河北寿王坟铜矿碳-氧同位素地球化学特征及其意义

系统研究寿王坟矿区矽卡岩型矿石和斑岩型矿石中热液成因碳酸盐矿物的碳免同位素组成，结合矿区蚀变白云质围岩地层碳免同位素组成特征，提出：1)尽管矽卡岩矿床产在碳酸盐地层与中酸性侵入体的接触带上，是碳酸盐地层受热液交代作用的产物，但矽卡岩矿石中热液碳酸盐矿物的碳同位素组成却主要反映了深部岩浆(甚或地馒)来源碳的特征，基本可以排除沉积碳酸盐的碳大规模加入的可能性。2)寿王坟矿田对应着一个与高侵位岩浆岩有关的热液成矿系列，其浅部的下渗大气降水加热环流体系和深部上升的岩浆热液体系，均能在不同部位通过系统的碳免同位素地球化学研究加以揭示。作为矿山开采主体的矽卡岩型矿体和部分斑岩型矿体都是上升岩浆热液(甚或更深的馒源流体)的产物。     

矿产资源地球化学定量预测在蓟县夕卡岩型铜矿中的应用

蓟县北部山区具有良好的夕卡岩型铜矿成矿条件,与河北省兴隆县寿王坟夕卡岩型铜矿具有相似的成矿模式。选取寿王坟铜矿作为蓟县夕卡岩型铜矿研究的典型矿床,参照矿产资源地球化学定量预测方法技术,计算出盘山预测区的剥蚀系数约为0.7,石臼预测区的剥蚀系数约为0.5,属于中-深度剥蚀;盘山预测区和石臼预测区的相似系数均为0.74,采用考虑剥蚀系数的面金属量法计算了蓟县夕卡岩型铜矿的预测资源量。     

燕山地区寿王坟杂岩体锆石U-Pb年代学、Hf同位素和地球化学特征及其地质意义

燕山地区寿王坟杂岩体由石英闪长岩、石英二长岩组成。LA-ICP-MS锆石U-Pb年代学研究表明,石英闪长岩和石英二长岩形成于(128±1) Ma,是早白垩世岩浆活动的产物。对比区域岩浆作用特点显示,研究区岩浆作用与华北克拉通东部大规模岩浆活动时代相近。寿王坟杂岩体富碱(Na2O+K2O含量为8.48%~9.06%(质量分数),属钾玄质系列(K2O 3.87%~4.96%)、准铝质岩石(A/CNK=0.69~0.89,A/NK=1.19~1.35),富集Rb、Ba、Sr等元素,亏损Nb、Ta、Th、P等元素,具高Sr((684~1 018)×10-6)和Ba((1 163~1 506)×10-6)、高Sr/Y(43~102)和La/Yb(31~91)比值、低Y((7.19~16.55)×10-6)和Yb((0.47~1.28)×10-6)、富集LREE、基本无Eu异常等特征。εHf(t)值较低,石英闪长岩εHf(t)=-18.1~-11.1,石英二长岩εHf(t)=-18.6~-13.2。研究认为寿王坟杂岩体主要形成于早白垩世古太平洋板块向欧亚大陆俯冲背景下的伸展环境,来源于古元古代地壳物质的部分熔融,并有不同程度富集地幔的贡献。Sr/Y值与SiO2含量呈正相关表明其不具源区特征,主要是岩浆在侵位过程中富水岩浆分异演化发生角闪石等矿物的结晶分异作用造成的。     

Early cretaceous igneous activities in the north flank of the North China Craton: the Shouwangfen complex example

ABSTRACT

The Early Cretaceous igneous complexes in the north flank of the North China Craton (NCC) provide a window to investigate the Mesozoic magmatism in the NCC. Here we report the precise timing of Early Cretaceous magmatism and magma petrogenesis of the different rock types in the north flank of the NCC based on petrology, mineral chemistry, geochemistry, zircon geochronology and Sr-Nd isotopes. Zircon U-Pb dating reveals that the Shouwangfen complex was crystallized at 130–128 Ma. The rocks display enrichment in large ion lithophile elements (LILE) and LREE, and depletion in high field strength elements (HFSE) and HREE, with relatively high Sr/Y and La/Yb values, typical of subduction-related magmatic rocks. The mafic microgranular enclaves show typical igneous textures, acicular apatites, sieve-texture of plagioclase phenocrysts and overgrowth of amphibole around the pyroxene, corresponding to magma mixing and mingling and thermal exchange. The quartz monzonites display normal zoning of the plagioclase, low and homogeneous εNd(t) values and linear co-variations in two-component diagrams. The quartz monzodiorites are characterized by high and homogeneous εNd(t) values. Petrologic feature and geochemical data suggest that the quartz monzonites represent lower crustal magma with minor contribution of enriched melt of the sub-continental lithospheric mantle (SCLM), followed by fractional crystallization. The mafic microgranular enclaves were sourced from enriched SCLM, followed by mixing and mingling with the host quartz monzonitic magma. The quartz monzodiorites are mainly SCLM-derived and subsequently mixed with lower crust melts. The high water contents (≥3%) of these Early Cretaceous igneous complexes suggests a hydrous SCLM beneath the NCC. The Early Cretaceous igneous complexes formed within an extensional tectonic setting which were related to the retreat and dehydration of the paleo-Pacific slab. The hydration of the lithosphere induced extensive crust-mantle interaction and large-scale water-rich magmatism, leading to lithospheric thinning in the NCC during the Mesozoic.     

河北寿王坟花岗闪长岩中暗色微粒岩石包体的成因

暗色微粒岩石包体可以提供花岗岩浆的起源和演化、壳—幔物质及能量交换、岩浆混合等重要信息。河北兴隆寿王坟闪长质暗色微粒岩石包体及其寄主花岗闪长岩的岩石学、岩石地球化学特征显示了岩浆的混合成因,并具有以下特征:(1)在基性岩浆中丰度大于酸性岩浆中的不相容元素在与SiO2的相关图中呈一向上凸的弧形型式;(2)在基性岩浆中丰度小于酸性岩浆中的不相容元素在与SiO2的相关图中呈正相关的线性趋势;(3)相容元素在与SiO2的相关图中呈一负相关的线性趋势;(4)在w(La) w(La)/w(Sm)图上微粒包体与其寄主花岗闪长岩为一下凹的型式。基性岩浆与酸性岩浆的两端元岩浆的简单混合模型不能解释以上特征,可以用三阶段混合模型来解释,即第一阶段为基性岩浆注入酸性岩浆中,第二阶段为基性岩浆演化并分离结晶形成微粒包体,第三阶段为演化了的基性岩浆与酸性岩浆混合,形成寄主花岗闪长岩。     

河北寿王坟铜矿黄铜矿铷锶同位素年龄测定及其成矿意义

本文以黄铜矿及其共生矿物为定年对象,采用亚样品取样和铷锶等时线定年方法测定了寿王坟铜矿的成矿时代.分析测试获得黄铜矿 黄铁矿单矿物组合的等时线年龄113.6Ma,黄铜矿 夕卡岩组合的等时线年龄112.3Ma和黄铜矿 黄铁矿 夕卡岩组合的等时线年龄115.0Ma.对比同一矿石亚样品,认为河北寿王坟夕卡岩型铜矿成矿时代为111.0Ma.实验表明,采用矿石亚样品取样方法和直接测定金属硫化物单矿物铷-锶同位素年龄可以有效地确定矿床成矿时代.