Fossilisation of a silica diagenesis reaction front on the mid-Norwegian margin

The diagenetic transformation of biogenic silica from opal-A to opal-CT was recognised on seismic reflection data over an area of 78 × 10³ km² on the mid-Norwegian margin. The opal-A/CT diagenetic boundary appears as a positive, high amplitude reflection that generally cross-cuts the hosting stratigraphy. We demonstrate that it is not a sea bottom simulating reflection (BSR) and also that is not in thermal equilibrium with the present day isotherms. We present arguments that three styles of deformation associated with the opal-A/CT reflection – polygonal faulting, regional anticlines and synclines and differential compaction folding – indicate that the silica diagenesis reaction front is fossilised at a regional scale. Isochore maps demonstrate the degree of conformity between the opal-A/CT reflection and three seismic horizons of Late Miocene to Early Pliocene age that potentially represent the paleo-seabed when ‘fossilisation’ of the reaction front took place. The seismic interpretational criteria for recognition of a fossilised diagenetic front are evaluated and the results of our study are integrated with previous studies from other basins of the NE Atlantic in order to determine if the arrest of silica diagenesis was diachronous along this continental margin.     

Phytoliths infer locally dense and heterogeneous paleovegetation at FLK North and surrounding localities during upper Bed I time, Olduvai Gorge, Tanzania

The phytolith content of 10 samples collected immediately under Tuff IF (~ 1.785 Ma) at FLK N and other surrounding localities (~ 2 km²) provides a direct botanical evidence for woody vegetation in the eastern margin of Olduvai Gorge during uppermost Bed I time. Observation and counting of 143 phytolith types (5 to >150 μ) reveal dense but heterogeneous woody cover (~ 40–90%) of unidentified trees and/or shrubs and palms associated to the freshwater springs surrounding FLK N, and more open formation (presumably ~ 25–70% woody cover) in the southeast at localities VEK, HWK W and HWK E. The paleovegetation is best described as groundwater palm forest/woodland or bushland, which current analogue may be found near Lake Manyara in similar hydrogeological context (freshwater springs near saline/alkaline lake). Re-evaluating the published pollen data based on this analogy shows that 70% of the pollen signal at FLK N may be attributed to thicket-woodland, Acacia groundwater woodland, gallery and groundwater forests; while < 30% is attributed to swamp herbage and grasslands. Micro-botanical, isotopic, and taphonomical studies of faunal remains converge on the same conclusion that the area surrounding FLK N, which attracted both carnivores and hominins in the early Pleistocene, was densely wooded during uppermost Bed I time.     

Preliminary results from U-Th dating of glacial-interglacial deposition cycles in a silica speleothem from Venezuela

Recent explorations in Cueva Charles Brewer, a large cave in a sandstone tepui, SE Venezuela, have revealed silica biospeleothems of unprecedented size and diversity. Study of one — a sub-spherical mass of opaline silica — reveals a complex, laminated internal structure consisting of three narrow dark bands alternating with two wider light bands. Uranium-thorium dating has produced 3 stratigraphically correct dates on the light bands from 298 ± 6 (MIS 9) to 390 ± 33 ka (MIS 11). U concentration is only 30-110 ppb. Initial ²³⁴U/²³⁸U ratios are high and increase over time from 1.8 to 5.3. Growth rate is very low, the fastest, at 0.37 ± 0.23 mm/ka, in MIS 9. Trace element and heavy metal content of the dark bands is distinctly higher than that of the light bands. It is hypothesized that the dark and light bands correlate with drier/glacial and wetter/interglacial periods, respectively, and that this sample probably began to grow in MIS 13. The cave is in a region that straddles a regionally important ecotone: the speleothem isotopic and trace element variations may preserve a useful paleoclimatic signal. This is the first published suite of U-Th dates from a single silica speleothem and the longest Quaternary record for this region.     

Estimation of biogenic silica contents in marine sediments using seismic and well log data: Sediment Drift 7, Antarctica

Petrophysical properties (wet bulk density, porosity, P-wave velocity) are used to predict biogenic silica contents along a seismic reflection profile that ties two well sites, 1095 and 1096, drilled by Ocean Drilling Program (ODP) Leg 178 on sediment drifts on the Pacific continental margin of the Antarctic Peninsula. The biogenic silica contents along the seismic reflection profile were estimated on the basis of three hypotheses about petrophysical properties distributions in the two boreholes and statistical relationships between biogenic silica and other petrophysical properties, which were established on various sediment layers within the boreholes. Our study demonstrates the possibility to reliably predict the distribution of biogenic silica in the sub-seabed sediments if seismic data processed with amplitude preservation are used and statistical relations are considered. We conclude that the statistical extrapolation of biogenic silica content along seismic reflection profiles tied to borehole data is an efficient tool to quantify the amounts of silica undergoing crystalline transformation, which may have strong implications for submarine slope destabilisation.     

The limited suitability of silica diagenetic boundaries as isothermal markers: Insights from seismic reflection imaging,Offshore Sakhalin,Russian Far East

In many sedimentary basins the seismic reflections that mark the conversion of opal-A to opal-CT and the subsequent conversion of opal-CT to quartz, are parallel to the present-day seabed. As the reactions are in part thermally activated these boundaries have been proposed as potential isothermal markers and could have utility for hydrocarbon exploration. We describe opal-A to opal-CT and opal-CT to quartz diagenetic boundaries using 2D seismic data from the North Sakhalin Basin (NSB). These are not parallel to the present-day seabed, but for 80% of the area of the basin are parallel to an unconformity of Late Miocene age and may represent palaeo-isotherms that were parallel to the Late Miocene seabed. This characteristic has been identified in other basins and may indicate silica diagenetic boundaries do not make reliable present-day isothermal boundaries. We propose diagenetic boundaries, which are not parallel to the seabed, are not present-day isothermal boundaries. This characteristic could result from: (1) temperature decrease, such as through a declining geothermal gradient or erosion of the overburden, which will cause the rate of conversion to slow; (2) variations in the burial rate that would cause changes to the rate of conversion; and (3) a change in the rate of conversion as a result of variation in the physico-chemical factors influencing the silica diagenetic reactions.     

Quartz cementation in Late Cretaceous mudstones,northern North Sea: Changes in rock properties due to dissolution of smectite and precipitation of micro-quartz crystals

Late Cretaceous mudstones from two wells located in the northern North Sea and the Norwegian Sea have been examined with respect to quartz cement. Two different types of quartz cement (Type 1 and Type 2) have been identified using SEM/EDS/CL-analysis of drill-bit cuttings at depths 2370–2670 m (80–85 °C). Type 1 appears as relatively large aggregates (30–100 μm) of depth/temperature related crypto- or microcrystalline to macrocrystalline irregular quartz cement formed by local re-crystallization of biogenic silica. The CL-responses of Type 1 quartz cement give a clear indication of an authigenic origin. Type 2 quartz cement represents relatively high amounts of extremely fine-grained micro-sized (1–3 μm) crystals embedded as discrete, short chains or small clusters/nests within the illitized clay matrix. The CL-responses of micro-quartz crystals indicate an authigenic origin. The micro-quartz is most probably sourced from silica released during the smectite to illite dissolution–precipitation reaction. The petrographic evidence indicates that most of the silica released by the smectite to illite reaction has not been exported out of the mudstones. The silica released produce a subtle inter-connected micro-quartz network interlocked with aggregates of micro-quartz and authigenic clay crystals. This micro-quartz cementation process causes a significant and sharp change in the mudstone stiffness at the onset of the chemical compaction regime. This is indicated by an abrupt increase in well log velocity (Vp) and change in seismic facies close to 2500 m (80/85 °C).     

Diagenesis of diatomite from the Kolubara Coal Basin,Baroševac,Serbia

Diatomite associated with the Kolubara Coal Basin was studied to better understand early stage silica diagenesis of shallow water deposits. The Kolubara Basin consists of Neogene siliciclastic rocks, diatomite, marlstone and rare carbonates. Palaeozoic metamorphic and Mesozoic sedimentary and igneous basement rocks are transgressively overlain by Upper Miocene sandstone, siltstone, shale and mudstone. This Upper Miocene section is transgressively overlain by the Pontian section, which contains diatomite and coal beds. White and grey diatomite forms beds 0.7-2.2 m thick that are continuous over an area of about 2 km². Siliceous rocks vary in composition from diatomite (81-89 per cent SiO₂) to diatom-bearing shale (58-60 per cent SiO₂). Siliceous deposits are laminated in places, with the laminae defined by variations in clay minerals, organic matter and diatoms. Diatomite shows only incipient diagenesis characterized by the fragmentation of diatom frustules, the minor to moderate corrosion of frustules and the formation of minor amounts of opal-A' (X-ray amorphous inorganic opal) cement. The low degree of diagenesis results from the young age of the deposits, low burial temperatures and possibly also from the presence of abundant organic matter and the dissolution of kaolinite. The presence of only weak diagenesis is also reflected by the characteristically poor consolidation of the rocks and low rank of the associated coal.