高精度温度采集系统设计

针对高精度温度采集的需求,设计了一个以低功耗单片机MSP430F149作为核心处理器,以PT100铂电阻为传感器的温度采集系统。为了提高系统的复用性,采用精密电阻法,从硬件设计上消除了恒流源电流漂移以及A/D转换电路参考电压精度对温度测量数据的影响。重点描述了系统设计方案,详细说明了恒流源选择的原则、电流偏差的消除以及AD7792转换器的操作步骤。实验结果表明,温度测量精度优于0.1 ℃。对比试验表明,系统稳定性良好,已应用于业务产品中。     

香炉山地区水系沉积物铂·钯地球化学异常特征

香炉山地区采用1个样/km²的水系沉积物测量,在苏家营-则家坪地区圈出1个Pt、Pd、Au异常带,异常带明显受NNW向或近SN向构造控制,从异常规模和强度推测苏家营-则家坪Pt、Pd、Au地球化学异常具有找寻铂钯矿的远景.     

滇东铂钯地球化学勘查及异常评价

利用滇东地区1∶20万水系沉积物化探的组合副样,按8km×8km面积重新组合,采用C-OES法定量分析其Pt、Pd含量,在此基础上圈定了4种主要类型Pt、Pd异常:①与中古元古代昆阳群黑色页岩建造有关的Pt、Pd异常;②与上震旦统—下寒武统黑色页岩建造有关的Pt、Pd异常;③与二叠纪峨眉山玄武岩建造有关的Pt、Pd异常;④与其他沉积建造有关的Pt、Pd异常。并对该地区Pt、Pd地球化学异常进行了评价,为进一步开展Pt、Pd资源评价提供科学依据。     

Genesis of the Huangshannan high-Ni tenor magmatic sulfide deposit in the Eastern Tianshan,northwest China: Constraints from PGE geochemistry and Os–S isotopes

The Huangshannan magmatic Ni-Cu sulfide deposit is one of a group of Permian magmatic Ni-Cu deposits located in the southern Central Asian Orogenic belt in the Eastern Tianshan, northwest China. It is characterized by elevated Ni tenor (concentrations in recalculated 100% sulfide) in sulfide within ultramafic rocks (9–19 wt%), with values much higher than other deposits in the region. Sulfides of the Huangshannan deposit are composed of pentlandite, chalcopyrite, and pyrrhotite and the host rock is relatively fresh, indicating that the high-Ni tenor is a primary magmatic feature rather than formed by alteration processes. It is shown that sulfides with high-Ni tenor can be generated by sulfide-olivine equilibrium at an oxygen fugacity of QFM +0.5, for magmas containing 450 ppm Ni and 20% olivine. Ores with >10 wt% sulfur have relatively low PGE and Ni tenors compared to other ores, R factor (mass ratio of silicate to sulfide liquid) modeling of Ni indicates that they formed at moderate R values (150–600). Based on this constraint on R values, ores with <10 wt% sulfides in the Huangshannan deposit can be segregated from a similar parental magma with 0.05 ppb Os, 0.023 ppb Ir, and 0.5 ppb Pd at R values between 600 and 3000. This, coupled with the supra-cotectic proportions of sulfide liquid to cumulus silicates in the Huangshannan ores imply mechanical transport and deposition of sulfide liquid in a magma pathway or conduit, in which sulfides must have interacted with large volumes of silicate magma. Platinum and Pd depletion relative to other platinum group elements (PGEs) are observed in fresh and sulfide-rich samples (S > 4.5 wt%). As sulfide-rich samples are also depleted in Cu, and as interstitial sulfides in those samples are physically interconnected at a scale of several cms, the low Pt and Pd anomalies are attributed to solid Pt and Pd phases crystallization and retention with the monosulfide solid solution (MSS) and Cu-rich sulfide liquid percolation during MSS fractionation. This finding indicates that Pt anomalies in sulfide-rich rocks from magmatic Ni-Cu deposits in the Eastern Tianshan are the result of sulfide fractionation rather than a hydrothermal effect. ¹⁸⁷Os/¹⁸⁸Os_(278Ma) values of the lherzolite samples vary from 0.27 to 0.37 and γOs_(278Ma) values vary from 110 to 189, indicating significant magma interaction with crustal sulfides, rich in radiogenic Os. Well constrained γOs values and δ³⁴S values (−0.4 to 0.8‰) indicate that crustal contamination occurred at depth before the arrival of the magma in the Huangshannan chamber. Regionally, deposits with high-Ni tenor have not been reported other than the Huangshannan deposit; however, many intrusions with high-Ni contents in olivine are present in NW China, such as the Erhongwa, Poyi and Poshi intrusions. Those intrusions are capable of forming high-Ni tenor sulfides due to olivine-sulfide-silicate equilibrium and relative high-Ni content in parent magma, making them attractive exploration targets.     

Au-Pb compounds in nature: A general overview and new evidence from the Inagli Pt–Au placer deposit,the Aldan Shield,Russia

This study presents a new and first finding of Au-Pb intermetallic compounds in the Inagli Pt–Au placer deposit, the Republic of Sakha (Yakutia), Russia. This is the first time that all three accepted minerals (hunchunite, anyuiite and novodneprite), as well as unnamed Au-Pb intermetallics, corresponding in composition to Au_1.5Pb and AuPb, are present together in the same locality. We provide chemical compositions of Au-Pb compounds and host gold particles, describe morphology and relationships between different mineral phases. We also present an unexpected finding of unusual inclusion of Pb-Fe-aluminosilicate associated with K-feldspar and anyuiite in the gold grain. The new data together with data from other occurrences of Au-Pb compounds worldwide were reviewed to discuss type localities, mineralogy, conditions and possible mechanisms of formation of Au-Pb intermetallics and to provide an overview of current knowledge about these uniquely rare but naturally occurring minerals.     

内蒙古渣尔泰山群和白云鄂博群中Pt、Pd地球化学特征及找矿建议

内蒙古渣尔泰山群和白云鄂博群是一套陆源碎屑岩、泥页岩、碳酸盐岩,地层中Pt、Pd的含量与原岩中泥质、有机碳、有机质的含量有关。其中渣尔泰山群中的阿古鲁沟组炭质板岩、增隆昌组硅质炭质板岩为含Pt、Pd最佳层位(岩性),白云鄂博群中的比鲁特组千枚状板岩也为含Pt、Pd的最佳层位(岩性)。通过研究Pt、Pd的富集状况、存在形式、矿物学特征等,可查明渣尔泰山群、白云鄂博群中的含矿层位,以达到寻找铂、钯矿床的目的。     

中国与基性—超基性岩有关的Cu－Ni（Pt）矿床成矿系列类型

中国与基性—超基性岩有关的Ｃｕ－Ｎｉ（Ｐｔ）矿床，主要形成于以前寒武系为基底的大陆裂谷，部分形成于增生褶皱带中显生宙地层为基底的裂陷槽环境。根据形成时代、当时所在的构造环境单元及成矿岩浆系列，划分为９个矿床成矿系列和８个矿床成矿亚系列。成矿时代以元古代、晚古生代为主。现今，矿床主要分布于地台边缘，造山带中也有产出，但不代表其当时形成的地质背景。成矿物质来源为上地幔，原始岩浆以上地幔部分熔融的高ＭｇＯ拉斑玄武岩（拉斑橄榄玄武岩）岩浆系列为特征，也有钙碱性岩浆（喀拉通克）和科马提岩岩浆系列（桂北）。地壳物质混染比较普遍。矿床成因类型主要为岩浆熔离型，且以硅酸盐岩浆上侵前的深部熔离作用为主。还有热液成因类型（煎茶岭）。矿床成矿系列的时空分布与中国大陆的构造演化密切相关     

四川石棉县首次发现独特的自然铂矿床

攀西地区大片前震旦纪结晶基底杂岩中产出有众多的前晋宁期层状侵入体，其间可见钒钛磁铁矿化，铬铁矿化，最近在石棉境内新发现一处含铂矿化体呈层状，网脉状产于层状侵入体中，且多以自然铂单矿物存在。伴生主要矿物为磁铁矿，钛铁矿，黄铁矿，黄铜矿等。初步认为该矿床类型属产于层状铁质基性-超基性岩与铜硫化物-钡钛磁铁矿有关的构造-热液再活化型自然铂矿床。     

泡沫塑料富集-电感耦合等离子体质谱法测定土壤中超痕量金铂钯

样品采用王水溶解,二氯化锡还原,泡沫塑料富集,用Re作内标,电感耦合等离子体质谱法同时测定土壤中超痕量金、铂、钯。在盐酸-二氯化锡体系中,盐酸酸度为15%,二氯化锡浓度为45 g/L,吸附时间30 min时吸附效果明显,吸附温度为25℃时吸附率相对稳定。方法检出限Au为0.21 ng/g,Pt为0.18 ng/g,Pd为0.16 ng/g,方法加标回收率Au为91.3%~97.8%,Pt为92.0%~96.7%,Pd为96.0%~101.6%。该方法用于测定国家一级标准物质,线性范围宽、重现性好,结果准确可靠,样品处理简便、快速。     

聚氨酯泡塑富集硫脲解脱-石墨炉原子吸收光谱法测定地质样品中金铂

泡沫塑料常用于富集常规地质样品中的铂族元素,而富集后往往用高温灰化法解脱,此法操作繁琐,温度过高易使铂配合物分解为王水难以提取的不溶性残渣,导致测试结果不稳定、效率低;单独使用20 g/L硫脲溶液解脱,测试结果的重现性差。本文对此方法进行改进,采用50%王水封闭溶解试样,氯化亚锡还原,聚氨酯泡塑富集,20 g/L硫脲-20%盐酸溶液解脱,石墨炉原子吸收光谱法测定金和铂。在盐酸-氯化亚锡体系中,吸附温度为20℃,振荡时间为30 min时,金和铂的回收率均在95%以上,金和铂的检出限分别为0.23 ng/g和0.39 ng/g,精密度(RSD,n=10)分别为1.8%～10.3%和1.3%～13.3%。经国家一级标准物质验证,测定值和标准值基本相符。该方法泡塑解脱时无需高温灰化,用王水多次提取,在100℃沸水浴中即可一次完成,样品处理快捷。与高温灰化法相比,提取温度大为降低,分析流程简单,显著提高了单次测样量,且干扰小、空白值低,可以满足除王水难溶的铂矿种外大部分地质样品快速测定的需要。