硫化锑溶胶的电动电位研究

溶胶的电动电位是溶胶发生电动现象的主要原因,它的大小直接影响溶胶的稳定性。本文采用界面移动法研究了溶胶的浓度,电极的种类以及不同的辅助液和硫化锑溶胶的电动电位之间的关系。     

钛酸锶的掺杂研究

采用溶胶 -凝胶方法 ,以 Co(AC) 2 、Zn(AC) 2 、Mg(AC) 2 、Ca(AC) 2 、Y2 O3、L a2 O3为掺杂物 ,对 Sr Ti O3进行了掺杂研究 ,研究结果表明 ,以醋酸盐为掺杂物所制得的样品 ,分散开的颗粒近似呈球形 ,粒径约为5 0 nm ,主相是 Sr Ti O3;以氧化钇为掺杂物所制得的样品 ,颗粒明显呈六边形 ,粒径约为 2 5 0 nm。各样品的阻温曲线显示 ,室温电阻率可达 10 6 欧姆·厘米。各样品的表征都是基于 XRD分析、TEM分析     

Morphodynamic interactions of continental shelf,beach and dunes: the Cabopino dune system in southern Mediterranean Spain

The complex morphodynamic interactions between nearshore, shoreface and dune systems are usually simplified by studying these zones and their associated processes in isolation. However, the established relationships between each of them suggests that an integrated approach is required to examine the genesis, evolution and adaptation of the entire morphodynamic system. The Cabopino dune system in the southern Spanish Mediterranean Sea provides a clear example of a linked morphodynamic system in which a relatively large dune system has been generated and grown through the supply of sediments from an adjacent littoral supply environment. Here, we present a conceptual model of how the nearshore has provided suitable conditions for beach and dune development. We purport that synchronization of sediment activation in the marine and aeolian sections of the system have played a major role in this microtidal setting in which temporal aspects are not only tied to storm action, but to large sedimentary features moving alongshore. © 2019 John Wiley & Sons, Ltd.     

Reconstitution des apports en éléments traces métalliques et bilan de leur migration dans un Luvisol sableux soumis à 100 ans d'irrigation massive par des eaux usées brutes

Raw wastewaters were massively spread on sandy luvisols near Paris from 1899 to 2002, leading to high trace metals (TM) pollution of soils. Mass balance calculations were performed on a soil profile to assess vertical migration of TM. The contamination was estimated by subtracting the natural pedo-geochemical background of the horizons. TM inputs were estimated using Cr as an invariant. It is shown that Pb and Cr remained in the surface horizon, while Ni, Cd, Cu and Zn migrated downward, being more or less trapped depending on the physicochemical properties of the horizons. To cite this article: C. Dère et al., C. R. Geoscience 338 (2006).     

Mediterranean dune vegetation: conservation of a threatened ecosystem in southern Spain

This paper investigates the plant diversity and current state of the vegetation of a little-known threatened dune complex located in Estepona (southern Spain). This littoral fringe has in the past 60 years experienced a continuous process of intensive occupation derived primarily from tourism and agriculture, which has led to the degradation of the fragile and dynamic coastal systems. Its diminished size and lack of legal protection make it vulnerable to a variety of anthropogenic stresses that threaten the survival of the system. Fieldwork has been the primary methodological procedure to conduct research, given the scarcity of previous studies. The results first of all provide a biogeographical and phytosociological view that elucidates the remarkable plant diversity of the area studied and the complete zonal structure of the communities that comprise the ecosystem. Secondly, a vegetal cartography was created (detail of 1: 2500) to characterize the distribution of flora. This exploration and mapping of vegetation are effective tools in forming a conservation proposal to combat anthropogenic conflicts that destabilize the system. In this sense, harmful human activities threatening the plant phytodiversity of the various strips of vegetation forming the dunes have also been identified.     

Post-cropping change and dynamics in soil and vegetation properties after forest clearing: Example of the semi-arid Mikea Region (southwestern Madagascar)

This study concerns post-cultural dynamics in the semi-arid South-West of Madagascar (Analabo area, near the Mikea Forest). A synchronic comparison was performed on a set of abandoned fields plots aged from 2 to 30 years and on forest and savanna reference ecosystems, located on cambic arenosols developed from same Quaternary dune sands. The studied parameters concerned mainly a few physical and chemical soil properties (density, permeability, compaction, texture, C, N, K, P content). Important changes occur in the post-cultural succession: an increase of the soil density and compaction, and decrease of the soil upper layer permeability. Consequently, slash and burn cultivation leads to a packing and an induration of the soil surface. Results about edaphic indicators have shown that the physical parameters used better discriminate various stages of evolution than the chemical parameters do. The multivariate analysis of soil indicators shows that vegetative succession over 30 years in a forest ecosystem cleared, burnt, cultivated and left, does not lead to features corresponding to a closed-canopy forest but rather to those of a tree savanna with open, mixed woody-herbaceous vegetation. The primary dense dry deciduous regeneration of the primary forest is very low or nil. In the semi-arid SW Madagascar (Analabo region), post-cultural dynamics conditions consists in a savanna-formation process, controlled by: (1) the intensity and duration of the disturbance (during the cultivation phase); and (2) the more drastic environmental conditions (including both climate and soil).     

Development of Easy and Reproducible Immobilization Techniques Using TiO2 for Photocatalytic Degradation of Aquatic Pollutants

Two main routes of methods for the preparation of photocatalytic active titanium dioxide films on glass substrates were investigated: (1) the use of titanium dioxide powder and (2) the in situ generation of the catalyst via hydrolysis of titanium tetraisopropoxide (TTIP) or TiCl₄. The activities of the catalyst films were evaluated by measuring the degradation of dichloroacetic acid (DCA), clofibric acid, and terbuthylazine used as model organic compounds. The concentration decrease of DCA and the concentration increase of chloride ions as the decomposition product allowed to distinguish between photocatalytic degradation of DCA and adsorption onto the TiO₂ films. Furthermore, TiO₂ films of the commercially available materials P25 (Degussa) and Hombikat UV100 (Sachtleben Chemie) were used to investigate whether there was a difference in the degradation pathways of terbuthylazine as a model compound. For the experiments mini flow‐through reactors were constructed. The investigated immobilization techniques were easy to handle without need of any expensive equipment. All TiO₂ coatings showed good photocatalytic activities and mechanical stabilities with efficient long‐term stabilities. The best immobilization reproducibility was achieved by the spray coating technique and by the in situ method with the dipping sol‐gel process starting by TTIP. During the continuous use of the TiO₂ films no TiO₂ particles were found in the irradiated solutions.     

A study of dissipation of wind-waves by mud at Cassino Beach,Brazil: Prediction and inversion

The impact of a non-rigid seafloor on the wave climate at Cassino Beach, Brazil, May–June 2005 is studied using field measurements and a numerical wave model. The measurements consist of wave data at four locations; rheology and mud thickness from grab samples; and an estimate of the horizontal distribution of mud based on echo-soundings. The dissipation of waves by a non-rigid bottom is represented in the wave model by treating the mud layer as a viscous fluid. Applied for 431 time periods, the model without this type of dissipation has a strong tendency to overpredict nearshore wave energy, except during a period of large storm waves. Two model variations which include this dissipation have a modest tendency to underpredict the nearshore wave energy. An inversion methodology is developed and applied to infer an alternate mud distribution which, when used with the wave model, yields the observed waveheights.     

溶胶-凝胶法的技术进展与应用现状①

溶胶-凝胶法是一种在较低温度下即可得到希望的化合物的 新 方法。简述了溶胶-凝胶法的基本原理,总结了溶胶-凝胶技术发展现状,着重介绍了溶胶 -凝胶技术在制备块状、纤维、涂层和薄膜、超细粉末及复合材料方面的应用现状。