全文获取类型
收费全文 | 257篇 |
免费 | 39篇 |
国内免费 | 43篇 |
专业分类
测绘学 | 3篇 |
大气科学 | 44篇 |
地球物理 | 35篇 |
地质学 | 200篇 |
海洋学 | 32篇 |
天文学 | 4篇 |
综合类 | 6篇 |
自然地理 | 15篇 |
出版年
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 7篇 |
2020年 | 9篇 |
2019年 | 5篇 |
2018年 | 5篇 |
2017年 | 11篇 |
2016年 | 12篇 |
2015年 | 3篇 |
2014年 | 18篇 |
2013年 | 14篇 |
2012年 | 7篇 |
2011年 | 4篇 |
2010年 | 13篇 |
2009年 | 13篇 |
2008年 | 25篇 |
2007年 | 17篇 |
2006年 | 17篇 |
2005年 | 15篇 |
2004年 | 9篇 |
2003年 | 13篇 |
2002年 | 16篇 |
2001年 | 15篇 |
2000年 | 16篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 10篇 |
1996年 | 1篇 |
1995年 | 3篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 3篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 4篇 |
1986年 | 3篇 |
1985年 | 3篇 |
1983年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有339条查询结果,搜索用时 15 毫秒
1.
电感耦合等离子体发射光谱法同时测定玻璃中铝钙铁钾镁钠钛硫 总被引:2,自引:2,他引:0
通过选择分析谱线、处理样品方法和消除干扰因素等实验,建立了电感耦合等离子体发射光谱法同时测定玻璃中的Al2O3、CaO、Fe2O3、K2O、MgO、Na2O、TiO2和SO3的方法,克服了利用常规化学法测定玻璃中各氧化物步骤繁琐、耗时长、工作量大的不足。方法的回收率为95.0%~103.0%,精密度(RSD,n=10)为0.20%~1.72%。方法具有快速、简便、线性范围宽等优点,分析误差满足常规化学分析法的要求。用于钠钙硅玻璃及其制品的分析,结果令人满意。 相似文献
2.
Conventional understanding of the nitrogen cycle in marine sediments has changed in recent years with the discovery of an alternative pathway for ammonia oxidation via the reduction of manganese oxides (during anoxic nitrification). In anoxic sediments, the potential for manganese oxides to serve as oxidant for nitrification may be considerable yet previous work on manganese-rich sediments has suggested anoxic nitrification may not be significant. In this study, the potential for anoxic nitrification in a range of sediment types was investigated. Laboratory incubation of sediment from three sites on the Humber Estuary, a microbially diverse environment, showed anoxic accumulation of nitrate, nitrite and dinitrogen gas, with and without the addition of synthetic manganese oxides. Incubation experiments confirmed anoxic nitrification as microbially mediated, with heat-killed controls yielding negative results. The anoxic nitrification reaction significantly depleted ammonia concentrations, and occurred simultaneously with manganese-, iron- and sulphate reduction, and methanogenesis. Taken in conjunction with other studies, results suggest anoxic nitrification may not only be dependent on total manganese concentrations but on manganese dynamics. Anoxic nitrification may be explained as a non-steady state reaction, dependent on the recent stability of a sediment system. Physical perturbation of sediments may cause the redistribution and/or introduction of manganese oxides and promote anoxic nitrification. The significance and persistence of anoxic nitrification is likely to depend on the frequency and magnitude of sediment perturbation, which explains why the reaction varies so widely across studied sites, and why it may not occur in some manganese-rich sediment. 相似文献
3.
4.
Effects of irrigation on geochemical processes in a paddy soil and in ground waters in Camargue (France) 总被引:2,自引:0,他引:2
In waterlogged soils, dynamics of water influence the redox conditions and thus the mobility of elements. Irrigation of rice in Camargue (South eastern France) induces yearly dynamics of water. In order to determine the impact of irrigation on the geochemical properties of ground waters, a continuously in situ record of physico-chemical parameters (pH, Eh, temperature and electric conductivity) is performed during 1 year in an irrigated rice field. Seasonal dynamics show large Eh and pH variations. An annual irrigation cycle generates fast precipitations of Ca–Mg carbonates and Fe oxides between 50 and 110 cm depth when the soil is waterlogged. The dissolution of these minerals is initiated during a year without irrigation. 相似文献
5.
Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24
The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales (Peng et al., 2004), the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals: V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios (Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr) and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks. 相似文献
6.
Authigenic albites in carbonate rocks typically grow in a high-grade diagenetic to low-grade metamorphic environment and often show Roc-Tourné-twinning sensu Füchtbauer. Based on an investigation of four Middle to South European occurrences, they show Mn2+- and Fe3+-activated cathodoluminescence (CL), as revealed by combined high resolution spectroscopy of cathodoluminescence emission (HRS-CL), electron paramagnetic resonance (EPR), and proton-induced X-ray emission (μPIXE). 相似文献
7.
细菌浸铜技术在紫金山铜矿的应用 总被引:4,自引:0,他引:4
介绍了生物浸矿技术在紫金山铜矿的应用及在这一过程中发现的一些问题,并提出了有待进一步解决的一些问题。 相似文献
8.
灰色系统理论预测大气氮氧化物污染的应用 总被引:11,自引:0,他引:11
根据中国南方某省所辖城市近年来N0x污染指数的测量数据的统计资料,建立了GM(1,1)灰色预测模型,通过预测探讨了大气中氮氧化物指数的变化趋势。所建模型残差仅1.17%,关联系数为0.9067,精度较高,具有较好的可行性和适应性,可以为管理规则提供决策依据。 相似文献
9.
吉林省土壤中有效锰、铜、钼和锌含量的时空变化 总被引:5,自引:0,他引:5
选择吉林省的五个大豆种植区(敦化、桦甸、榆树、农安、白城)、四个水稻种植区(白城、九台、延吉、梅河口)及3个草场分布区(镇赉、洮南、大安),对其土壤中有效锰、铜、钼和锌的含量在过去20年的变化作了比较和分析。经研究表明:吉林省土壤中有效锰和有效铜含量较20年前有所增高,有效钼含量总体呈降低趋势,中部部分地区和东部地区土壤有效锌含量降低,其余地区含量增高。空间分布东部高于中西部。 相似文献
10.
S. Solberg T. Krognes F. Stordal OØ Hov H. J. Beine D. A. Jaffe K. C. Clemitshaw S. A. Penkett 《Journal of Atmospheric Chemistry》1997,28(1-3):209-225
Simultaneousindependent measurements of NOy and NOx(NOx= NO + NO2) by high-sensitivitychemiluminescence systems and of PAN (peroxyacetylnitrate) and PPN (peroxypropionyl nitrate) by GC-ECDwere made at Spitsbergen in the Norwegian Arcticduring the first half year of 1994. The average mixingratio of the sum of PAN and PPN (denoted PANs)increased from around 150 pptv in early winter to amaximum of around 500 pptv in late March, whereasepisodic peak values reached 800 pptv. This occurredsimultaneously with a maximum in ozone which increasedto 45–50 ppbv in March–April. The average NOxmixing ratio was 27 pptv and did not show any cyclethrough the period. The NOy mixing ratio showeda maximum in late March, while the difference betweenNOy and PAN decreased during spring. This is anindication of the dominance of PAN in the NOybudget in the Arctic, but possible changes in theefficiency of the NOy converter could alsocontribute to this. Although most PAN in theArctic is believed to be due to long range transport,the observations indicate local loss and formationrates of up to 1–2 pptv h-1 in April–May.Measurements of carbonyl compounds suggest thatacetaldehyde was the dominant, local precursor ofPAN.Now at 1. 相似文献