The contribution of throughflow to storm runoff: An evaluation of a chemical mixing model

The contribution of throughflow to storm runoff is examined using a chemical mixing model. The results predict that throughflow is an important component of storm runoff particularly during the period of stream recession. Supporting hydrological data suggests that a major throughflow input occurs coincident with the stream discharge peak. The two sets of results therefore conflict in the predicted timing of the throughflow response.     

Soil water residence times and solute uptake on a dolomite bedrock—preliminary results

Calcium and magnesium levels have been monitored in slope foot drainage waters on a dolomite bedrock. Both calcium and magnesium rich pulses occur. Short term dissolution experiments demonstrate high calcium levels in solution while other authors have suggested that long residence time groundwater has relatively high levels of magnesium due to calcite precipitation. Patterns of field fluctuations in Ca: Mg ratios can thus be tentatively interpreted in terms of short residence time water of high calcium content mixing with long residence time water of high magnesium content. Fluorometric dye tracing has been used to indicate the orders of magnitude of soil water residence times, suggesting that quickflow components are resident in the system for a few hours to a few days. Further work is in progress.     

水位波动下的呼伦湖上覆水体与沉积物间隙水之间溶质的运移特征

为了探求内蒙古呼伦湖上覆水体和沉积物间隙水之间溶质运移机制,对呼伦湖的1个沉积物柱芯的间隙水、3个湖泊水体以及湖周边7个地下水体中的氯离子(Cl~-),氢、氧稳定同位素(δD和δ~(18)O)分别进行分析测试,并利用其示踪性对沉积物中溶质运移特征进行研究.结果显示,δD、δ~(18)O和Cl~-浓度在不同水体中的分布具有相似的分布规律,整体上从底部沉积物到上部湖水浓度分布呈现逐渐递减的抛物线趋势,在间隙水中最大值位于所取沉积物柱芯的最深处,Cl~-浓度为306 mg/L,δD和δ~(18)O分别为-58‰和-5.9‰;最小值位于沉积物柱芯上层,并与上覆水体中的值相似,Cl~-浓度为159 mg/L,δD和δ~(18)O分别为-66‰和-7.3‰.为了明确沉积物柱芯中间隙水的高浓度Cl~-和偏正δD、δ~(18)O的来源,比较不同水体的δ~(18)O-δD关系点分布,表明含有偏正值的δD、δ~(18)O和高浓度Cl~-的间隙水与上覆湖水关系密切,可能是由于低水位时期湖水与间隙水相互发生扩散作用而产生的结果.一维对流扩散迁移模型证实扩散作用是控制着沉积物间隙水中溶质浓度在垂向上分布的主要机制,同时湖水水位的变化会影响沉积物间隙水与上覆水体的扩散过程,特别是在水位上升期,富集在沉积物中的溶质可能成为湖水的重要物质来源,影响上覆水体的水质.因此,对于封闭湖泊水位的控制和管理不仅在维持湖泊水量方面有着直接的作用,同时在稳定湖泊水质条件上也有着重要的意义.     

A study on functional and structural traits of the nocturnal flowers of Capparis spinosa L.

Functional and structural traits of the Capparis spinosa flower were studied in order to understand the mechanisms that allow this species to flower during the dry summer in the Mediterranean. Stomata were found on the abaxial surface of sepals, and on both the adaxial and abaxial surfaces of petals. Filaments and style were densely packed with small cells, exhibiting an increased density of cell wall material that provides strength. Petals possessed vacuolated parenchyma cells with large intercellular space. Turgor of petals was sustained mainly due to a decline in solute potential during the night and to a rise in water potential and solute potential at sunrise, concomitantly with a decrease in solute accumulation. Estimates of total sugars made in floral tissues of nine successive flowers along newborn stems were 100-fold higher than those of proline accumulation. Unsaturated fatty acids were identified as major components of lipids in petals, thereby influencing the fluidity of membranes.     

Sources of dissolved solids and water in Wadi Al Bih aquifer,Ras Al Khaimah Emirate,United Arab Emirates

Regional brines that underlie the potable groundwater appear to be responsible for the increase in dissolved solids in the Wadi Al Bih aquifer in the Ras Al Khaimah Emirate, United Arab Emirates. In this karstic carbonate aquifer, groundwater extraction exceeds recharge and the reduced heads can induce transport of underlying brines into the potable water aquifer. Increasing dissolved solids with time threatens the continued use of groundwater for agricultural and domestic uses. The potential of intrusion of seawater, dissolution of minerals, or intrusion of regional brines as a source of these solutes were evaluated based on groundwater samples collected in April and September 1996 from the Wadi Al Bih well field and isotope data from previously collected samples. Hydrogeologic conditions and solute modeling suggest the dominant source of solutes in the Wadi Al Bih aquifer is most likely an underlying regional brine. The pervasive presence of tritium is consistent with recent (since 1960s) recharge in the drainage basin, thus, the solutes and water appear to be from different sources. The chemical and isotopic data are also consistent with enhanced groundwater recharge associated with dams constructed to reduce flooding.

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Résumé Dans l’aquifère de Wadi Al Bih, dans l’Emirat de Ras Al Khaimah (Emirats Arabes Unis), les eaux sursalées présentes sous les eaux souterraines potables paraissent responsables de l’augmentation en solides dissous. Dans cet aquifère carbonaté karstique, l’exploitation des eaux souterraines est supérieure à la recharge, et la baisse des niveaux piézométriques peut engendrer une remontée des eau sursalées vers la ressource en eau potable. L’augmentation des solides dissous dans le temps met en danger la pérennité de l’utilisation des eaux souterraines pour l’agriculture et les besoins domestiques. Les potentiels de l’intrusion d’eau de mer, de la dissolution des minéraux et de l’intrusion d’eaux sursalées régionales en tant que sources de ces solutés ont été évalués sur la base d’échantillons prélevés en avril 1996 sur le champ captant de Wadi Al Bih, et de données isotopiques acquises antérieurement. Les conditions hydrogéologiques et les modélisations de solutés suggèrent que la source majeure des solutés la plus vraisemblable est une eau sursalée sous-jacente à l’échelle régionale, dans le cas de l’aquifère de Wadi Al Bih. L’omniprésence du tritium concorde avec une réalimentation récente (depuis les années 1960) sur le bassin versant, c’est pourquoi l’eau et les solutés paraissent provenir de sources différentes. Les données chimiques et isotopiques concordent également avec une réalimentation accrue des eaux souterraines, liée à la construction récente de digues pour réduire les inondations.

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Resumen El incremento de sólidos disueltos en el acuífero Wadi Al Bih, en el Emirato Ras Al Khaimah, Emiratos árabes Unidos, parece deberse a la existencia de salmueras regionales, subyacentes a las aguas subterráneas potables. En este acuífero carbonatado kárstico, la extracción de agua subterránea supera la recarga y el descenso de niveles puede provocar el transporte de las salmueras hacia las aguas potables del acuífero. El incremento temporal en sólidos disueltos amenaza el uso continuo de agua subterránea para usos agrícolas y domésticos. Se ha evaluado el potencial de intrusión marina, disolución de minerales o intrusión de salmueras regionales como una fuente de estos solutos, a partir de muestras de agua subterránea recogidas en abril y septiembre de 1996 en el campo de pozos de Wadi Al Bih y de datos isotópicos de muestreos anteriores. Las condiciones hidrogeológicas y el modelo de solutos sugiere que la fuente dominante de solutos en el acuífero Wadi Al Bih son probablemente las salmueras subyacentes. Los datos químicos e isotópicos son también consistentes con un aumento de la recarga de agua subterránea asociado con la construcción de presas para reducir inundaciones.

     

Solute concentrations in the lower niger river and the source rock contribution

Water quality analyses for the Niger River for the 1980/81 hydrological year are presented. The samples were collected from the main river at Lokoja, and from two main tributaries, the Kaduna and the Benue Rivers. Different water types were distinguished by the concentrations of major ions. The type Ca > Na > Mg > K - HCO₃ > SO₄ > Cl was represented at all stations during at least part of the year. Chloride was found to dominate the sulphate ion in the Kaduna and Niger, while the Benue maintained a higher concentration of sulphate relative to chloride all year round. Distinct patterns of seasonal variation in the ion concentrations were observed, particularly for the samples collected at Lokoja. Low ion concentrations were prominent during periods of high discharge, while low flow periods coincided with high dissolved ion concentrations. The contribution of rainwater to the total dissolved solids in the river waters was assessed indirectly using rainwater chemistry data from the Gulf of Guinea. The estimated rainwater contribution to the Lower Niger amounts to 5.15 mg 1^?1. Geochemical weathering calculations involving reactions of the four major minerals of granitic rocks - anorthite, biotite, albite, and K-feldspar - with carbon dioxide and water, can account for the average water composition of the Lower Niger. The proportion of the ionic components was also related to the occurrence of the respective element in the minerals.     

Solute dynamics of meltwater of Gangotri glacier,Garhwal Himalaya,India

The present study investigates solute dynamics of meltwater of Gangotri glacier system in terms of association of different chemical compounds with the geology of the area. In the meltwater, the presence of cations varied as c(Mg²⁺) > c(Ca²⁺) > c(Na⁺) > c(K⁺), while order of concentration of anions has been c(HCO₃ ⁻) > c(SO₄ ²⁻) > c(Cl⁻) > c(NO₃ ⁻) in years 2003 and 2004. The magnesium and calcium are found as the dominant cations along with bicarbonate and sulphate as dominant anions. The high ratios of c(Ca²⁺ + Mg²⁺)/total cations and c(Ca²⁺ + Mg²⁺)/c(Na⁺ + K⁺) indicate that the meltwater chemistry of the Gangotri glacier system catchment is mostly controlled by carbonate weathering. Attempts are made to develop rating curves for discharge and different cations. Sporadic rise in discharge without corresponding rise in concentration of most of cations is responsible for their loose correlation in a compound valley glacier like Gangotri glacier.     

Soil pipes and their role in runoff generation and chemical denudation in a humid tropical catchment in dominica

Numerous soil pipes are reported from a small catchment in an area of kandoid (kaolin-rich) soils and 2375 mm annual rainfall in the humid tropical volcanic island of Dominica, West Indies. Two spot surveys in August 1982 at baseflow during the wet season indicated that pipes contributed at least 14–16 per cent of streamflow. Sampled pipeflow was of similar chemical composition to the baseflow-dominated streamwater. Specific conductance (249–420 μS cm^?1) and silica (75 mg l^?1) levels of pipeflow were high and suggested that the pipes tapped solute-rich water close to the soil-rock interface. The principal pipes flow perennially and showed little response to daily rainfalls of up to 43 mm during the monitoring period.     

The relationship between throughflow generation and the solute concentration of soil and stream water

Variation in solute concentrations of soil and stream water during throughflow events was studied at Bicknoller Combe, Somerset, England. The main hydrological process acting in the catchment involves a delayed throughflow discharge pulse a day or two after the rainfall event. During the period of storm runoff, coincident with the rainfall, the solutes in the stream are diluted, but their concentration in the throughflow remains unchanged. During the delayed throughflow pulse, concentrations of both soil and stream water increase. This is due to additional leaching from the soil in hollows where saturated moisture conditions prevail. The results suggest that two distinct erosional environments may exist: on the spurs, leaching seems to be related solely to infiltration processes, whilst in the hollows, saturated throughflow also contributes to the solute removal. This contrast in erosional processes may perhaps account for the difference in slope form and development between the hollow and spur zones.     

Watershed geochemistry: The control of aqueous solutions by soil materials in a small watershed

Laboratory and field data indicate that the aqueous geochemistry of a small watershed in siliceous materials is largely determined by reactions between soil and water. For dissolved SiO₂, Ca⁺², K⁺, Na⁺, a reversible steady state is achieved in the soil within hours. The solute concentrations are in equilibrium with kaolinite, the end-product in the local weathering sequence. The processes occur in a drainage basin in which solution activities are the predominant form of erosion.