几丁糖酯原料药稳定性研究

该文建立高效凝胶渗透色谱法 (HPGPC) ,明胶比浊法 ,氧瓶燃烧法三种分析方法考察海洋硫酸多糖药物几丁糖酯的稳定性 ,采用这三种方法分别考察几丁糖酯原料药在高温、高湿、强光照射及加速条件下分子量及分布宽度、样品中硫酸根含量及样品含量的变化情况。结果表明 :三种方法均适用于几丁糖酯的稳定性考察 ,几丁糖酯在上述影响因素条件下稳定性良好     

Interactive behavior of soil–pile-superstructure system in transient state to liquefaction by means of large shake table tests

Shaking table tests were conducted by means of a large-scale laminar box with 4 m in length, 2 m in width and 2 m in height in order to investigate behavior of a soil-pile-superstructure system in liquefiable ground. A model two-storey structure, supported by a pile group, was set in a saturated sand deposit, and subjected to a sinusoidal base motion with increasing amplitude. Discussions are focused on the transient behavior until soil liquefaction occurs. Main interests are characteristics of springs used in a sway-rocking model and a multi-freedom lumped mass (MFLM) model that are frequently used in soil–pile interaction analysis. The spring constant in the sway-rocking model is represented by restoring force characteristics at the pile head, and that in the MFLM system is represented by an interaction spring connecting the pile to the free field. The transient state prior to soil liquefaction is shown to be important in the design of a pile because dynamic earth pressure shows peak response in this state. The reduction of the stiffness due to excess porewater generation and strain dependent nonlinear behavior is evaluated.     

高频GNSS形变波的震相识别：模拟实验与实例分析

高频GNSS震时形变波震相及识别是GNSS地震学的重要内容.在实时数据处理基础上,本文利用振动台的高频GNSS观测实验,并结合近期部分大震的高频GNSS形变波震相特征进行研究.数据处理结果表明,实时处理与事后处理的精度在同一量级,且与采样率无关.通过与同址观测强震仪和地震计记录的对比及特定震相的频谱分析,发现高频GNSS可完整记录P波、S波、Love波及Rayleigh波震相,影响震相记录的主要因素是GNSS定位精度与震级,而仅当震中距很小时,采样率将产生一定影响.研究结果得出：基于地震波传播规律,利用高频GNSS台阵记录的形变波空间分段特征,结合震相运动轨迹及其他地震波记录,可实现实时高频GNSS形变波的震相识别.     

Shake table tests of a new steel–asphalt composite layer system for the seismic base isolation of housing units

Base isolation is an effective way to reduce earthquake energy transfer from ground to structure, but existing seismic isolation systems are not very suitable for rural buildings for some reasons. A new steel–asphalt composite layer for the seismic base isolation of housing units is present in this paper. Its dynamic characteristics and isolation effect are studied by shake table tests of two full-scale specimens. Different earthquake waves with different peak ground accelerations (PGA, from 0.1 g to 0.4 g) are input. Test results show that the isolation layer could efficiently reduce the input acceleration. Moreover, as the PGA increase, the isolation layer shows good function of the displacement limit.     

地震计灵敏度的对比测量法

本文提出一种地震计灵敏度的对比测量法, 该方法将被测地震计和一台校准过的地震计比邻、 平行摆放, 共同记录地振动数据, 通过对比分析两台地震计的输出信号, 计算被测地震计的灵敏度。 与振动台测量法相比, 该方法成本低, 与电测法相比, 不需已知地震计的标定常数, 是一种简单易行、 精度高的地震计灵敏度测量方法。     

Prediction of pile response to lateral spreading by 3-D soil–water coupled dynamic analysis: Shaking in the direction perpendicular to ground flow

The 1995 Kobe earthquake seriously damaged numerous buildings with pile foundations adjacent to quay walls. The seismic behavior of a pile group is affected by movement of quay walls, pile foundations, and liquefied backfill soil. For such cases, a three-dimensional (3-D) soil–water coupled dynamic analysis is a promising tool to predict overall behavior. We report predictions of large shake table test results to validate 3-D soil–water coupled dynamic analyses, and we discuss liquefaction-induced earth pressure on a pile group during the shaking in the direction perpendicular to ground flow. Numerical analyses predicted the peak displacement of footing and peak bending moment of the group pile. The earth pressure on the pile in the crustal layer is most important for the evaluation of the peak bending moment along the piles. In addition, the larger curvatures in the bending moment distribution along the piles at the water side in the liquefied ground were measured and predicted.     

Nonlinear seismic soil–pile–structure interactions: Shaking table tests and FEM analyses

In this paper, a soil–pile–structure model is tested on a shaking table subject to both a sinusoidal wave and the acceleration time history of the scaled 1940 El Centro earthquake. A medium-size river sand is compacted into a 1.7-m-high laminar rectangular tank to form a loose fill with a relative density of 15%. A single-storey steel structure of 2.54 ton is placed on a concrete pile cap, which is connected to the four end-bearing piles. A very distinct pounding phenomenon between soil and pile is observed; and, the acceleration response of the pile cap can be three times larger than that of the structural response. The pounding is due to the development of a gap separation between soil and pile, and the extraordinary large inertia force suffered at the top of the pile also induces cracking in the pile. To explain this observed phenomenon, nonlinear finite element method (FEM) analyses with a nonlinear gap element have been carried out. The spikes in the acceleration response of the pile cap caused by pounding can be modeled adequately by the FEM analyses. The present results suggest that one of the probable causes of pile damages is due to seismic pounding between the laterally compressed soil and the pile near the pile cap level.     

中国4个国家级野外站大气CH4本底浓度变化特征

CH4是仅次于CO2的重要温室气体。2006年9月至2008年8月期间,按全球大气本底观测要求,在青海瓦里关、北京上甸子、浙江临安和黑龙江龙凤山4个国家级野外站开展每周一次空气样品flask瓶采样分析,获得了该地区为期2 a的大气CH4本底浓度资料。结果表明,2 a间瓦里关、上甸子、临安和龙凤山4站CH4浓度年均增幅分别为9.1×10-9、3.8×10-9、21.8×10-9和8.2×10-9;瓦里关站大气CH4浓度增长趋势与全球平均状况较为接近,能较好地反映北半球中高纬度内陆地区大气本底特征;但上甸子站年均本底值相对较低且季振幅偏小,而龙凤山和临安站季节变化规律相似,表现为CH4浓度冬季高而夏季偏低且季振幅较大。     

中国第二次北极科学考察路线上温室气体瓶采样结果分析

用气相色谱和非红外色散分析方法,分析了中国第二次北极科学考察路线上采集到的气体样品中温室气体(CO₂和CH₄)的浓度,对不同纬度带上CO₂和CH₄平均浓度变化特征进行了研究.结果表明:海洋表面不同纬度带上CO₂的浓度呈现出随纬度升高而减小的趋势,这与全球范围内CO₂的年平均浓度的地理分布特征相反,显示了海洋对CO₂气体的吸收作用.45°N以北的海洋表面,CH₄浓度有随纬度升高而增大的趋势,这与全球范围内CH₄的年平均浓度的地理分布特征相同;中纬度近海岸地区温室气体浓度变化无明显规律,可能受到区域或局地气团的影响较大.     

ESR谱仪低温杜瓦瓶的研制及其在矿物学研究中的应用

文章介绍了ＥＳＲ谱仪低温杜瓦差的研制原理和方法以及应用它在液氮温度下研究孔雀石中的Ｃｕ＾２＋和天然刚玉中Ｔｉ＾３＋存在形式的实验结果。