Determination of Sr/Sr mass-dependent isotopic fractionation and radiogenic isotope variation of Sr/Sr in the Neoproterozoic Doushantuo Formation

We measured both mass-dependent isotope fractionation of δ⁸⁸Sr (⁸⁸Sr/⁸⁶Sr) and radiogenic isotopic variation of Sr (⁸⁷Sr/⁸⁶Sr) for the Neoproterozoic Doushantuo Formation that deposited as a cap carbonate immediately above the Marinoan-related Nantuo Tillite. The δ⁸⁸Sr and ⁸⁷Sr/⁸⁶Sr compositions showed three remarkable characteristics: (1) high radiogenic ⁸⁷Sr/⁸⁶Sr values and gradual decrease in the ⁸⁷Sr/⁸⁶Sr ratios, (2) anomalously low δ⁸⁸Sr values at the lower part cap carbonate, and (3) a clear correlation between ⁸⁷Sr/⁸⁶Sr and δ⁸⁸Sr values. These isotopic signatures can be explained by assuming an extreme greenhouse condition after the Marinoan glaciation. Surface seawater, mixed with a large amount of freshwater from continental crusts with high ⁸⁷Sr/⁸⁶Sr and lighter δ⁸⁸Sr ratios, was formed during the extreme global warming after the glacial event. High atmospheric CO₂ content caused sudden precipitation of cap carbonate from the surface seawater with high ⁸⁷Sr/⁸⁶Sr and lighter δ⁸⁸Sr ratios. Subsequently, the mixing of the underlying seawater, with unradiogenic Sr isotope compositions and normal δ⁸⁸Sr ratios, probably caused gradual decrease of the ⁸⁷Sr/⁸⁶Sr ratios of the seawater and deposition of carbonate with normal δ⁸⁸Sr ratios. The combination of ⁸⁷Sr/⁸⁶Sr and δ⁸⁸Sr isotope systematics gives us new insights on the surface evolution after the Snowball Earth.     

The Carrancas Formation,Bambuí Group: A record of pre-Marinoan sedimentation on the southern São Francisco craton,Brazil

The Carrancas Formation outcrops in east-central Brazil on the southern margin of the São Francisco craton where it comprises the base of the late Neoproterozoic Bambuí Group. It is overlain by the basal Ediacaran cap carbonate Sete Lagoas Formation and was for a long time considered to be glacially influenced and correlative with the glaciogenic Jequitaí Formation. New stratigraphic, isotopic and geochronologic data imply that the Carrancas Formation was instead formed by the shedding of debris from basement highs uplifted during an episode of minor continental rifting. Reddish dolostones in the upper Carrancas Formation have δ¹³C values ranging from +7.1 to +9.6‰, which is a unique C isotopic composition for the lowermost Bambuí Group but similar to values found in the Tijucuçu sequence, a pre-glacial unit in the Araçuaí fold belt on the eastern margin of the São Francisco craton. The stratigraphic position below basal Ediacaran cap carbonates and the highly positive δ¹³C values together indicate a Cryogenian interglacial age for the Carrancas Formation, with the high δ¹³C values representing the so-called Keele peak, which precedes the pre-Marinoan Trezona negative δ¹³C excursion in other well characterized Cryogenian sequences. Hence, The Carrancas Formation pre-dates de Marinoan Jequitaí Formation and represents an interval of Cryogenian stratigraphy not previously known to occur on the southern margin of São Francicso craton. Documentation of Cryogenian interglacial strata on the São Francisco craton reinforces recent revisions to the age of Bambuí Group strata and has implications for the development of the Bambuí basin.     

新元古代冰期及其年代

新元古代在全球范围内出现了几期冰期事件,称之为“雪球地球”事件。这种剧烈的环境变化带来此后地球上生命演化的一次飞跃。“雪球地球”事件的核心是全球冰期的同时性,需要同位素地质年代学的证据。新元古代末期两次主要的冰期事件是Marinoan冰期和Sturtian冰期,其中Marinoan冰期结束于635Ma;Sturtian冰期可能发生在710～720Ma,已发表的年龄数据限定它在670Ma之前结束。Marinoan冰期后的Gaskiers冰期发生在580～590Ma。对华南的古城、铁丝坳、长安组、江口组等进行进一步精确定年,将对限定Sturtian冰期持续时间和Cryogenian、南华系的下限年龄具有重要意义。     

Coupling between metallogenesis of the Cryogenian Datangpo-type manganese deposit in South China and major geological events

The exploration of the Cryogenian manganese deposits in the Datangpo Formation of South China has achieved great progress in recent years. It is concern in the long term there are many studies on this manganese deposits due to its particularity in the temporal and spatial distribution and the mineralization background. In this paper,we systematically summarize the previous achievements on the Datangpo-type manganese deposits. Besides,we also review current findings of Neoproterozoic global geotectonics,palaeoclimate evolution,ancient marine chemistry,and microbial evolution etc. The possible linkage between the massive metallogenesis of the Cryogenian Datangpo manganese deposits in the South China and Neoproterozoic major geological events is established. The break-up of Rodinia supercontinent led to the widespread rift basin systems in the world since the Middle Neoproterozoic. The Nanhua Basin in South China,which is a manganese-forming sedimentary basin,developed from the rift basin. The rift basin provided space for manganese deposits and controlled the distribution of manganese deposit. The hydrothermal activities at the bottom of the basin provided favorable manganese source. During the Neoproterozoic ice period(“Snowball Earth”event),global ice-sheets cut off or hindered exchanges of mass and energy between different spheres of Earth,which may lead to the widespread anoxic condition in the ice age ocean. The palaeoclimate changes during the glacial-interglacial period led to the disappearance of ice-sheets and the triggering of mass and energy exchanges between different sub-systems of Earth,followed by the variation of redox condition of the ancient sea. For the Nanhua Basin,the oxidation of surface water and the oxygen-bearing base flow provided the oxidation environment for the precipitation of manganese. Besides,new evidence indicated that manganese microbiological mineralization was the potential mechanism for manganese deposit under the microbial resuscitation condition during the interglacial period. All these major geological events have complicated connections and they provided essential metallogenic conditions for the sedimentary mineralization of “Datangpo”manganese deposit. It is believed that there is a coupling between the sedimentary metallogenesis of the Cryogenian Datangpo-type manganese deposit in South China and Neoproterozoic major geological events.     

Explosive volcanic eruptions triggered by cosmic rays: Volcano as a bubble chamber

Volcanoes with silica-rich and highly viscous magma tend to produce violent explosive eruptions that result in disasters in local communities and that strongly affect the global environment. We examined the timing of 11 eruptive events that produced silica-rich magma from four volcanoes in Japan (Mt. Fuji, Mt. Usu, Myojin-sho, and Satsuma-Iwo-jima) over the past 306 years (from AD 1700 to AD 2005). Nine of the 11 events occurred during inactive phases of solar magnetic activity (solar minimum), which is well indexed by the group sunspot number. This strong association between eruption timing and the solar minimum is statistically significant to a confidence level of 96.7%. This relationship is not observed for eruptions from volcanoes with relatively silica-poor magma, such as Izu-Ohshima. It is well known that the cosmic-ray flux is negatively correlated with solar magnetic activity, as the strong magnetic field in the solar wind repels charged particles such as galactic cosmic rays that originate from outside of the solar system. The strong negative correlation observed between the timing of silica-rich eruptions and solar activity can be explained by variations in cosmic-ray flux arising from solar modulation. Because silica-rich magma has relatively high surface tension (~ 0.1 Nm^?1), the homogeneous nucleation rate is so low that such magma exists in a highly supersaturated state without considerable exsolution, even when located relatively close to the surface, within the penetration range of cosmic-ray muons (1–10 GeV). These muons can contribute to nucleation in supersaturated magma, as documented by many authors studying a bubble chamber, via ionization loss. This radiation-induced nucleation can lead to the pre-eruptive exsolution of H₂O in the silica-rich magma. We note the possibility that the 1991 Mt. Pinatubo eruption was triggered by the same mechanism: an increase in cosmic-ray flux triggered by Typhoon Yunya, as a decrease in atmospheric pressure results in an increase in cosmic-ray flux. We also speculate that the snowball Earth event was triggered by successive large-scale volcanic eruptions triggered by increased cosmic-ray flux due to nearby supernova explosions.     

Glaciation and ~ 770 Ma Ediacara (?) Fossils from the Lesser Karatau Microcontinent,Kazakhstan

The Cambrian explosion, c. 530–515 Ma heralded the arrival of a diverse assembly of multicellular life including the first hard-shelled organisms. Fossils found in Cambrian strata represent the ancestors of most modern animal phyla. In contrast to the apparent explosiveness seen in the Cambrian fossil record, studies of molecular biology hint that the diversification observed in Cambrian strata was rooted in ancestry extending back into the Ediacaran (635–542 Ma). Fossil evidence for this mostly cryptic phase of evolution is derived from the soft-bodied fossils of the Ediacaran biota found throughout the world and bilaterian embryos found in the Doushantuo lagerstätte in South China. The first appearance of Ediacara fauna is thought to have followed the last of the ~ 750–635 Ma Neoproterozoic glacial episodes by 20–30 million years. In this paper, we present evidence for the oldest discovery of the ‘Ediacara’ discoidal fossils Nimbia occlusa and Aspidella terranovica (?) that predate the early Cryogenian glaciations by more than fifty million years. There is considerable disagreement over the significance of discoidal Ediacaran fossils, but our findings may support earlier suggestions that metazoan life has roots extending deeper into the Proterozoic Eon. We also confirm the presence of a Late Cryogenian (e.g. “Marinoan”) glaciation on the Lesser Karatau microcontinent including dropstones and striated clasts within the glacial strata.     

Nature and significance of the Neoproterozoic Sturtian–Marinoan Boundary,Northern Adelaide Geosyncline,South Australia

The Cryogenian succession of the Northern Flinders Ranges reveals a complex sedimentary record between the Sturtian and Marinoan glacial deposits. A major unconformity separates the Sturtian and Marinoan-aged sedimentary successions in the area. This forms a subaerial erosion surface with terrestrial and marginal marine infill directly above the Angepena and Balcanoona Formations in their respective localities. This exposure surface is here correlated with the previously documented submarine unconformity between the Yankaninna Formation and the underlying deep marine Tapley Hill Formation. This erosional event provides a chronostratigraphic marker horizon that coincides approximately with thepreviously defined Sturtian–Marinoan Time Series boundary in the Northern Flinders Ranges. These stratigraphic relationships also constrain lateral facies relationships between the Oodnaminta ReefComplex (Balcanoona Formation) and the Angepena Formation. Similarly, the shallow-water Weetootla Dolomite is correlated with the deeper water carbonates of the Yankaninna Formation.     

Rodinia超大陆构造演化研究的新进展和主要目标

概略评述了1997年以来国际上有关Rodinia超大陆构造演化问题的研究成果，并提出今后工作的主要目标。Rodinia超大陆的聚合造山发生在1300－1000Ma，基本形式表现为早期弧一陆碰撞和晚期陆－陆碰撞，并在1000－900Ma继以伸展作用。Rodinia超大陆的裂解发生于830Ma之后，但其过程具有明显的时，空分布不均一性，地幔柱可能是导致超大陆裂解的主要机制，大火成岩省”是地幔柱发育的关键性标志，已经初步证实裂解过程影响地球大气圈和水圈中二氧化碳的循环，进而改变晚前寒武纪的全球气候，控制生物圈的兴衰和岩石圈表层的碳酸盐，铁，锰和磷等沉积，这些现象可用“雪球化地球”（Snowball Earth)模式概括。     

中南地区南华纪地层序列及对重大地质事件的响应

罗迪尼亚超大陆裂解、雪球地球、锰铁成矿作用耦合是南华纪重大地质事件。中南地区南华纪地层广泛分布,自北而南沉积类型丰富,本文以冰期沉积、锰矿层和铁矿层为标志,以同位素年龄为格架,厘定了南华纪岩石地层和年代地层序列,自北而南对比了超大陆裂解事件、斯图特冰期、马里诺冰期、成锰事件、成铁事件、火山事件和早期生命演化事件沉积的差异性。本文认为中南地区南华系表现为两次冰期和一次间冰期的沉积特征,下铁上锰、南铁北锰的时空格局揭示了裂谷的演化历程。建议进一步聚焦南华系存在的关键地质问题,加强锰铁成矿作用与全球重大地质事件的响应关系调查研究,为新一轮找矿突破战略行动提供理论支撑。     

Ca isotopic compositions of dolomite, phosphorite and the oldest animal embryo fossils from the Neoproterozoic in Weng'an, South China

Deciphering the drastic changes of surface environment and the emergence of animals after the Neoproterozoic Snowball Earth event are important for understanding the changes of surface environment and its influence on the evolution of life through geologic time. Especially, the emergence of two types of Metazoan animals such as animal embryo fossils, cnidarians or sponges, and Ediacaran fauna in the late Neoproterozoic was one of the critical turning points in the biological evolution.Calcium is one of the essential elements for the growth of most animals. In this study, in order to evaluate the Ca cycles in the Neoproterozoic, we have measured Ca isotopic ratios (⁴⁴Ca/⁴²Ca and ⁴³Ca/⁴²Ca) for phosphorite, dolostone and phosphatic animal embryo fossils with a multiple collector, inductively coupled plasma-mass spectrometer (MC-ICP-MS). The resulting ⁴⁴Ca/⁴²Ca ratio defined by the relative deviation from the ratio of NIST SRM915a (δ^44/42Ca_NIST915) for phosphorite and dolostone ranges from 0.83 to 0.95‰, demonstrating that the fractionation between phosphorite/dolostone and seawater was very small. This evidence indicates that at the emergence of the Weng'an biota seawater was deficient in Ca probably due to mass deposition of phosphorite/dolostone and to the beginning of Ca-biomineralization.Three phosphatic animal embryo fossils have lower δ^44/42Ca values than the phosphorite and dolomite, implying that the precursor of the phosphatic embryo fossils was able to fractionate Ca isotopes through Ca-biomineralization, consistent with marine gastropods.