deformation. A ‘numerical experiment’ with a state-of-the-art reference model is used to produce ‘measurement data’ for an inverse-modelling-based estimation of the model input parameters for the phenomenological concept.