Geostatistical estimation of chemical contamination in stream sediments: The case study of Vale das Gatas mine (northern Portugal)

Based on an environmental geochemistry case study carried out in the neighbourhood of a W–Sn abandoned mine, the pollution in stream sediments was modelled through a Global Contamination Index. Such an index permits one to summarize the combination of deleterious elements in a single variable, obtained by the projection of samples onto the first axis of a PCASD (Principal Components Analysis of Standardized Data) applied to the entire n × p matrix containing the available concentrations of p = 16 elements in the set of n = 220 collected samples.In order to provide a sound basis for a coherent planning of the remediation process which will be put in operation in the affected area, it is necessary to balance the costs of reclaiming with the probabilities of exceeding the upper limits accepted for concentrations of environmentally harmful elements in sediments. Given these limits, they are back-transformed in the index values, providing a practical threshold between ‘clean’ and ‘contaminated’ samples. On the other hand, the minimum dimension of the cell to be reclaimed is restrained by the selected remediation process to be applied in the affected area. Hence, to meet the constraints of such a remediation process, it is required to estimate the probabilities of exceeding the index threshold in technologically meaningful sub-areas. For this end, the Indicator Block Kriging technique was applied, producing a series of maps where sub-areas to be reclaimed can be spotted for different probability levels. These maps, on which the decision making remediation agency can rely for its cost-benefit analysis, take into account both the spatial structure of ‘clean’ vs. ‘contaminated’ samples and the constraints of the reclaiming process.     

Monazite behaviour and age significance in poly-metamorphic high-grade terrains: A case study from the western Musgrave Block, central Australia

Integrated, in situ textural, chemical and electron microprobe age analysis of monazite grains in a migmatitic metapelitic gneiss from the western Musgrave Block, central Australia has identified evidence for multiple events of growth and recrystallisation during poly-metamorphism in the Mesoproterozoic. Garnet + sillimanite-bearing metapelite underwent partial melting and segregation to palaeosome and leucosome during metamorphism between 1330 and 1296 Ma, with monazite grains in leucosome recording crystallisation at 1300 Ma. Monazite breakdown during melting is inferred to have occurred in the palaeosome. During a subsequent granulite facies event at 1200 Ma, deformation and metamorphism of leucosome and palaeosome resulted in partial disturbance of ages and potential minor growth on 1300 Ma monazite in leucosome. Growth of new, high-Y (+HREE) monazite in palaeosome domains occurred during garnet breakdown in the presence of sillimanite to cordierite and spinel, as a result of post-peak isothermal decompression. Diffusive enrichment of resorbed garnet rims in Y + HREE suggests garnet breakdown occurred slower than volume diffusion of REE. Monazite in both palaeosome and leucosome were subsequently partially to penetratively recrystallised during a retrogression event that is suggested to have occurred at 1150–1130 Ma. The intensity of recrystallisation and disturbance of ages appears linked to proximity to retrogressed garnet porphyroblasts and their occurrence in the relatively reactive or ‘fertile’ local environments provided by the palaeosome/mesosome volumes, which caused localised changes in retrogressive fluids towards compositions more aggressive to monazite. Like reaction textures, it is apparent that domainal equilibrium and reaction may control or at least strongly influence monazite REE and U–Th–Pb chemistry and hence ages.     

五里冲水库--治理和利用喀斯特溶洞的范例

滇南蒙自五里冲水库，系充分利用盲谷地形、地下隐蔽喀斯特大厅、地下暗河等自然条件，扬长避短，通过明堵暗灌、高压灌浆、构建防渗帷募等特殊综合工程手段建造的无大坝型水库。该区地质情况复杂，喀斯特十分发育，先后投入大量钻探、平硐及基础地质调查工作量，采和合适的防漏、防渗工程。1996年竣工下闸蓄水后水位持续上升，达到设计要求，为蒙自工农业经济发展提供条件，亦为在我国南方复杂喀斯特地区构建大、中型水库闯出新路。     

Origin and tectonic significance of a Mesozoic multi-layer over-thrust system within the Yangtze Block (South China)

In the Yangtze Block (South China), a well-developed Mesozoic thrust system extends through the Xuefeng and Wuling mountains in the southeast to the Sichuan basin in the northwest. The system comprises both thin- and thick-skinned thrust units separated by a boundary detachment fault, the Dayin fault. To the northwest, the thin-skinned belt is characterized by either chevron anticlines and box synclines to the northwest or chevron synclines to the southeast. The former structural style displays narrow exposures for the cores of anticlines and wider exposures for the cores of synclines. Thrust detachments occur along Silurian (Fs) and Lower Cambrian (Fc) strata and are dominantly associated with the anticlines. To the southeast, this style of deformation passes gradually into one characterized by chevron synclines with associated principal detachment faults along Silurian (Fs), Cambrian (Fc) and Lower Sinian (Fz) strata. There are, however, numerous secondary back thrusts. Therefore, the thin-skinned belt is like the Valley and Ridge Province of the North American Applachian Mountains. The thick-skinned belt structurally overlies the thin-skinned belt and is characterized by a number of klippen including the Xuefeng and Wuling nappes. It is thus comparable to the Blue Ridge Province of Appalachia.The structural pattern of this thrust system in South China can be explained by a model involving detachment faulting along various stratigraphic layers at different stages of its evolution. The system was developed through a northwest stepwise progression of deformation with the earliest delamination along Lower Sinian strata (Fz). Analyses of balanced geological cross-sections yield about 18.1–21% (total 88 km) shortening for the thin-skinned unit and at least this amount of shortening for the thick-skinned unit. The compressional deformation from southeast to northwest during Late Jurassic to Cretaceous time occurred after the westward progressive collision of the Yangtze Block with the North China Block and suggests that the orogenic event was intracontinental in nature.     

对下扬子与华南边界结合带东延问题的地球物理探讨

以江山-绍兴、铅山-宜春等断裂带作为华南与扬子块体之间的边界结合带，这种认识目前已基本为大家所接受．但是，这条边界结合带向东延伸入海之后的位置与去向一直是多年来研究的热点．本文基于黄、东海研究区的地球物理数据(空间重力数据、布格重力数据和地震层析成像结果)，利用方向导数等处理方法，对研究区的地球物理数据进行处理，并对研究区的地球物理场进行了分析，划分出不同的区块．结合研究区的磁力与地质资料，利用各种成图、成像技术，形成一系列分析图件．在此基础上对华南与扬子块体之间的边界结合带进行了追踪．研究结果认为：该结合带的位置有可能比传统认识中自长江口至大黑山群岛的位置更向南一些，在杭州湾-长崎、对马海峡一线，并呈现向北略微凸出的弓形．边界结合带在深度上属于深大断裂带，一直可以追索到上地幔的顶部．与中朝与扬子块体之间的边界结合带相比较，本条结合带的踪迹不是十分清晰．表明加里东运动之后，该结合带的运动明显减弱．     

Timing and exhumation of eclogite facies shear zones, Musgrave Block, central Australia

Timing constraints on shear zones can provide an insight into the kinematic and exhumation evolution of metamorphic belts. In the Musgrave Block, central Australia, granulite facies gneisses have been affected, to varying degrees, by mylonitic deformation, some of which attained eclogite facies. The Davenport Shear Zone is a dominant strike-slip system that formed at eclogite facies conditions ( T  ≈650  °C and P ≈12.0  kbar). Sm–Nd mineral isochrons obtained from equilibrated high-pressure assemblages, as well as ⁴⁰Ar–³⁹Ar data, show that the eclogite and greenschist facies high-strain overprints were coeval, at c .  550  Ma. Mylonitic processes do not appear to have reset the U–Pb system in zircon, but may have partially disturbed it. The thermal gradient in the Musgrave Block crust at c .  550  Ma was c .  16  °C  km⁻¹ and at c .  535  Ma was c .  18  °C  km⁻¹, based on P – T  estimates of eclogite and greenschist facies shear zones, respectively. These estimates are similar to present-day geothermal gradients in many stable continental shield areas, suggesting that the region did not undergo a significant transient perturbation of the geotherm. Therefore, in the Musgrave Block, cooling subsequent to eclogite facies metamorphism appears to have been controlled by exhumation, rather than by the removal of a heat source. Estimated exhumation rates in the range 0.2 to ≥1.5  mm year⁻¹ are comparable with other orogenic belts, rather than cratonic areas elsewhere.     

中朝板块元古宙板内地震带与盆地格局

地史中发生的强地震事件在地层中留下固定的记录 (图 1～ 3) ,这些记录在区域上呈带状分布 ,代表地史中的地震带。中朝板块元古宙目前可识别出两个板内地震带 (图 5 )。中元古代板内地震带 (170 0～ 12 0 0Ma)西起太行山北段 ,经燕山山脉、辽宁西部、穿越辽河平原至辽宁北部的泛河流域分布 ,即燕山—泛河地震带 ,现今呈NEE向延伸。新元古代震旦纪地震带沿吉林南部、辽东半岛、山东中部及苏皖北部现今呈NNE走向分布 ,即古郯庐地震带 (6 5 0～ 6 0 0Ma)。上述两个板内地震带是元古宙不同时期超大陆裂解的响应。中元古代与新元古代两个不同方向的地震断裂带分别控制着两个时期的盆地边界。燕山泛河地震断裂带构成中元古代海盆南界 (指现在的位置 ) ,形成向北开放的海域。古郯庐地震断裂带将中朝板块裂解为华北块体与胶辽朝块体。古郯庐地震断裂带构成震旦纪海域的边界 ,震旦纪海盆通过朝鲜半岛与当时的外海相连接 ,华北块体则为陆源剥蚀区。文内四幅古地理图 (图 6～ 9)是以地震灾变思想为指导 ,以新的地层研究、对比为基础编制的 ,侧重反映了盆地的格局及其变化。根据地震、同沉积断裂新的思路 ,可提供地质学家重新认识与解释某些沉积矿床的成因 ,它们的成矿元素均来自地球深部而非地表风化作用。文中编制