The Mordor Alkaline Igneous Complex,Central Australia: PGE-enriched disseminated sulfide layers in cumulates from a lamprophyric magma

The Mordor Alkaline Igneous Complex (MAIC) is a composite intrusion comprising a body of syenite and a funnel-shaped layered mafic–ultramafic intrusion of lamprophyric parentage, the Mordor Mafic–Ultramafic Intrusion or MMUI. The MMUI is highly unusual among intrusions of lamprophyric or potassic parentage in containing primary magmatic platinum-group element (PGE)-enriched sulfides. The MMUI sequence consists largely of phlogopite-rich pyroxenitic cumulates, with an inward dipping conformable layer of olivine-bearing cumulates divisible into a number of cyclic units. Stratiform-disseminated sulfide accumulations are of two types: disseminated layers at the base of cyclic units, with relatively high PGE tenors; and patchy PGE-poor disseminations within magnetite-bearing upper parts of cyclic units. Sulfide-enriched layers at cycle bases contain anomalous platinum group element contents with grades up to 1.5 g/t Pt+Pd+Au over 1-m intervals, returning to background values of low parts per billion (ppb) on a meter scale. They correspond to reversals in normal fractionation trends and are interpreted as the result of new magma influxes into a continuously replenished magma chamber. Basal layers have decoupled Cu and PGE peaks reflecting increasing PGE tenors up-section, due to increasing R factors during the replenishment episode, or progressive mixing of between resident PGE-poor magma and more PGE-enriched replenishing magma. The presence of PGE enriched sulfides in cumulates from a lamprophyric magma implies that low-degree partial melts do not necessarily leave sulfides and PGEs in the mantle restite during partial melting. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

广西佛子冲铅锌矿田成岩成矿时代研究

广西佛子冲铅锌矿田位于桂东南博白-岑溪多金属成矿带的NE端,区内发育燕山期花岗岩、花岗闪长岩、二长花岗斑岩和英安质凝灰熔岩等;其中花岗闪长岩和二长花岗斑岩与铅锌成矿关系密切,成矿岩体形成时代分别为156Ma和127Ma。     

Trace metals in suspended particulate matter and in sediment trap material from a permanently anoxic fjord — Framvaren, South Norway

Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite.     

Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.     

Mineralogy, geochemistry, and Nd isotope composition of the Rainbow hydrothermal field, Mid-Atlantic Ridge

Petrological, geochemical, and Nd isotopic analyses have been carried out on rock samples from the Rainbow vent field to assess the evolution of the hydrothermal system. The Rainbow vent field is an ultramafic-hosted hydrothermal system located on the Mid-Atlantic Ridge characterized by vigorous high-temperature venting (∼365°C) and unique chemical composition of fluids: high chlorinity, low pH and very high Fe, and rare earth element (REE) contents (Douville et al., Chemical Geology 184:37–48, 2002). Serpentinization has occurred under a low-temperature (<270°C) retrograde regime, later overprinted by a higher temperature sulfide mineralization event. Retrograde serpentinization reactions alone cannot reproduce the reported heat and specific chemical features of Rainbow hydrothermal fluids. The following units were identified within the deposit: (1) nonmineralized serpentinite, (2) mineralized serpentinite—stockwork, (3) steatite, (4) semimassive sulfides, and (5) massive sulfides, which include Cu-rich massive sulfides (up to 28wt% Cu) and Zn-rich massive sulfide chimneys (up to 5wt% Zn). Sulfide mineralization has produced significant changes in the sulfide-bearing rocks including enrichment in transition metals (Cu, Zn, Fe, and Co) and light REE, increase in the Co/Ni ratios comparable to those of mafic Cu-rich volcanic-hosted massive sulfide deposits and different ¹⁴³Nd/¹⁴⁴Nd isotope ratios. Vent fluid chemistry data are indicative of acidic, reducing, and high temperature conditions at the subseafloor reaction zone where fluids undergo phase separation most likely under subcritical conditions (boiling). An explanation for the high chlorinity is not straightforward unless mixing with high salinity brine or direct contribution from a magmatic Cl-rich aqueous fluid is considered. This study adds new data, which, combined with the current knowledge of the Rainbow vent field, brings compelling evidence for the presence, at depth, of a magmatic body, most likely gabbroic, which provides heat and metals to the system. Co/Ni ratios proved to be good tools used to discriminate between rock units, degree of sulfide mineralization, and positioning within the hydrothermal system. Deeper units have Co/Ni <1 and subsurface and surface units have Co/Ni >1.     

Sulfur Content and Isotopic Ratio of Cambro-Ordovician Carbonate Rocks from South Korea: A Possible Source for Mesozoic Magmatic-hydrothermal Ore Sulfur

Abstract: Carbonate rocks of Cambrian (18 samples) and lower-middle Ordovician (11 samples) ages from South Korea were analyzed for sulfur contents of structurally substituted sulfate (SSS) and sulfides and their δ³⁴S values. The δ³⁴S values of SSS ranging from +25.9 to +45.2 permil, are averaged as +33.6 and +33.5 permil for the Cambrian and Ordovician rocks, respectively, which indicate high δ³⁴S values of the Cambro-Ordovician seawater. The SSS contents in the carbonate rocks are low being 2.9 to 17.3 ppm S (averaged as 7.0 ppm S). Sulfide sulfur, on the contrary, is much abundant containing 3 to 1,880 ppm S and the δ³⁴S values range widely between –17.6 and +31.1 permil. Sulfide sulfur of the studied rocks excluding impure carbonates has an average content of 187 ppm S and δ³⁴S value of +12.8 permil (n=24). The estimated δ³⁴S (sulfate–sulfide) values, which range from 13.8 to 25.4 permil in general with a few exceptions from 36.5 up to 52.3 permil for some impure carbonates, may provide evidence for the persistent oceanic anoxia with its temporary recovery during the Cambro-Ordovician time.
The SSS and sulfide sulfurs have often higher δ³⁴S values than the Mesozoic-Cenozoic ore sulfur (Ishihara et al., 2000). Since carbonate rocks are very reactive with circulating hydrothermal ore solution, high δ³⁴S values of the Korean ore deposits might be caused to some extent by ³⁴S enrichment from the host carbonates, resulting in the low SSS contents observed.     

Aeromagnetic signatures over western Marie Byrd Land provide insight into magmatic arc basement, mafic magmatism and structure of the Eastern Ross Sea Rift flank

Aeromagnetic signatures over the Edward VII Peninsula (E7) provide new insight into the largely ice-covered and unexplored eastern flank of the Ross Sea Rift (RSR). Positive anomalies, 10–40 km in wavelength and with amplitudes ranging from 50 to 500 nT could reveal buried Late Devonian(?)–Early Carboniferous Ford Granodiorite plutons. This is suggested by similar magnetic signature over exposed, coeval Admiralty Intrusives of the Transantarctic Mountains (TAM). Geochemical data from mid-Cretaceous Byrd Coast Granite, contact metamorphic effects on Swanson Formation and hornblende-bearing granitoid dredge samples strengthen this magnetic interpretation, making alternative explanations less probable. These magnetic anomalies over formerly adjacent TAM and western Marie Byrd Land (wMBL) terranes resemble signatures typically observed over magnetite-rich magmatic arc plutons. Shorter wavelength (5 km) 150 nT anomalies could speculatively mark mid-Cretaceous mafic dikes of the E7, similar to those exposed over the adjacent Ford Ranges. Anomalies with amplitudes of 100–360 nT over the Sulzberger Bay and at the margin of the Sulzberger Ice Shelf likely reveal mafic Late Cenozoic(?) volcanic rocks emplaced along linear rift fabric trends. Buried volcanic rock at the margin of the interpreted half-graben-like “Sulzberger Ice Shelf Block” is modelled in the Kizer Island area. The volcanic rock is marked by a coincident positive Bouguer gravity anomaly. Late Cenozoic volcanic rocks over the TAM, in the RSR, and beneath the West Antarctic Ice Sheet exhibit comparable magnetic anomaly signature reflecting regional West Antarctic Rift fabric. Interpreted mafic magmatism of the E7 is likely related to mid-Cretaceous and Late Cenozoic regional crustal extension and possible mantle plume activity over wMBL. Magnetic lineaments of the E7 are enhanced in maximum horizontal gradient of pseudo-gravity, vertical derivative and 3D Euler Deconvolution maps. Apparent vertical offsets in magnetic basement at the location of the lineaments and spatially associated mafic dikes and volcanic rocks result from 2.5D magnetic modelling. A rift-related fault origin for the magnetic lineaments, segmenting the E7 region into horst and graben blocks, is proposed by comparison with offshore seismic reflection, marine gravity, on-land gravity, radio-echo sounding, apatite fission track data and structural geology. The NNW magnetic lineament, which we interpret to mark the eastern RSR shoulder, forms the western margin of the “Alexandra Mountains horst”. This fundamental aeromagnetic feature lies on strike with the Colbeck Trough, a prominent NNW half-graben linked to Late Cretaceous(?) and Cenozoic(?) faulting in the eastern RSR. East–west and north–north–east to NE magnetic trends are also imaged. Magnetic trends, if interpreted as reflecting the signature of rift-related normal faults, would imply N–S to NE crustal extension followed by later northwest–southeast directed extension. NW–SE extension would be compatible with Cenozoic(?) oblique RSR rifting. Previous structural data from the Ford Ranges have, however, been interpreted to indicate that both Cretaceous and Cenozoic extensions were N–S to NE–SW directed.     

西秦岭中川花岗岩岩浆活动特征及地质效应

西秦岭中川花岗岩为3期5次侵入的复式岩体,其主侵入体为印支—燕山期黑云母同碰撞S型二长花岗岩。该岩浆活动在沉积建造中形成热变质作用带和岩浆侵位构造,并产生成矿地质效应。     

Characterisation of the 1997 Vulcanian explosions of Soufrière Hills Volcano,Montserrat, by video analysis

The activity of Convention at Montserrat Soufrière Hills Volcano, Montserrat, during the period 1995–1999 included numerous violent explosions. Two major cycles of Vulcanian explosions occurred in 1997: a first of 13 explosions between 4 and 12 August and a second of 75 between 22 September and 21 October. The explosions were short-lived events lasting a few tens of seconds during which partial fountain collapse generated pyroclastic surges and pyroclastic flows, and buoyant plumes ascended 3–15 km into the atmosphere. Each explosion discharged on average 3×10⁵ m³ (dense-rock equivalent, DRE) of magma, draining the conduit to depths of 1–2 km. The paper focuses on the first few seconds of three explosions of the 75 that occurred in September/October 1997: 6 October 1997 at 17:50, 7 October 1997 at 16:02 and 9 October 1997 at 12:32. Physical parameters such as exit velocities, magmatic water contents and magma pressures at fragmentation are estimated by following and modelling the ascent of individual momentum-dominated finger jets visible on videos during the initial stages of each explosion. The model treats each finger jet as an incompressible flow sustained by a steady flux of gas and particles during the few seconds of ascent, and produces results that compare favourably with those using a multiphase compressible code run using similar eruptive parameters. Each explosion reveals a progressive increase in eruptive intensity with time, jet exit velocities increasing from 40 m s^–1 at the beginning of the explosion up to 140 m s^–1 after a few seconds. Modelling suggests that the first magma to exit was largely degassed, whereas that discharged after a few seconds contained up to 2 wt% water. Magma overpressures up to ~10 MPa are estimated to have existed in the conduit immediately prior to each explosion. Progressive increases in jet exit velocity with time over the first few seconds of each explosion provide direct evidence for strong pre-eruptive gradients in water content and magma pressure in the upper reaches (probably 100–500 m) of the conduit. Fountain collapse occurred during the first 10–20 s of each explosion because the discharging jets had bulk densities up to 100 times that of the atmosphere and were unable to entrain enough air to become buoyant. Such high eruptive densities were due to the presence of partially degassed magma in the conduit.Editorial responsibility: A. Woods