Distribution and fluxes of metals in the St. Lawrence River from the outflow of Lake Ontario to Québec City

Six anchor stations in the St. Lawrence River from the outflow of Lake Ontario to Quebec City, were occupied for ca. 24 hours in June 1987 during low flow conditions. Samples of water and suspended particulate matter were separated by continuous-flow centrifugation, and were collected every two hours.During this sampling period, fluxes of dissolved forms of zinc, copper and nickel increased in Lac St. François and downstream relative to the sum of the fluxes for the two upstream stations at the outflow of Lake Ontario. Increases in the flux of dissolved zinc and copper were pronounced below Montreal and above Lac St. Pierre. For particulate forms of metals, all five metals show that there are significant inputs in the section of the St. Lawrence River between Lac St. François and the station just above the entrance to Lac St. Pierre.The average concentrations of dissolved cadmium, lead, zinc, copper and nickel ranged from 7–23 ng/l; 9–35 ng/l; 0.434–0.939 g/l; 0.15–0.89 g/l and 0.58–1.12 g/l respectively.Regression analysis of the dissolved and particulate metal concentrations suggests that the concentration of dissolved cadmium, lead, zinc and nickel can be predicted from the regression equation and the determination of particulate metal concentration. This prediction appears to be independent of the suspended particulate matter concentration which varies from ca. 1 to 10 mg/l from the outflow of Lake Ontario to Québec City.     

ENSO对天目山柳杉树轮同位素的影响

在Nin↑～o3,4区SST序列和Jones等的SOI序列基础上，通过主分量分析方法建立了一个ENSO指数序列。并与根据天目山柳杉树轮碳，氢同位素组成比所建立的树轮指数序列进行相关分析。结果表明，天目山树轮指数与ENSO指数有很好的相关性，尤其与前2年的ENSO指数相关显著。说明ENSO对该地区树木的生长和同位素的分馏有影响，也说明天目山地区的树木年轮对于ENSO事件具有一定的记录能力。     

Radiocarbon redating of contaminated samples from a tropical volcano: the Mansion ‘Series’ of St Kitts,West Indies

Heavy rainfall and dense vegetation on tropical volcanoes produce abundant carbonized wood in pyroclastic deposits, in addition to easy contamination of this wood by root systems and soluble humic material. Because the physical nature of the charcoal varies, some samples are more prone to contamination. Two independent studies of the same volcano, Mt Liamuiga on St Kitts in the Lesser Antilles, sometimes using samples from the same carbonized tree, yielded a systematic difference in radiocarbon ages. An exchange of samples and a re-investigation of three physically distinct types of charcoal yielded the following results. Rare, hard, dense charcoal, lacking contamination, which had yielded a spurious age of 2860 years bp, was redated at 1845±58 years bp. Common soft, friable charcoal with good cellular structure proved to be susceptible to contamination. A field decontamination technique utilized by one group seems significant as it yields older ages than when only routine laboratory pre-treatment was used, indicating that the latter technique only partly removes the dried and hard residue produced by the decomposition of modern plant rootlets. A previous date of 24870 years bp obtained from powdery charcoal in a horizon beneath the Mansion Series contradicted ages older than 41000 years bp from common friable charcoal in the lower Mansion Series. The soft powdery charcoal was re-investigated using a sample collected a few centimeters from the original, although field decontamination of this sample was not possible, more extensive laboratory treatment yielded an age of ca. 43000 years bp, again proving that routine laboratory pretreatments are inadequate. A revised geochronology for the Mansion Series is described and a cautionary discussion is presented for the benefit of investigators using radiocarbon ages to date volcanic deposits.     

Historic Dead Sea Level Fluctuations Calibrated with Geological and Archaeological Evidence

The Dead Sea, the Holocene terminal lake of the Jordan River catchment, has fluctuated during its history in response to climatic change. Biblical records, calibrated by radiocarbon-dated geological and archaeological evidence, reinforce and add detail to the chronology of the lake-level fluctuations. There are three historically documented phases of the Dead Sea in the Biblical record: low lake levels ca. 2000–1500 B.C.E. (before common era); high lake levels ca. 1500–1200 B.C.E.; and low lake levels between ca. 1000 and 700 B.C.E. The Biblical evidence indicates that during the dry periods the southern basin of the Dead Sea was completely dry, a fact that was not clear from the geological and archaeological data alone.     

华北地台北缘成矿带大青山绿岩型金矿地质特征

本文详细阐述了大青山地区绿岩型金矿的地质特征和找矿标志,指出金矿化带赋存在二道洼群大理岩与其它岩层的接触部位,同时受韧性剪切带控制,在大理岩褶曲部位或下层位有利于形成较富矿体。该类型金矿的发现,大大地拓展了在大青山地区的找矿空间。     

Fluvial sediment transport and deposition following the 1991 eruption of Mount Pinatubo

The 1991 eruption of Mount Pinatubo generated extreme sediment yields from watersheds heavily impacted by pyroclastic flows. Bedload sampling in the Pasig–Potrero River, one of the most heavily impacted rivers, revealed negligible critical shear stress and very high transport rates that reflected an essentially unlimited sediment supply and the enhanced mobility of particles moving over a smooth, fine-grained bed. Dimensionless bedload transport rates in the Pasig–Potrero River differed substantially from those previously reported for rivers in temperate regions for the same dimensionless shear stress, but were similar to rates identified in rivers on other volcanoes and ephemeral streams in arid environments. The similarity between volcanically disturbed and arid rivers appears to arise from the lack of an armored bed surface due to very high relative sediment supply; in arid rivers, this is attributed to a flashy hydrograph, whereas volcanically disturbed rivers lack armoring due to sustained high rates of sediment delivery. This work suggests that the increases in sediment supply accompanying massive disturbance induce morphologic and hydrologic changes that temporarily enhance transport efficiency until the watershed recovers and sediment supply is reduced.     

Chemical, Isotopic, and Fluid Inclusion Evidence for the Hydrothermal Alteration of the Footwall Rocks of the BIF-Hosted Iron Ore Deposits in the Hamersley District, Western Australia

Abstract. The petrography, chemical, fluid inclusion and isotope analyses (O, Rb-Sr) were conducted for the shale samples of the Mount McRae Shale collected from the Tom Price, Newman, and Paraburdoo mines in the Hamersley Basin, Western Australia. The Mount McRae Shale at these mines occurs as a footwall unit of the secondary, hematite-rich iron ores derived from the Brockman Iron Formation, one of the largest banded iron formations (BIFs) in the world. Unusually low contents of Na, Ca, and Sr in the shales suggest that these elements were leached away from the shale after deposition. The δ¹⁸O (SMOW) values fall in the range of + 15.0 to +17.9 per mil and show the positive correlation with calculated quartz/sericite ratios of the shale samples. This suggests that the oxygen isotopic compositions of shale samples were homogenized and equilibrated by postdepositional event. The pyrite nodules hosted by shales are often rimmed by thin layers of silica of varying crystallinity. Fluid inclusions in quartz crystals rimming a pyrite nodule show homogenization temperatures ranging from 100 to 240C for 47 inclusions and salinities ranging from 0.4 to 12.3 wt% NaCl equivalent for 18 inclusions. These fluid inclusion data give direct evidence for the hydrothermal activity and are comparable to those of the vein quartz collected from the BIF-derived secondary iron ores (Taylor et al, 2001). The Rb-Sr age for the Mount McRae Shale is 1,952 ± 289 Ma and at least 200 million years younger than the depositional age of the Brockman Iron Formation of ∼ 2.5 Ga in age. All the data obtained in this study are consistent with the suggestion that high temperature hydrothermal fluids were responsible for both the secondary iron ore formation and the alteration of the Mount McRae Shale.     

A late quaternary record of eolian silt deposition in a maar lake, St. Michael Island, western Alaska

Recent stratigraphic studies in central Alaska have yielded the unexpected finding that there is little evidence for full-glacial (late Wisconsin) loess deposition. Because the loess record of western Alaska is poorly exposed and not well known, we analyzed a core from Zagoskin Lake, a maar lake on St. Michael Island, to determine if a full-glacial eolian record could be found in that region. Particle size and geochemical data indicate that the mineral fraction of the lake sediments is not derived from the local basalt and is probably eolian. Silt deposition took place from at least the latter part of the mid-Wisconsin interstadial period through the Holocene, based on radiocarbon dating. Based on the locations of likely loess sources, eolian silt in western Alaska was probably deflated by northeasterly winds from glaciofluvial sediments. If last-glacial winds that deposited loess were indeed from the northeast, this reconstruction is in conflict with a model-derived reconstruction of paleowinds in Alaska. Mass accumulation rates in Zagoskin Lake were higher during the Pleistocene than during the Holocene. In addition, more eolian sediment is recorded in the lake sediments than as loess on the adjacent landscape. The thinner loess record on land may be due to the sparse, herb tundra vegetation that dominated the landscape in full-glacial time. Herb tundra would have been an inefficient loess trap compared to forest or even shrub tundra due to its low roughness height. The lack of abundant, full-glacial, eolian silt deposition in the loess stratigraphic record of central Alaska may be due, therefore, to a mimimal ability of the landscape to trap loess, rather than a lack of available eolian sediment.