Stable isotopic signature of a palaeoaquifer, Mississippian Alamogordo Member limestones, Sacramento Mountains, New Mexico, USA

Nine stratigraphic sections, each ≈5 m thick, were sampled from the Alamogordo Member limestones of the Lake Valley Formation, Sacramento Mountains, New Mexico, USA. Four stratigraphic sections consist entirely of lime mudstone and wackestone, whereas the other five sections have a prominent layer of crinoidal packstone about 1 m thick at their base. Stable isotopic analyses reveal that the lime muds in the sections with basal packstone layers show a downward decrease in δ¹⁸O and constant δ¹³C values, whereas those in the sections solely composed of lime mudstone and wackestone have, in general, relatively uniform δ¹⁸O and δ¹³C values. The diagenesis of the Alamogordo Member limestones was previously believed to have been governed by the downward percolation of meteoric water from a regional pre-Pennsylvanian exposure surface ≈100 m above this unit. However, the uniform δ¹³C and downward decrease in δ¹⁸O values in the lime muds in the sections with basal packstones indicate that the meteoric water ascended within the Alamogordo Member, rather than descended from the overlying exposure surface. This indicates that the basal packstones were probably a conduit for meteoric water. This is further supported indirectly by the relatively uniform δ¹⁸O and δ¹³C values of the lime mud in the sections without basal packstones. The implications are that the oxygen isotopic gradients may be used to identify palaeoaquifers, flow directions within these aquifers and that meteoric diagenesis below an exposure surface could be governed by flow through a palaeoaquifer.     

Isotopic constraints on growth conditions of multiphase calcite–pyrite–barite concretions in Carboniferous mudstones

Carbonate concretions in the Lower Carboniferous Caton Shale Formation contain diagenetic pyrite, calcite and barite in the concretion matrix or in different generations of septarian fissures. Pyrite was formed by sulphate reduction throughout the sediment before concretionary growth, then continued to form mainly in the concretion centres. The septarian calcites show a continuous isotopic trend from δ¹³C=?28·7‰ PDB and δ¹⁸O=?1·6‰ PDB through to δ¹³C=?6·9‰ PDB and δ¹⁸O=?14·6‰ PDB. This trend arises from (1) a carbonate source initially from sulphate reduction, to which was added increasing contributions of methanogenic carbonate; and (2) burial/temperature effects or the addition of isotopically light oxygen from meteoric water. The concretionary matrix carbonates must have at least partially predated the earliest septarian cements, and thus used the same carbonate sources. Consequently, their isotopic composition (δ¹³C=?12·0 to ?10·1‰ PDB and δ¹⁸O=?5·7 to ?5·6‰ PDB) can only result from mixing a carbonate cement derived from sulphate reduction with cements containing increasing proportions of carbonate from methanogenesis and, directly or indirectly, also from skeletal carbonate. Concretionary growth was therefore pervasive, with cements being added progressively throughout the concretion body during growth. The concretions contain barite in the concretion matrix and in septarian fissures. Barite in the earlier matrix phase has an isotopic composition (δ³⁴S=+24·8‰ CDT and δ¹⁸O=+16·4‰ SMOW), indicating formation from near‐surface, sulphate‐depleted porewaters. Barites in the later septarian phase have unusual isotopic compositions (δ³⁴S=+6 to +11‰ CDT and δ¹⁸O=+8 to +11‰ SMOW), which require the late addition of isotopically light sulphate to the porewaters, either from anoxic sulphide oxidation (using ferric iron) or from sulphate dissolved in meteoric water. Carbon isotope and biomarker data indicate that oil trapped within septarian fissures was derived from the maturation of kerogen in the enclosing sediments.     

Elucidating hydrological complexity and climate-influenced diagenesis during the early Carboniferous of South Wales

A revised age provided by conodonts from the Gilwern Oolite of the Clydach area of South Wales allows a clearer understanding of the palaeohydrology, palaeoclimatic history and diagenesis of previously correlated oolitic units. Earlier uncertainty over the apparent sub-regional differences in climate during the early Visean (Chadian—Arundian) lowstand is resolved. Previously a humid interval evidenced by prominent palaeo-epikarst capping the Gilwern Oolite along the northern outcrops of the South Wales synclinorium, was not recognized in what were regarded as correlative outcrops in the Chadian Gully Oolite in the southern part of the synclinorium. Conodont dating now shows that the Gilwern Oolite is much older (Courceyan) than the Chadian Gully Oolite, and during the prolonged exposure of the former there was an interval of weathering under a humid climate. This also explains the contrast between the diagenesis seen between the Gilwern and Gully oolites, which are no longer seen as correlatives.     

Pendleian (early Serpukhovian) marine carbonates from SW Spain: sedimentology,biostratigraphy and depositional model

The San Antonio–La Juliana tectono‐sedimentary unit contains the only Namurian marine carbonates in the southwestern part of the Iberian Peninsula. The analysis of this unit is fundamental in understanding the sedimentary evolution and tectonic movements which operated during the Namurian in this area. Using foraminifera the succession has been assigned to two biozones (Zones 17 and 18), both occurring in the Pendleian (early Namurian). Seven stratigraphic sections have been analysed: San Antonio, Burjadillo, Lavadero de la Mina, Cornuda, Lozana, Caridad and Via Crucis. The stratigraphic succession of the San Antonio–La Juliana Unit consists of olistolites in the basal part, with common debris‐flow deposits (mainly of carbonates, with minor siliciclastic rocks), and turbidites, all of them embedded in shales. These rocks, interpeted as slope deposits, pass up into shallow‐water platform facies, with sediments characteristic of the inner platform and tidal flats. Above these rocks, terrigenous deltaic deposits occur. Thus, the stratigraphic sections show an overall shallowing‐upward trend. The isolation of some outcrops, and the duplication and absence of some parts of the stratigraphic succession are explained by tectonic movements. Overall, tectonic factors seem to be the main control rather than glacio‐eustatic or autocyclic processes, and sedimentation took place in a strike‐slip regime. Copyright © 2004 John Wiley & Sons, Ltd.     

Coal resource potential of Afghanistan

abstract

Coal exploration in Afghanistan has focused exclusively on expanding the boundaries of the known Jurassic coal deposits. The systematic stratigraphic and sedimentologic studies needed to locate and characterize new prospects in other parts of the country have never been conducted. Exploration strategies are based on received wisdom formulated before tectonic theory developed, and do not incorporate current understanding of the geologic and environmental processes responsible for peat formation and burial. This analysis reassesses existing data and limited new field reconnaissance data using modern tectonic and coal geology concepts to provide a new understanding of Afghanistan’s true coal potential. Afghanistan assembled during the Phanerozoic from a minimum of 11 microcontinental fragments, 5 arc systems, 3 accretionary wedges, and 2 rift systems. An unknown number of additional Precambrian terranes with separate tectonic histories are exposed in the cores of the Phanerozoic microcontinents. All of the Phanerozoic microcontinents separated from the disintegrating Gondwanaland. Each transited equatorial latitudes prior to accreting to Asia. From a purely theoretical standpoint, peat could have accumulated on every fragment during its equatorial transit. Mississippian, Triassic, Jurassic, Cretaceous, Oligocene, and Pliocene coals and carbonaceous shales are known. Triassic, Jurassic, and Pliocene deposits have been mined, but only the economically important Jurassic outcrops have been studied to any detail. Graphite-rich Precambrian strata are common from the Mesoarchean to the Neoproterozoic, and a Neoproterozoic bone coal was encountered while drilling for copper near Kabul. Jurassic and potentially Triassic and Carboniferous coals may underlie a significant percentage of the North Afghan Platform. Jurassic coals are extremely gassy and are known hydrocarbon source rocks across most of Central Asia. In Afghanistan, where these coal systems are closer to the surface, they could be coalbed methane reservoir rocks.     

U–Pb detrital zircon evidence of transcontinental sediment dispersal: provenance of Late Mississippian Wedington Sandstone member,NW Arkansas

ABSTRACT

U–Pb ages of detrital zircons from the Wedington Sandstone member in northwest Arkansas provide evidence for Late Mississippian westward transcontinental sediment transport from the Appalachian foreland. The Late Mississippian Wedington Sandstone member of the Fayetteville Shale is a fine- to medium-grained quartzarenite. It separates the Fayetteville Shale into informal lower and upper intervals, and was deposited as a small constructive delta complex that prograded towards the south and southeast during the Late Mississippian. As a major influx of clastic sediments, the Wedington Sandstone member records the sediment source and dispersal in the mid-continent during the Late Mississippian. A total of 559 detrital zircon grains from six Wedington samples were recovered for U–Pb detrital zircon geochronological analysis. Results show that age distributions can be subdivided into six groups: ~350–500, ~900–1350, ~1360–1500, ~1600–1800, ~1800–2300, and > ~2500 Ma, and are characterized by a prominent peak for the age group of ~900–1350 Ma, a major peak at ~1600–1800 Ma, and a few other minor age clusters. Regional correlation and geological evidence from surrounding areas suggest that the transcontinental sediment dispersal started as early as the Late Mississippian. U–Pb detrital zircon age distribution suggests that the Wedington Sandstone member was likely derived from the Appalachian foreland with contributions from the Nemaha Ridge to the west where the Yavapai–Mazatzal sources were exposed during the Late Mississippian. Sediment was likely transported westward through or around the Illinois Basin, merged with mid-continent sediment, and then entered into its current location in northwest Arkansas. Transportation of this sediment from mixed sources continued along its course to the south, forming a delta on the Northern Arkansas Structural Platform.     

Late Viséan–Serpukhovian foraminiferans and calcareous algae from the Adarouch region (central Morocco), North Africa

Three Upper Viséan to Serpukhovian limestone formations from the Adarouch region (central Morocco), North Africa, have been dated precisely using foraminiferans and calcareous algae. The lower and middle part of the oldest formation, the Tizra Formation (Fm), is assigned to the latest Asbian (upper Cf6γ Subzone), and its upper part to the Early Brigantian (lower Cf6δ Subzone). The topmost beds of this formation are assigned to the Late Brigantian (upper Cf6δ Subzone). The lower part of the succeeding Mouarhaz Fm is also assigned to the Late Brigantian (upper Cf6δ Subzone). The Akerchi Fm is younger than the other formations within the region, ranging from the latest Brigantian (uppermost Cf6δ Subzone) up to the Serpukhovian (E₁–E₂). The base of the Serpukhovian (Pendleian Substage, E₁) is repositioned, to coincide with the appearance of a suite of foraminiferans including Archaediscus at tenuis stage, Endothyranopsis plana, Eostaffella pseudostruvei, Loeblichia ukrainica, Loeblichia aff. minima and Biseriella? sp. 1. The upper Serpukhovian (Arnsbergian Substage, E₂) is marked by the first appearance of Eostaffellina ex. gr. paraprotvae and Globoomphalotis aff. pseudosamarica. The biostratigraphical scheme used for the reassessment of the foraminiferal zones and subzones in the Adarouch area closely compares with that for the British succession in northern England (Pennine Region), where the stratotypes of the Upper Viséan (Asbian and Brigantian) and Early Serpukhovian (Pendleian) substages are located. Thus, a succession equivalent to an interval from the Melmerby Scar Limestone to the Great (or Little) Limestone is recognized. These assemblages are also compared to other foraminiferal zones proposed in other regions of Morocco. Several foraminiferans have been identified that are proposed as potential Serpukhovian markers for other basins in Western Europe, and compared to sequences in Russia and the Donets Basin, Ukraine. Copyright © 2008 John Wiley & Sons, Ltd.     

Protophyllocladoxylon jingyuanense sp.nov.,a Gymnospermous Wood of the Serpukhovian (Late Mississippian) from Gansu,Northwest China

<正>A new species of gymnospermous fossil wood,Protophyllocladoxylon jingyuanense sp.nov., is described from the lower part of the Tsingyuan Formation(Serpukhovian/Late Mississippian),near the coal mine of Ciyao,Gansu,northwestern China.The specimen is preserved only in silicified secondary xylem,while growth rings are absent.Pits in radial tracheidal walls are araucaroid in type, uniseriate,occasionally biseriate.Xylem rays are homogeneous,uniseriate,occasionally biseriate. Cross-field pits are simple,large,one to two in number.Axial parenchyma is absent.The anatomical characters and geographic distribution of Protophyllocladoxylon woods through geological ages are documented.Those species with axial parenchyma and without growth rings live in warm climate, whereas the species without axial parenchyma and with growth rings are present either in warm or cool climate.The ideal living climate for Protophyllocladoxylon woods is warm and wet.Our new species,as a fossil wood of Early Carboniferous,is likely the earliest known species of Protophyllocladoxylon.     

Mississippian foraminifers from the Onimaru Formation in the Hikoroichi area, South Kitakami Belt, Northeast Japan

Abundant foraminifers were found from the Mississippian Onimaru Formation distributed in the Hikoroichi area of the central part of the South Kitakami Belt, Northeast Japan. They include Brunsia pulchra, Archaediscus sp., Paraarchaediscus? sp., Neoarchaediscus? sp., Palaeotextularia spp., Climacammina, spp., Tetrataxis spp., Haplophragmella sp., Lituotubella? sp., Forschiella sp., Cribrospira sp., Bradyina spp., Janischewskina sp., Endothyra spp., Planoendothyra aljutovica., Endothyranopsis compressa, E. crassa, Omphalotis samarica, Eo-staffella spp., Mediocris breviscula, and several others. The Onimaru foraminiferal fauna is similar to those re-ported from MFZ (Mamet Foraminiferal Zone) 15-16. This supports a late Visean (V3b-V3c) age of the formation, which has been proposed previously by rugose corals.