Investigation of vertical distribution and morphology of indigenous organic matter at Sleeping Bear site,Michigan

This study evaluates the nature and origin of particulate organic carbon and organic coatings on aquifer sands upgradient from a fuel spill site near the Sleeping Bear Dunes National Lakeshore in Michigan. The distribution of carbon was found to be highly complex due to the occurrence of high organic carbon horizons, bounded above and below by high carbonate sediments. The organic coatings on the sands were examined using white light and fluorescence microscopy and by scanning electron microscopy. Core samples were analyzed for organic and inorganic carbon, solution pH, humic/fulvic acid ratios, and insoluble organic matter content (that is, humin) as a function of depth from the ground surface. The organic geochemistry of the soil profile at this site was found to be significantly influenced by the carbonates producing a sharp boundary of precipitated organic matter. This boundary was followed by coatings of predominantly fulvic acid salts on mineral grains deeper in the soil column. The coatings extended into the aquifer. The existence of native organic films on sand grains is well documented in the soils literature. The study reported here was greatly aided by this information and provides the framework for future studies concerning the influence of carbon distribution, chemical identity, and morphology on contaminant fate and transport processes.     

Holocene loess deposition and soil formation as competing processes, Matanuska Valley, southern Alaska

Although loess–paleosol sequences are among the most important records of Quaternary climate change and past dust deposition cycles, few modern examples of such sedimentation systems have been studied. Stratigraphic studies and 22 new accelerator mass spectrometry radiocarbon ages from the Matanuska Valley in southern Alaska show that loess deposition there began sometime after 6500 ¹⁴C yr B.P. and has continued to the present. The silts are produced through grinding by the Matanuska and Knik glaciers, deposited as outwash, entrained by strong winds, and redeposited as loess. Over a downwind distance of 40 km, loess thickness, sand content, and sand-plus-coarse-silt content decrease, whereas fine-silt content increases. Loess deposition was episodic, as shown by the presence of paleosols, at distances >10 km from the outwash plain loess source. Stratigraphic complexity is at a maximum (i.e., the greatest number of loesses and paleosols) at intermediate (10–25 km) distances from the loess source. Surface soils increase in degree of development with distance downwind from the source, where sedimentation rates are lower. Proximal soils are Entisols or Inceptisols, whereas distal soils are Spodosols. Ratios of mobile CaO, K₂O, and Fe₂O₃ to immobile TiO₂ show decreases in surface horizons with distance from the source. Thus, as in China, where loess deposition also takes place today, eolian sedimentation and soil formation are competing processes. Study of loess and paleosols in southern Alaska shows that particle size can vary over short distances, loess deposition can be episodic over limited time intervals, and soils developed in stabilized loess can show considerable variability under the same vegetation.     

Estimating the Time Since Final Stabilization of a Perched Dune Field Along Lake Superior

The Nodaway dune field is perched along Lake Superior in Upper Michigan. This study uses absolute and relative‐age dating methods to test the hypothesis that the dune field finally stabilized after the Nipissing high stand, about 4,000 years ago. Surface soils on snouts of all dunes are moderately developed Spodosols, indicating that dunes stabilized within a few hundred years of each other. One thermoluminescence date provided an age of 8 ka from soil parent material, but is probably overestimated due to residual thermoluminescence. Subsequent optical stimulated luminescence and accelerator mass spectrometry age estimates indicate that the most recent accumulation of sand occurred between ?3.7 and 3.0 ka. This interval suggests one of three possibilities: 1) that the dune field was reactivated during the Algoma high stand and then stabilized; 2) that the dune field stabilized gradually, probably as sand supply diminished after the Nipissing high stand; and 3) that a combination of these two processes occurred.     

Hornblende etching and quartz/feldspar ratios as weathering and soil development indicators in some Michigan soils

Weathering can be used as a highly effective relative age indicator. One such application involves etching of hornblende grains in soils. Etching increases with time (duration) and decreases with depth in soils and surficial sediments. Other variables, related to intensity of weathering and soil formation, are generally held as constant as possible so as to only minimally influence the time-etching relationship. Our study focuses on one of the variables usually held constant—climate—by examining hornblende etching and quartz/feldspar ratios in soils of similar age but varying degrees of development due to climatic factors. We examined the assumption that the degree of etching varies as a function of soil development, even in soils of similar age. The Spodosols we studied form a climate-mediated development sequence on a 13,000-yr-old outwash plain in Michigan. Their pedogenic development was compared to weathering-related data from the same soils. In general, soils data paralleled weathering data. Hornblende etching was most pronounced in the A and E horizons, and decreased rapidly with depth. Quartz/feldspar ratios showed similar but more variable trends. In the two most weakly developed soils, the Q/F ratio was nearly constant with depth, implying that this ratio may not be as effective a measure as are etching data for minimally weathered soils. Our data indicate that hornblende etching should not be used as a stand-alone relative age indicator, especially in young soils and in contexts where the degree of pedogenic variability on the geomorphic surface is large.