华北地台中元古代碳酸盐岩中的微生物成因构造及其生烃潜力

华北地台中元古界主要由环潮坪石英砂岩、浅海碳酸盐岩和浅海—泻湖相暗色页岩3种沉积相组合构成,以陆表海浅水碳酸盐岩占主导。碳酸盐岩中除含有丰富的微古植物、宏观藻类和微生物建隆外,还发育大量的微生物成因构造(MISS)和微生物诱发的碳酸盐沉淀(MMCP)。微生物席和MISS构造在高于庄组上部(约1.6 Ga)和雾迷山组下部(约1.45 Ga)碳酸盐岩中尤为发育,表明活跃的微生物活动和高有机质产量。在石化微生物席中,发现有丝状、球状细菌化石和草莓状黄铁矿;围岩中发现有针状文石、花瓣状重晶石、放射状菱铁矿、铁白云石和葡萄状碳酸盐胶结物等多种自生碳酸盐矿物,指示甲烷厌氧氧化(AOM)导致的自生碳酸盐沉淀。中元古代的温暖气候和海洋分层、缺氧、硫化条件有利于微生物的高生产量和高有机质埋藏率。气隆构造和核形石状碳酸盐结核反映浅埋藏条件下活跃的成烷作用和甲烷排放,围岩和MMCP中富沥青质。华北地台中元古界富微生物席碳酸盐岩有良好的生烃潜力,有可能形成重要的烃源岩。据微生物席、MISS构造及MMCP的研究,初步估算华北地台中元古代碳酸盐岩的概略生烃潜力约为10×108t石油当量。     

The bimodal rift-related Juscelândia volcanosedimentary sequence in central Brazil: Mesoproterozoic extension and Neoproterozoic metamorphism

The Barro Alto Complex and Juscelândia volcanosedimentary sequence are exposed in the central part of the Neoproterozoic Brasília belt of central Brazil. The former is a large (approximately 150 km long), boomerang-shaped, mafic-ultramafic, layered complex formed by two different intrusions metamorphosed under granulite facies. These rocks are tectonically overlain by rocks of the Juscelândia volcanosedimentary sequence, represented mainly by biotite-gneiss and amphibolite, or amphibolite facies metamorphic equivalents of rhyolite and basalt, respectively. New SIMS U–Pb zircon data and Sm–Nd isochron data presented herein help clarify the igneous and metamorphic evolution of the Juscelândia volcanosedimentary sequence, as well as its relationship with the Barro Alto Complex. Zircon grains from two biotite gneisses were analyzed by SIMS (SHRIMP) and indicate Mesoproterozoic dates, approximately 1.28 Ga, interpreted as the time of bimodal volcanism in a tectonic setting transitional between a continental rift and an ocean basin. Metamorphism is constrained by Sm–Nd garnet-whole-rock isochrons for garnet amphibolite and pelitic schists of the Juscelândia sequence, as well as for clinopyroxene-garnet amphibolite and garnet granulite of the Barro Alto Complex, which give ages between 0.74 and 0.76 Ga, in agreement with SIMS dates for metamorphic zircon rims. These new data are significant, because they establish that a single metamorphic event affected both the Barro Alto Complex and the Juscelândia sequence. Based on these new data, we present a modified tectonic model for the Brasília belt.     

燕山地区中元古代常州沟组潜穴化石

在燕山地区中元古代常州沟组中发育有大量的潜穴化石，潜穴产于常州沟组中部的泥质粉砂岩中。潜穴呈个体较大的直管状，垂直层面保存。这是我国迄今为止发现的最古老的遗迹化石，表明在距今近1800Ma前就已出现古老的后生动物，这对于研究后生动物的起源及演化具有重要意义。     

华北燕山裂陷槽中元古代的深水沉积

对燕山沉降带中元古代的沉积相，有关学者大多定位于以滨海－浅海相为主体。根据在冀北地区的研究，于中元古代团山子组、高于庄组、杨庄组、雾迷山组、洪水庄组和铁岭组中发现大量深水沉积，主要有硅质页岩、含锰页岩、深水浊积岩及各种碳酸盐岩溶解相的系列沉积等。这对于深入研究燕山裂陷槽发展演化具有重要意义。     

Hydrothermal Mineralization on the Mesoproterozoic Passive Continental Margins of China： A Case Study of the Langshan-Zha＇ertaishan Belt, Inner Mongolia, China

Most ore-forming characteristics of the Langshan-Zha‘ertaishan hydrothermal exhalation belt, which consists of the Dongshengmiao, Huogeqi, Tanyaokou and Jiashengpan large-superlarge Zn-Pb-Cu-Fe sulfide deposits, are most similar to those of Mesoproterozoic SEDEX-type provinces of the world. The characteristics include: (1) All deposits of this type in the belt occur in third-order fault-basins in the Langshan-Zha‘ertaishan aulacogen along the northern margin of the North China Platform; (2) these deposits with all their orebodies hosted in the Mesoproterozoic impure dolomite-marble and carbonaceous phyllite (or schists) have an apparent stratabound nature; ores display laminated and banded structures, showing clear depositional features; (3) there is some evidence of syn-sedimentary faulting, which to a certain extent accounts for the temporal and spatial distribution and the size of the orebodies in all deposits and the formation of intrabed conglomerates and breccias; (4) they show lateral and vertical zonation of sulfides; (5) The Cu/(Pb Zn Cu) ratio of the large and thick Pb Zn Cu orebodies gradually decreases from bottom to top; and (6) barite is interbedded with pyrites and sometimes with sphalerite. However, some characteristics such as the Co/Ni radio of the pyrites, the volcanism, for example, of the Langshan-Zha‘ertalshan metallogenic belt, are different from those of the typical SEDEX deposits of the world. The meta-basic volcanic rock in Huogeqi, the sodic bimodal volcanic rocks in the Dongshengmiao and potassic bimodal-volcanic rocks with blastoporphyfitic and blasto-glomeroporphyritic texture as well as blasto-amygdaloidal structure in the Tanyaokou deposits have been discovered in the only ore-bearing second formation of the Langshan Group in the past 10 years. The metallogeny of some deposits hosted in the Langshan Group is closely related to syn-sedimentary volcanism based on the following facts: most of the lead isotopes in sphalerite, galena, pyrite, pyrrhotite and chalcopyrite plot on both sides of the line for the mantle or between the lines for the mantle and lower crust in the lead isotope composition diagram; cobalt content of some pyrites samples is much higher than the nickel content (Co/Ni= 11.91-12.19). Some volcanic blocks and debris have been picked out from some pyritic and pyrrhotitic ores. All Zn-Pb-Cu-Fe sulfide orebodies in these deposits occur in the strata overlying metamorphic volcanic rocks in the only ore-bearing second formation. In the Jiashengpan deposit that lacks syn-sedimentary volcanic rocks in the host succession only Pb and Zn ores occur without Cu ore, but in the Dongshengmiao, Tanyaokou and Huogeqi deposits with syn-sedimentary volcanic rocks in the host succession Cu ores occur. This indicates a relatively higher ore-forming temperature. The process of synsedimentary volcanic eruption directly supplied some ore-forming elements, and resulted in secular geothermal anomaly favorable for the circulation of a submarine convective hydrothermal system, which accounts for the precipitation of deep mineralizing fluids exhaling into anoxidic basins along the syn-sedimentary fault system in the Langshan-Zha‘ertai rift. The Dongshengmiao, Tanyaokou, and Huogeqi deposits hosted in the Langshan Group appear to be a transitional type of mineral deposit between SEDEX and VMS-types but with a bias towards SEDEX, while the Jiashengpan deposit hosted in the Zha‘ertai Group is of a characteristic SEDEX type. This evidence, together with other new discoveries of Mesoproterozoic volcanic rocks and the features of lithogeny and metallogeny of the Bayun Obo deposit in the neighborhood emphasize the diversity, complexity and uniqueness of the Mesoproterozoic Langshan-Zha‘ertal-Bayun Obo ore belt.     

First estimate for the age of a mesoproterozoic palaeomagnetic pole from the Volodarsk-Volynsky Massif,the Ukrainian Shield

Palaeomagnetic data are presented from the southern Volodarsk-Volynsky Massif (VVM) of the Korosten Pluton, the Ukrainian Shield. Laboratory experiments (AF and thermal demagnetization, IRM acquisition, thermal separation), field tests (consistency and secular variation methods) and optical observations indicate that single domain and nearly single domain magnetite is the dominant carrier of a primary TRM in the anorthosites. Palaeomagnetic poles from the three sampling sites (Golovino and Turchinka quarries) are indistinguishable at the 95% confidence level and have been combined to yield a mean pole at P_lat = 30 °N, P_lon = 178 °E, a₉₅ = 3.4 °.In the large slow cooling Korosten Pluton the U-Pb zircon/baddeleyite (U_zb) technique gives an age for the anorthosites, which are not equivalent to the time of magnetic blocking. Based on integrated analysis of geochronologic information and blocking-temperature data for magnetic minerals proposed by Briden et al. (1993), a first attempt has been undertaken to estimate the palaeomagnetic pole age from the Mesoproterozoic anorthosites. The Korosten Pluton has cooled from 850 °C (the closure temperature of U-Pb systematics in zircon/baddeleyite) to 350 °C (the closure temperature of K-Ar systematics in biotite) during 150 Ma after the emplacement of the anorthosites. Assuming a uniform cooling of the intrusion yields a rate of 3.3 °C/Ma. The cooling rate for the granites is 3.1 °C/Ma. The mafic and acid rocks have an average rate of 3.2 °C/Ma. Using the cooling gradient for the VVM (3.2 °C/Ma) and the mean natural blocking temperature of magnetite (520 °C) can be determined a remanence age. The estimate for TRM acquisition is 1656 ± 10.0 Ma.The magnetic pole for the VVM is in good agreement with the mean pole from the Baltic quartz porphyry dykes with an age of 1630 – 1648 Ma. The VVM pole is best dated and requires a revision of the latest paleogeographic reconstructions for the Fennoscandian and Ukrainian Shields at 1770 and 1650 Ma. (Pesonen et al., 2003).     

燕山中段南麓蓟县北部常州沟-杨庄一带地质构造基本特征

在燕山中段南麓的蓟县北部山区有着中国国家地质公园，中国北方中-新元古代正层型剖面标志碑就耸立在那里。对这一地区基本地质事实和地质体真实位态的研究，不仅关系着对华北地区晚前寒武纪标准剖面可靠性的评价，也关系着燕山运动命名地的基本地壳结构的合理解析和我国北方中生代以来构造一岩浆活动序列的正确建立。本文展示的基础地质调查成果可揭示：蓟县北部常州沟-杨庄一带的地质结构构造远不是我国大多数地学学者们对此描述的那样简单。调查区约200km。面积可代表燕山中段南麓的大面积中-新元古界分布区的基本地质结构构造特征。已识别出的18条断层和由其限制的21个以上构造岩片的现实位态表明，该地区地壳上部是由多个复杂地块堆叠构成的，主体构造形成于燕山晚期，在形成方式上以大规模多次不同方向运移的薄皮构造岩片叠覆为主要特征。     

Using Mesoproterozoic sedimentary geochemistry to reconstruct basin tectonic geography and link organic carbon productivity to nutrient flux from a Northern Australian large igneous Province

The Beetaloo Sub-basin, northern Australia, is considered the main depocentre of the 1,000-km scale Mesoproterozoic Wilton package of the greater McArthur Basin – the host to one of the oldest hydrocarbon global resources. The ca. 1.40–1.31 Ga upper Roper Group and the latest Mesoproterozoic to early Neoproterozoic unnamed group of the Beetaloo Sub-basin, together, record ca. 500 million years of depositional history within the North Australia Craton. Whole-rock shale Sm–Nd and Pb isotope data from these sediments reveal sedimentary provenance and their evolution from ca. 1.35 to 0.85 Ga. Furthermore, these data, together with shale major/trace elements data from this study and pyrolysis data from previous publications, are used to develop a dynamic tectonic geography model that links the organic carbon production and burial to an enhanced weathering of nutrients from a large igneous province. The ca. 1.35–1.31 Ga Kyalla Formation of the upper Roper Group is composed of isotopically evolved sedimentary detritus that passes up, into more isotopically juvenile Pb values towards the top of the formation. The increase in juvenile compositions coincides with elevated total organic carbon (TOC) contents of these sediments. The coherently enriched juvenile compositions and TOC the upper portions of the Kyalla Formation are interpreted to reflect an increase in nutrient supply associated with the weathering of basaltic sources (e.g. phosphorous). Possible, relatively juvenile, basaltic sources include the Wankanki Supersuite in the western Musgraves and the Derim Derim–Galiwinku large igneous province (LIP). The transition into juvenile, basaltic sources directly before a supersequence-bounding unconformity is here interpreted to reflect uplift and erosion of the Derim Derim–Galiwinku LIP, rather than an influx of southern Musgrave sources. A new baddeleyite crystallisation age of 1,312.9 ± 0.7 Ma provides both a tight constraint on the age of this LIP, along with its associated magmatic uplift, as well as providing a minimum age constraint for Roper Group deposition. The unconformably overlying lower and upper Jamison sandstones are at least 300 million years younger than the Kyalla Formation and were sourced from the Musgrave Province. An up-section increase in isotopically juvenile compositions seen in these rocks is interpreted to document the progressive exhumation of the western Musgrave Province. The overlying Hayfield mudstone received detritus from both the Musgrave and Arunta regions, and its isotopic geochemistry reveals affinities with other early Neoproterozoic basins (e.g. Amadeus, Victoria and Officer basins), indicating the potential for inter-basin correlations.     

Mesoproterozoic Earthquake Events and Breakup of the Sino-Korean Plate

In the Mesoproterozoic time, the northern part of the Sino-Korean Plate experienced a period of intensive tectonic extension and breakup. 1. An abundance of sedimentary earthquake records is preserved in the Chuanlinggou, Tuanshanzi and Gaoyuzhuang formations in the Mesoproterozoic Changcheng System （1800-1400 Ma） and in the Mesoproterozoic Wumishan Formation of the Jixian System （1400-1000 Ma）. These earthquake records are characterized by various liquefied sand-veins, carbonate microspar and coarser spar veins, limestone dikes, liquefied breccia and various forms of liquefied contorted bedding. This deformation is always associated with synsedimentary faults and igneous activity. 2. Three liquefaction models for soft carbonate sediments are recognized, including liquefaction in laminated carbonate rocks, liquefaction in thin-bedded carbonates and large-scale liquefaction along huge carbonate dikes. 3. Based on the record of earthquake and volcanic activities, the Sino-Korean Plate experienced at least twice intraplate breakups. One occurred between 1800-1400 Ma, and the other occurred at about 1200 Ma. The last breakup resulted in formation of the Yan-Liao aulacogen, a tectonic zone characterized by deeper material vibrancy, active faults, major igneous activity and frequent earthquakes.     

Mesoproterozoic Fraser Complex: Geochemical evidence for multiple subduction‐related sources of lower crustal rocks in the Albany‐Fraser Orogen,Western Australia

The 1300 Ma Fraser Complex in the Albany‐Fraser Orogen of Western Australia is a thrust stack of mainly gabbroic rocks metamorphosed to granulite facies. This package of fault‐bounded units was elevated from a deep crustal level onto the margin of the Yilgarn Craton during continental collision between the Mawson and Yilgarn Cratons. Incompatible trace‐element distributions demand at least three mantle sources. Primitive‐mantle‐normalised incompatible‐element distributions show strong negative Ta–Nb anomalies, typical of subduction‐derived magmas. Three lines of evidence indicate that the mafic magmas did not acquire these anomalies by assimilation of crustal rocks: (i) major‐element compositions do not allow appreciable contamination with felsic material; (ii) Ni contents of many mafic rocks are too high for a significant contribution from a felsic assimilant; and (iii) Sr and Nd isotopic data support a largely juvenile source for the magmas that produced the Fraser Complex. Hence, the Ta–Nb anomalies are interpreted to reflect subduction‐related magmatic sources. On multielement diagrams, depletions in Sr, Eu, P, and Ti can be explained by fractional crystallisation, whereas Th and Rb depletions in many of the Fraser Complex rocks probably reflect losses during granulite‐facies metamorphism. These results suggest that the lower crust in this region at 1300 Ma was dominantly of arc origin, and there is no evidence to support mantle plume components. The Fraser Complex is interpreted as remnants of oceanic arcs that were swept together and tectonically interleaved with the margin of the Mawson Craton just before, or during, collision with the Yilgarn Craton at 1300 Ma.