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Historical data of total dissolved inorganic carbon (CT), together with nitrate and phosphate, have been used to model the evolution of these constituents over the year in the Atlantic water of the Norwegian Sea. Changes in nutrient concentration in the upper layer of the ocean are largely related to biological activity, but vertical mixing with the underlying water will also have an impact. A mixing factor is estimated and used to compute the entrainment of these constituents into the surface water from below. After taking the mixing contribution into account, the resulting nutrient concentration changes are attributed to biological production or decay. The results of the model show that the change in CT by vertical mixing and by biological activity based on nutrient equivalents needs another sink to balance the carbon budget. It cannot be the atmosphere as the surface water is undersaturated with respect to carbon dioxide and is, thus, a source of CT in this region. Inasmuch as the peak deficit of carbon is more than a month later than for the nutrients, the most plausible explanation is that other nitrogen and phosphate sources than the inorganic salts are used together with dissolved inorganic carbon during this period. As nitrate and phosphate show a similar trend, it is unlikely that the explanation is the use of ammonia or nitrogen fixation but rather dissolved organic nitrogen and phosphate, while dissolved organic carbon is accumulating in the water. 相似文献
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S. K. P. Coles C. I. Wright D. A. Sinclair P. Van den Bossche 《Marine Georesources & Geotechnology》2002,20(2):87-110
Extensive potassium and phosphorous-rich mineralization occurs on the outer continental shelf of the southern and west coasts of South Africa and Nambia. This article reviews the potential of exploiting these deposits in an environmentally sound manner for the manufacture of fertilizer. At present, reserves of potash and phosphate fertilizer are exploited from terresterial deposits, the majority being surface mined. The use of fertilizer in South Africa has shown no growth in the past 13 years, and, in some years, usage has even declined. On average, over the last decade, South Africa has consumed 2 million Mt of fertilizer (including nitrogen) per annum, the vast majority of phosphate fertilizer being produced by FOSKOR from the Phalaborwa Igneous Complex. Potash fertilizer is imported into South Africa. Although fertilizer consumption is expected to decrease in the short-term, there are good future prospects for the domestic and international fertilizer market. Considerable research into both glauconitic (containing K 2 O) and phosphatic deposits along the southern African continental shelf indicate that these sedimentary deposits have a complex genesis and mineralization. Of the total K 2 O reserves of 1300 million Mt on the southern African margin, 1000 million Mt is located off the southern African west coast, and the remainder situated on the Agulhas Bank. The largest glauconite concentration ( ±300 million Mt K 2 O) off southern Africa lies west of Saldanha Bay, South Africa. The distribution of P 2 O 5 off southern Africa is dominated by the vast deposit between Walvis Bay and Luderitz, Nambia. This reserve is estimated to contain 1000 million Mt of greater than 5% P 2 O 5 in a relatively small area of about 10000 km2. The phosphorite deposit south of Saldanha Bay constitutes a reserve of ±3500 million Mt of apatite and the deposit on the Agulhas Bank comprises 5500 million Mt. The phosphate deposit off Saldanha Bay occurs as an extensive, low to medium grade deposit. Although vast resources of potash and phosphatic minerals occur along the southern African outer continental shelf the expensive nature of marine exploitation may render most of these deposits, especially the phosphates, subeconomic. The low price of fertilizer andextensive natureontheonland deposits, although confined to asmallnumber of countries, mean that it will not be financially viable to extract these deposits. Assuming high grade glauconitic sand with the right composition can be located, the high market price indicates good future prospects for these potash deposits. 相似文献
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在1981、1991(1990)和1998年3次海洋环境调查的基础上,通过相同水质要素时空比较分析,江苏海域的溶解氧、磷酸盐、硝酸盐和亚硝酸 盐这4种主要海水化学因子具有时空变化特征,其高值区主要分布在灌河口、扁担港口、射阳河口、川东港和长江北支口北侧,且河口、近岸值高,向海含量渐小,不同年份、季节也有变化。沿海水化学性质主要受陆源排污(农田化肥等)影响,主要是入海河流携带污染物、海洋生物作用和本海域水体运动特征的影响,此外,溶解氧变化还受到水温变化的影响。 相似文献
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Phosphate mining in southeastern Idaho has historically resulted in the release of dissolved metals and inorganics to groundwater and surface water, primarily due to leachate from waste rock in backfilled pits and overburden storage piles. Selenium (Se) is of particular concern due to its high concentration in leachate and its limited attenuation downgradient of source zones under oxic conditions. Assessments of potential groundwater/surface water impacts from waste rock typically involve laboratory characterization using saturated and unsaturated flow columns packed with waste rock. In this study, we compare the results of saturated and unsaturated column tests with groundwater quality data from the Mountain Fuel, Champ, South and Central Rasmussen Ridge Area (SCRRA), Smoky Canyon, Ballard, Henry, and Enoch Valley Mines, to understand the release and attenuation of Se in different geochemical environments. Column studies and field results demonstrate that the ratio of aqueous Se to aqueous sulfate (Se:SO4 ratio) is a useful metric for understanding Se release and attenuation, where the extent of sulfate reduction is much less than Se reduction. Comparison of dissolved Se and sulfate results suggests that the net leachability of Se from unsaturated waste rock is variable. Overall, Se concentrations in groundwater directly beneath waste rock dumps is not as high as would be predicted from unsaturated columns. Lower Se:SO4 ratios are observed immediately beneath waste rock dumps and backfilled pits relative to areas receiving shallow waste rock runoff. It is hypothesized that Se released in the oxic upper portions of the waste rock is subsequently attenuated via reductive precipitation at depth in unsaturated, low-oxygen portions of the waste rock. This highlights an important mechanism by which Se may be naturally attenuated within waste rock piles prior to discharge to groundwater and surface water. These results have important implications for mining practices in the region. A better understanding of Se dynamics can help drive waste rock management during active mining and capping/water management options during post-mining reclamation. 相似文献
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Alison Searl 《Geological Journal》1992,27(3):243-270
The Broadford Beds comprise a basal carbonate-dominated unit overlain by dark muddy sandstones and an upper cross-bedded sandstone unit. The limestones include coralliferous and oolitic lithologies and the sandstones include pisolitic berthierine ironstones and abundant phosphate nodules. The Broadford Beds have a maximum thickness of 140 m and can be subdivided into 17 parasequences, each initiated by an approximately 20 m rise in relative sea level. Marine flooding surfaces are most readily recognized in the lower parts of the succession, where diagenetic data can be utilized to locate emergence surfaces. There is no diagenetic evidence of early emergence in the upper parts of the sequence, but a variety of sedimentological data can be used to identify parasequence boundaries. Deposition of the Broadford Beds occurred largely around the shores of a number of islands in the northern Hebridean area. These islands partly isolated the Skye–Applecross area from a deeper marine basin to the west, and this may have enhanced the formation of authigenic phosphates and iron silicates. It is possible to use the regional variability of parasequence thicknesses to investigate the role of active local tectonism in governing differential subsidence and sediment supply. 相似文献
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氮磷营养盐对中肋骨条藻生长及硝酸还原酶活性的影响 总被引:3,自引:0,他引:3
通过实验室培养,在不同氮磷浓度及氮磷比率的营养条件下,对中肋骨条藻(Skeletonema costatum)的生长及藻细胞硝酸还原酶的活性进行研究。实验结果表明,中肋骨条藻属于营养型藻类,氮磷营养盐的添加,极大地促进了藻细胞的增殖。在接种后的第4~5天,各培养组藻密度达到最大值并与对照组形成极显著性差异(P〈0.01)。实验进一步发现,环境中的氮、磷浓度及氮磷比率都会影响中肋骨条藻的生长及藻细胞硝酸还原酶活性(NRA)。此外,在各培养组中,中肋骨条藻硝酸还原酶活性的最大值(NRAmax)均出现在指数生长期(接藻后第1,2天),早于最大藻密度的出现时间(第4,5天),这表明藻对营养盐的同化速率与生长速率并不一致,后者存在一定的滞后效应。在本实验条件下,中肋骨条藻的硝酸还原酶活性存在一定的阈值。 相似文献
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象山港氮、磷营养盐环流和分布规律的研究 总被引:8,自引:1,他引:7
采用定点监测分析方法,研究了象山港狭湾内设置的六个固定站位1992-2007年时间段内的硝酸氮(NO3-N)、亚硝酸氮(NO2-N)、铵氮(NH4-N)和磷酸盐(PO4-P)浓度的监测数据,探讨了象山港狭湾内(122°00'E以西)氮、磷营养盐的环流和分布规律.结果表明,(1)除个别年份外,16年内硝酸氮、亚硝酸氮、铵氮和磷酸盐浓度的空间分布,从港顶1号站向港口6号站呈降低趋势,其中以PO4-P、NO2-N的降低趋势最为明显,而NH4-N的降低趋势相对较弱.(2)NO3-N的空间变化规律较为复杂,并且3号站的浓度往往达到最大值.(3)无论是平水期(4月)还是丰水期(7月),表层盐度均低于底层,而表层温度高于底层;盐度从港顶1号站向港口6号站递增,而温度递减.这种分布规律基本上可用余环流模式进行解释,但余环流输运并不是促使营养盐入海的唯一原因,潮振荡的垂向剪切造成的纵向弥散和潮混合亦对营养盐输运有重大贡献.(4)与1992年相比,2007年各站的NO3-N浓度几乎都增加了一倍,PO4-P浓度增幅更大,说明象山港的氮、磷污染与日俱增. 相似文献