Assessment of mercury mobility and bioavailability by fractionation method in sediments from coastal zone inundated by the 26 December 2004 tsunami in Thailand

The 26 December 2004 tsunami covered significant portion of a coastal zone with a blanket of potentially contaminated sediments. In this report are presented results on mercury concentrations in sediments deposited by the tsunami in a coastal zone of Thailand. Since the total mercury concentrations are insufficient to assess mercury mobility and bioavailability in sediment, its fractionation was applied. Sediments were sampled within 50 days after the event and analyzed by sequential extraction method. The procedure of sequential extraction involved five subsequent stages performed with solutions of chloroform, deionized water, 0.5 M HCl, 0.2 M NaOH, and aqua regia. The mean concentration of total mercury in sediments was 119 ± 50 ng g⁻¹ dry mass (range 66–230). The fractionation revealed that mercury is mainly bound to the least bioavailable sulphides 75 ± 6% (range 62–86), organomercury compounds 14 ± 7% (range 4–26), and humic matter 9 ± 7% (range 1–27). The lowest contributions bring fractions of water-soluble mercury 0.8 ± 1.0% (range 0.1–3.6) and acid soluble mercury 0.9 ± 0.5% (range 0.2–2.1). Although, the total mercury content is similar in a reference sample and in the tsunami sediments, the highly toxic organomercury fraction contribution is higher in the latter. The results were compared with chemical and sedimentological properties of the sediments but no significant correlations were obtained between them.     

Verification of the motion fields over Southeast Asia by the Florida State University (FSU) superensemble forecast

The Florida State University (FSU) multimodel superensemble forecast is evaluated against several other operational weather models for the Southeast Asia region. The superensemble technique has demonstrated its exceptional skills in forecasting precipitation, motion and mass fields compared to either individual global operational or ensemble mean forecasts. The motion field investigation for the season of 2001 reveals that the superensemble forecasts are closer to the observed data compared to the other global member operational models through its low systematic errors at the 850 hPa level. The FSU multimodel superensemble forecasts exhibit the lowest root mean square errors (RSMEs), the highest correlation against the best observed data and the lowest systematic errors compared to the other operational model members. These forecasts have the potential to provide better daily weather predictions over the Southeast Asia region, particularly during the early northeast monsoon that often causes heavy rainfall in the equatorial part of the Southeast Asia region.     

Tectonic Setting of the Permo-Triassic Chiang Khong Volcanic Rocks, Northern Thailand Based on Petrochemical Characteristics

The inferred Permo-Triassic Chiang Khong volcanic belt is composed of felsic to mafic volcanic rocks and their pyroclastic equivalents. Almost all the least-altered mafic volcanic rocks are lava flows; a few might have occurred as dykes. These mafic volcanic rocks are non-foliated to weakly foliated, and mostly have porphyritic textures. The phenocrysts/microphenocrysts in porphyritic samples are commonly plagioclase, and may include clinopyroxene, olivine, Fe-Ti oxide, apatite and amphibole. The matrix of lava flows ranges texturally from felty to trachytic but a few samples show felty to ophitic/subophitic, and glassy textures, whereas that of possible dyke samples is holocrystalline. The primary matrix constituents are largely plagioclase and variable proportions of clinopyroxene, Fe-Ti oxide, amphibole, olivine, apatite, quartz, alkali feldspar and/or glass. All the studied samples have been subjected to greenschist-facies regional metamorphism. Chemically, the samples show narrow ranges of least-mobile incompatible-element ratios and range compositionally from dacite to basalt of tholeiitic series. These samples are chemically analogous to those of the Tertiary andesite from Sardinian Rift, Sardinia, Italy, particularly in terms of least-mobile incompatible-element ratios. Accordingly, the studied mafic volcanic rocks are interpreted to have formed in a continental volcanic arc. However, the problem related to the geometry of plate convergence, giving rise to the continental volcanic arc, still exists.     

泰国三塔断裂活动性及其板缘动力学意义

通过对位于印度板块与欧亚板块碰撞带缅甸弧附近三塔断裂带活动性的野外考察研究，探讨了位于缅甸弧东侧的滇缅泰板缘地区现代构造与地震活动动力来源和空间不均匀性。指出印度板块与欧亚板块沿兴都库什弧的正面碰撞和青藏高原隆起导致的侧向挤出作用对滇缅泰板缘地区现代构造与地震活动的影响可能大于印度板块与欧亚板块沿缅甸弧的碰撞对上述地区的影响。     

Structural studies and their bearing on the Early Precambrian history of the Dharwar tectonic province,southern India

In the Dharwar tectonic province, the Peninsular Gneiss was considered to mark an event separating the deposition of the older supracrustal Sargur Group and the younger supracrustal Dharwar Supergroup. Compelling evidence for the evolution of the Peninsular Gneiss, a polyphase migmatite, spanning over almost a billion years from 3500 Ma to 2500 Ma negates a stratigraphic status for this complex, so that the decisive argument for separating the older and younger supracrustal groups loses its basis. Correlatable sequence of superposed folding in all the supracrustal rocks, the Peninsular Gneiss and the banded granulites, indicate that the gneiss ‘basement’ deformed in a ductile manner along with the cover rocks. An angular unconformity between the Sargur Group and the Dharwar Super-group, suggested from some areas in recent years, has been shown to be untenable on the basis of detailed studies, A number of small enclaves distributed throughout the gneissic terrane, with an earlier deformational, metamorphic and migmatitic history, provide the only clue to the oldest component which has now been extensively reworked.     

Classification and interpretation of piezometer well hydrographs in parts of southeastern peninsular India

Well hydrographs from 275 piezometers between 1998 and 2001 in the southeastern parts of peninsular India were used in this study. The area has a monsoon-type climate. Hard rocks cover 85% of the area. The form (shape) of the hydrograph depends upon (1) climatic and hydrogeologic parameters and (2) the scale of the graph. Therefore, hydrographs are drawn to a defined and standardised scale, which allows comparison of hydrographs and helps in bringing out reasons for different forms of the hydrographs. Hydrographs can be divided into seasonal segments and the slope of each segment then used as the basic element of a classification scheme. Slopes are classed as flat (inclination <20°), obtuse (between 20 and 45°), acute (45 and 80°), right angled (80 and 90°) and homoclinal (segments of hydrographs are either rising or falling during one complete water year). Hydrographs are assigned names that are a combination of these classes and begin with the rising segment, such as acute-obtuse. Seventy-six percent of segments were homoclinal-falling in 1999, which had a poor monsoon. Flat segments constitute 27% of all segments in confined Mesozoic aquifer systems. Water table fluctuations suggest an approximate recharge of 120 to 180 mm per annum constituting 18% of the annual precipitation. Cumulative rainfall required to affect a rise in water table is between 45 to 200 mm and lag time varies from 30 minutes to 200 rainy days, which suggests that moisture in the vadose zone holds a part of the annual replenishment for these aquifers.     

泰国水稻种植面积月变化的遥感监测

介绍了光学和微波遥感影像相结合进行泰国水稻种植面积监测方法。泰国雨季雨量充足 ,气温适合 ,同一时间耕地上水稻的物候多样 ,每月水稻种植面积都发生变化。利用旱季的TM影像 ,获得耕地信息。同时利用TM影像覆盖的雷达区域进行非耕地去除 ,进行非监督分类 ,提取反映水稻种植不同生长期的雷达影像后向反射系数特征 ,建立各种类型的分类模型 ,采用监督分类的方法对全景雷达数据进行水稻种植情况调查 ,并分别予以识别和统计 ,反映研究区水稻月种植情况。分类结果通过类别检验和面积量算检验进行精度评价和分析。     

DEFORESTATION IN NORTHEAST THAILAND, 1975–91: RESULTS OF A GENERAL STATISTICAL MODEL

Using a general statistical model, this study attempts to characterise the trend of deforestation in the northeast region (Isan) of Thailand between 1975 and 1991, a period when the kingdom had sustained high rates of economic growth and steady increases in population. Using data obtained directly from government bodies on the 17 provinces comprising this heavily deforested region, the study examines the correlations between forest area and a set of six variables: population density, agricultural area, real per capita income, accumulated irrigated area, agricultural credit levels, and distance from Bangkok, the national political and economic centre. It also considers the effect of the two logging bans instituted in 1979 and since 1989. The study found a negative correlation between forest area and population density in particular, followed in ranking by agricultural credit, per capita income, the logging bans and distance from Bangkok. Viewed together with more recent data showing that rates of deforestation in the kingdom as a whole have slowed and appear to be stabilising, these results also suggest the beginnings in the 1990s of a forest transition – from an industrial to a post‐industrial stage in forest utilisation – in Thailand.     

Petrochemistry of Granitoids Along the Loei Fold Belt,Northeastern Thailand

Petrochemical characteristics of Permo‐Triassic granitoids from five regions (i) Mung Loei, (ii) Phu Thap Fah – Phu Thep, (iii) Phetchabun, (iv) Nakon Sawan – Lobburi, and (v) Rayong – Chantaburi along the Loei Fold Belt (LFB), northeastern Thailand were studied. The LFB is a north–south trending 800 km fold belt that hosts several gold and base‐metal deposits. The granitoids consist of monzogranite, granodiorite, monzodiorite, tonalite, quartz‐syenite, and quartz‐rich granitoids. These are composed of quartz, plagioclase, and K‐feldspar with mafic minerals such as hornblende and biotite. Accessory minerals, such as titanite, zircon, magnetite, ilmenite, apatite, garnet, rutile, and allanite are also present. Magnetic susceptibilities in the SI unit of granitoids vary from 6.5 × 10⁻³ to 15.2 × 10⁻³ in Muang Loei, from 0.1 × 10⁻³ to 29.4 × 10⁻³ in Phu Thap Fah – Phu Thep, from 2.7 × 10⁻³ to 34.6 × 10⁻³ in Petchabun, from 2.4 × 10⁻³ to 14.1 × 10⁻³ in Nakon Sawan – Lobburi, and from 0.03 × 10⁻³ to 2.8 × 10⁻³ in Rayong – Chantaburi. Concentration of major elements suggests that these intermediate to felsic plutonic rocks have calc‐alkaline affinities. Concentration of REE of the granitoids normalized to chondrite displays moderately elevated light REE (LREE) and relatively flat heavy (HREE) patterns, with distinct depletion of Eu. Rb versus Y/Nb and Nb/Y tectonic discrimination diagrams illustrate that the granitoids from Muang Loei, Phu Thap Fah – Phu Thep, Phetchabun, Nakon Sawan – Lobburi, and Rayong – Chantaburi formed in continental volcanic‐arc setting. New age data from radiometric K‐Ar dating on K‐feldspar from granodiorite in Loei and Nakhon Sawan areas yielded 171 ± 3 and 221 ± 5 Ma, respectively. K‐Ar dating on hornblende separated from diorite in Lobburi yielded 219 ± 8 Ma. These ages suggest that magmatism of Muang Loei occurred in the Middle Jurassic, and Nakon Sawan – Lobburi occurred in Late Triassic. Both Nb versus Y and Rb versus (Y + Nb) diagrams and age data indicate that Nakon Sawan – Lobburi granitoids intruded in Late Triassic at Nong Bua, Nakon Sawan province and Khao Wong Phra Jun, Lobburi province in volcanic arc setting. Muang Loei granitoids at the Loei province formed later in Middle Jurassic also in volcanic arc setting. The negative δ³⁴S_CDT values of ore minerals from the skarn deposit suggest that the I‐type magma has been influenced by light biogenic sulfur from local country rocks. The Au‐Cu‐Fe‐Sb deposits correlate with the magnetite‐series granitoids in Phetchabun, Nakon Sawan – Lobburi and Rayong – Chantaburi areas. Metallogeny of the Au and Cu‐Au skarn deposits and the epithermal Au deposit is related to adakitic rocks of magnetite‐series granitoids from Phetchabun and Nakon Sawan areas. All mineralizations along the LFB are generated in the volcanic arc related to the subduction of Paleo‐Tethys. The total Al (^TAl) content of biotite of granitoids increases in the following order: granitoids associated with Fe and Au deposit < with Cu deposit < barren granitoids. X_Mg of biotite in granitoids in Muang Loei indicates the crystallization of biotite in magnetite‐series granitoids under high oxygen fugacity conditions. On the other hand, low X_Mg (<0.4) of biotite in magnetite‐series granitoids in Phu Thap Fah – Phu Thep and Rayong – Chantaburi indicates a reduced environment and low oxygen fugacity, associated with Au skarn deposit (Phu Thap Fah) and Sb‐Au deposit (Bo Thong), respectively. The magnetite‐series granitoids at Phu Thap Fah having low magnetic susceptibilities and low X_Mg of biotite were formed by reduction of initially oxidizing magnetite‐series granitic magma by interaction with reducing sedimentary country rocks as suggested by negative δ³⁴S_CDT values.     

Spatial analysis of water quality and its suitability in farming giant freshwater prawn (Macrobrachium rosenbergii) in Negeri Sembilan region,Peninsular Malaysia

Finding potential sites for resilient prawn production in the tropical environment that also prevents wastage of natural resources is not an easy task. The purpose of this study is to evaluate water quality suitability for prawn farming in Negeri Sembilan of Peninsular Malaysia based on Geographic Information System (GIS). To achieve this goal, numerous criteria including sources of water, water temperature, water pH, sources of pollution, salinity, soil texture and availability of phytoplankton criteria were considered for the modelling process. Analytic Hierarchy Process (AHP) technique was performed to standardize the criteria and the weighting process. The weighted overlay of indicators and results were accomplished by applying the Multi‐Criteria Decision Analysis (MCDA) method in GIS. It was indicated that the Negeri Sembilan area has potential for prawn farming. The results showed that about 25 per cent (163 056.93 ha) of the area was most suitable for prawn farming, about 58 per cent (384 656.88 ha) was considered moderately suitable, while 18 per cent (117 633.49 ha) was regarded as least suitable. The study concluded that the multi‐criteria decision analysis of water quality for prawn farming is vital for regional economic planning in the Negeri Sembilan area and also significant when establishing a model for aquaculture development.