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乙酰褐藻酸丙二酯的制备与表征 总被引:1,自引:0,他引:1
为了改变褐藻酸丙二酯的溶解性,本文以氢碘酸为催化剂,将褐藻酸丙二酯与乙酐反应,制备了乙酰褐藻酸丙二酯。生成物不溶于水,可溶于多种中等极性的有机溶剂。本文用IR,~1H-NMR,HGPC对其进行了表征,并对反应条件对产率的影响进行了探讨。 相似文献
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Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil 总被引:2,自引:0,他引:2
In order to reduce the brittleness of soil stabilized by lime only, a recent study of a newly proposed mixture of polypropylene fibre and lime for ground improvement is described and reported in the paper. To investigate and understand the influence of the mixture of polypropylene fibre and lime on the engineering properties of a clayey soil, nine groups of treated soil specimens were prepared and tested at three different percentages of fibre content (i.e. 0.05%, 0.15%, 0.25% by weight of the parent soil) and three different percentages of lime (i.e. 2%, 5%, 8% by weight of the parent soil). These treated specimens were subjected to unconfined compression, direct shear, swelling and shrinkage tests. Through scanning electron microscopy (SEM) analysis of the specimens after shearing, the improving mechanisms of polypropylene fibre and lime in the soil were discussed and the observed test results were explained. It was found that fibre content, lime content and curing duration had significant influence on the engineering properties of the fibre–lime treated soil. An increase in lime content resulted in an initial increase followed by a slight decrease in unconfined compressive strength, cohesion and angle of internal friction of the clayey soil. On the other hand, an increase in lime content led to a reduction of swelling and shrinkage potential. However, an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. An increase in curing duration improved the unconfined compressive strength and shear strength parameters of the stabilized soil significantly. Based on the SEM analysis, it was found that the presence of fibre contributed to physical interaction between fibre and soil whereas the use of lime produced chemical reaction between lime and soil and changed soil fabric significantly. 相似文献
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以FeCl3?6H2O、NiCl2?6H2O、MgCl2?6H2O为原料,以NaOH为沉淀剂采用水热法合成了镁镍铁水滑石 (MgNiFe-LDH),通过X射线衍射 (XRD)、傅里叶变换红外光谱 (FTIR) 和扫描电镜 (SEM) 分析了MgNiFe-LDH结构及形貌,探讨了不同陈化时间和水热温度对MgNiFe-LDH合成的影响。将制得的MgNiFe-LDH添加至聚丙烯 (PP) 中,制备MgNiFe-LDH/PP复合材料,通过对材料的加速老化测其力学性能,研究了添加MgNiFe-LDH前后材料力学性能的差异。研究结果表明,当Mg2+:Ni2+:Fe3+=2:1:1,反应温度为140℃、陈化时间为24 h时,合成的MgNiFe-LDH为片状,形貌较为规整,颗粒粒径约为2μm;经加速老化后,填充MgNiFe-LDH 复合材料的抗老化性能优于纯PP,当MgNiFe-LDH的填充量为6 wt% 复合材料拉伸强度不变,可明显提高PP的抗老化性能。 相似文献
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Sandwich pipes (SP), a composite structure consisting of two concentric steel tubes and a polymeric or cement-based core has been proposed to be well-insulated and withstand high installation and operational loads in deepwater oil and gas field. In the paper, the post-buckling responses and pressure capacity of sandwich pipes filled with the solid polypropylene annular were investigated. The degree of the inter-layer adhesion condition between the core layer and the surrounding pipes was modeled by the contact surfaces adopting different maximum shear strength values to allow the relative displacement between the layers. The effects such as inter-layer adhesion interactions, thickness-to-radius ratios, the core thickness, the material parameters, the relative initial ovality directions and the inelastic anisotropy on the collapse pressure of SPs were discussed. More than 2000 finite element (FE) models of the sandwich pipes with practical configurations were constructed and analyzed using the programming language Python within the FE software package ABAQUS. Based on the FE results, a simplified equation was developed and recommended for the collapse pressure calculation of sandwich pipes with the polypropylene annular. 相似文献
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顶空气相色谱法测定地层水中的苯系物 总被引:10,自引:2,他引:10
利用极性聚乙二醇弹性石英毛细管柱分离苯系物,在线顶空气相色谱法测定地层水中的苯系物。讨论了色谱柱、载气压力、液相体积、顶空压力、顶空加热温度等因素对测定的影响。该方法实现了地层水中苯、甲苯、乙苯、对二甲苯、间二甲苯、邻二甲苯、异丙苯、苯乙烯等各组分的完全分离,方法的检出限在0.07—0.23μg/L,8次测定相对标准偏差在2.98%-4.91%,加标回收率为95.2%-104%。方法可用于地层水等液体样品中苯系物的测定。 相似文献
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INTRODUCTION Gas hydrate is anice-like crystal compound gen-erally formed by water and natural gas molecules ,whichis mainly distributed under the oceanfloor andin the permafrost andis viewed as an energy resourcewith great potential (Jiang et al .,2002) .For the rel-ative exploration and development of gas hydrate inChina ,some specialists and scholars have suggestedthat relative test drilling exploitation should be donein the permafrost (Liu,2005 ; Li and Geng,2000) .Drillingin the per… 相似文献
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为了提高产品质量的稳定性,实验研究了采用新菲尔对藻酸双酯钠片剂进行薄膜包衣的方法,并运用正交试验确定了薄膜包衣的最佳工艺条件为:藻酸双酯钠片剂硬度为3~4kg/mm^2,包衣液浓度为11%,喷液流量为0.19kg/min,片芯水分为5.0%。采用新菲尔包制的薄膜衣片与藻酸双酯钠糖衣片相比较具有阻湿性能好,片剂增重小,工时短等优点。 相似文献