矿物的导电类型与矿物形成温度的关系

通过杂质对导电类型的影响的研究,得出了同种矿物的不同导电类型与矿物形成温度的规律:电子型(n型)导电矿物的形成温度大于电子与空穴混合型导电矿物的形成温度,又大于空穴型(p型)导电矿物的形成温度,绝缘体矿物的形成温度低于上述三种导电类型矿物。应用矿物热电图谱仪,天然金刚石半导体测试仪对闪锌矿、黄铁矿、金刚石等矿物的导电类型进行了测试,并探讨了导电类型成因,证实了上述规律的正确性。     

Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain)

Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of the Iberian Pyrite Belt. Concentrations were 19–994 mg kg⁻¹ for As, 41–4,890 mg kg⁻¹ for Pb, 95–897 mg kg⁻¹ for Zn and of 27–1,160 mg kg⁻¹ for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input, such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction. According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn, Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where the concentrations are not so high.     

Trace element diagenesis in pyrite-rich sediments of the Achterwasser lagoon, SW Baltic Sea

The early diagenesis of trace elements (V, Cr, Co, Cu, Zn, As, Cd, Ba, U) in anoxic sediments of the Achterwasser, a shallow lagoon in the non-tidal Oder estuary in the Baltic Sea, was investigated in the context of pyrite formation. The dissolved major redox parameters show a two-tier distribution with transient signals in the occasionally re-suspended fluid mud layer (FM) and a permanently established diagenetic sequence in the sediment below. Intense microbial respiration leads to rapid depletion of O₂ within the uppermost mm of the FM. The reduction zones of Mn, Fe and sulfate overlap in the FM and in the permanently anoxic sediment section which appears to be a typical feature of estuarine sediments, under low-sulfate conditions. Degrees of pyritization (DOP) range from 50% in the FM to remarkably high values > 90% at 50 cm depth. Pyrite formation at the sediment surface is attributed to the reaction of Fe-monosulfides with intermediate sulfur species via the polysulfide pathway. By contrast, intense pyritization in the permanently anoxic sediment below is attributed to mineral growth via adsorption of aqueous Fe-sulfide complexes onto pyrite crystals which had originally formed in the surface layer.The studied trace elements show differential behavior patterns which are closely coupled to the diagenetic processes described above: (i) Zn, Cu and Cd are liberated from organic matter in the thin oxic layer of the sediment and diffuse both upwards across the sediment/water boundary and downwards to be trapped as monosulfides, (ii) V, Cr, Co and As are released during reductive dissolution of Mn- and Fe-oxyhydroxides, (iii) U removal from pore water occurs concomitantly to Fe reduction in the FM and is attributed to reduction of U(VI) to U(IV), (iv) the Ba distribution is controlled by reductive dissolution of authigenic barite in the sulfate reduction zone coupled with upward diffusion and re-precipitation. The incorporation of trace elements into pyrite is most intense for Co, Mn and As, intermediate for Cu and Cr and little to negligible for U, Zn, Cd, V and Ba. The observed trend is largely in agreement with previous studies and may be explained with differing rates for ligand exchange. Slow and fast ligand exchange and thus precipitation kinetics are also displayed by downcore increasing (Mn, Cr, Co and As) or constantly low (Zn, Cu, Cd) pore water concentrations. The downward increasing degrees of trace metal pyritization (DTMP) for Co, Cu, Zn and As are, in analogy to pyrite growth, assigned to adsorption of sulfide complexes or As oxyanions onto preexisting pyrite minerals.     

黄河三角洲*暴雨雷达回波特征及临近预报

本文利用1994－1998年东营站713数字化雷达回波资料结合高空、地面形势，对发生在黄河三角洲地区的33个暴雨日41个暴雨中尺度雷达回波系统特征及形成过程进行了总结，提出了暴雨临近预报的着眼点。在1999年的预报服务中，取得了良好的经济效益和社会效益。     

进入渤海的热带气旋路径特点分析

热带气旋是夏季影响渤海的灾害性天气系统之一。其影响路径主要有三类，各类路径在影响时前期中高纬500hPa高空环流形势及夏季西太平洋副热带高压特征指数有显著差异。     

套子湾表层沉积物地球化学特征的研究

本文对套子湾表层沉积物中的pH、Eh、硫化物、氮、磷、有机质、铜、铅、锌、镉地球化学特征进行了分析研究.并讨论了如下几个关系:①与沉积类型之间的关系;②其相关性与环境的关系。③与矿物的关系;④与水和风等作用的关系;⑤与水化学的关系;⑥重点分析了表层沉积物中化学要素与生物的相互关系。这不仅为该湾的开发治理.生物养殖等提供科学依据.并进一步证明沉积物地球化学.在环境化学和生态学研究等方面的理论意义。     

云南潞西大矿山铅锌矿

矿体产于花岗岩以上断层附近大理岩中,大理岩与花岗岩接触部位是主要的矿化部位,在大矿山、小石林、灰窑等地见有强褐铁矿化、弱铅锌矿化的厚大矿化层。通过勘查工作,认为矿区具有寻找中-大型规模矿山的前景。     

城市形象资源和地域文化传统特色研究

城市是人类的一种社会组织结构形式,与其他任何组织形式一样,城市的发展也需要核心竞争力,核心竞争力依赖于城市核心资源系统的开发和创造。通过城市形象的塑造再创城市新型的核心资源,这已经是一个既成事实,城市形象可以在更高层次保护城市传统资源要素,使其发挥更大的作用。     

普朗铜矿找矿标志及找矿模型

普朗铜矿矿体形态简单,以铜为主,伴生金、硫等多种有益组份。找矿标志为深大断裂旁侧的次级两组断裂交汇部位;特别是多种岩类的杂岩体,裂隙发育地段;斑岩体靠沟谷部位(负地形)等。土壤化探异常Cu>400×10-6和Mo>10×10-6异常叠加部位;视极化率大于10%的激电异常,磁异常约50～100nT的部位等。初步建立找矿模型,运用该模型,在矿区外围已发现普上、亚杂等一批铜(多金属)矿体,矿化体,具有明显的找矿指导意义。     

三种类型烃-烃不混溶包裹体组合的特征和热力学条件的计算

在自然界广泛分布着烃-烃不混溶体系中捕获的流体包裹体,由于这些包裹体具有复杂的组成和相态,因此不混溶包裹体组合的判别和热力学参数的计算常常难以进行。根据烃-烃不混溶体系中两个端员组分流体包裹体室温下的相态特征和在温度-压力平面图上等容线交点显示的位置,划分成三种类型流体包裹体组合,本介绍了三种类型流体包裹体组合特征,叙述了不混溶烃-烃包裹体组合的测定和判别方法,并且阐述均一化包裹体相态方程和气-液平衡常数原理和方法与此同时列举了自然界简单的三种类型不混溶烃-烃包裹体组合的测定、判别和计算的几个实例,利用相态方程和气-液平衡常数,不但精确地计算出包裹体均一压力,并且精确地计算出流体密度和体积等热力学参数。最后,利用均一成气相和液相的两种包裹体在 p-T 平面图上等容线交点同样计算出流体包裹体组合的捕获温度和压力。