Trace element distribution among rock-forming minerals from metamorphosed to partially molten basic igneous rocks in a contact aureole (Fuerteventura, Canaries)

Low pressure partial melting of basanitic and ankaramitic dykes gave rise to unusual, zebra-like migmatites, in the contact aureole of a layered pyroxenite–gabbro intrusion, in the root zone of an ocean island (Basal Complex, Fuerteventura, Canary Islands). These migmatites are characterised by a dense network of closely spaced, millimetre-wide leucocratic segregations. Their mineralogy consists of plagioclase (An_32–36), diopside, biotite, oxides (magnetite, ilmenite), +/− amphibole, dominated by plagioclase in the leucosome and diopside in the melanosome. The melanosome is almost completely recrystallised, with the preservation of large, relict igneous diopside phenocrysts in dyke centres. Comparison of whole-rock and mineral major- and trace-element data allowed us to assess the redistribution of elements between different mineral phases and generations during contact metamorphism and partial melting.

Dykes within and outside the thermal aureole behaved like closed chemical systems. Nevertheless, Zr, Hf, Y and REEs were internally redistributed, as deduced by comparing the trace element contents of the various diopside generations. Neocrystallised diopside – in the melanosome, leucosome and as epitaxial phenocryst rims – from the migmatite zone, are all enriched in Zr, Hf, Y and REEs compared to relict phenocrysts. This has been assigned to the liberation of trace elements on the breakdown of enriched primary minerals, kaersutite and sphene, on entering the thermal aureole. Major and trace element compositions of minerals in migmatite melanosomes and leucosomes are almost identical, pointing to a syn- or post-solidus reequilibration on the cooling of the migmatite terrain i.e. mineral–melt equilibria were reset to mineral–mineral equilibria.     

鲁西～2.6 Ga 深熔作用：泰山地区浅色脉体的野外地质和地球化学研究

泰山地区深熔作用十分发育,是鲁西～2.6 Ga 构造热事件的典型代表。广泛分布的2.6 Ga浅色脉体主要是片麻状英云闪长岩在水不饱和的条件下含水矿物发生脱水熔融形成,在局部地区存在水饱和熔融。根据浅色脉体岩相学和地球化学特征,可将其进一步划分为3种类型：具正Eu异常奥长岩浅色体、无明显Eu异常奥长花岗岩浅色体和具负 Eu 异常 花岗岩浅色体。矿物结晶分异对浅色体组成变化起了很大作用。由于有充足的时间和空间,部分斜长石较早结晶出来并聚集形成具正Eu异常的浅色体。剩余熔体继续运移过程中,斜长石、钾长石及石英近同时结晶,组成近等粒镶嵌结构,形成具负 Eu 异常的花岗岩浅色体。无明显 Eu 异常的浅色体最接近原始熔体。     

Ion probe dating of a migmatite in SW Sweden: the fate of zircon in crustal processes

A migmatitic orthogneiss in the Western Segment in the Sveconorwegian Province of the Baltic Shield was dated using the ion-probe U–Pb method on zircon grains, which were also analysed for rare earth elements. Mesosome zircons have 1.605±0.010 Ga magmatic cores, which places the gneiss protolith in the same 1.61–1.59 Ga time bracket as continental arc-related gneisses, abundant in this part of the Sveconorwegian Province. These cores show REE profiles with strong HREE enrichment, positive Ce- and negative Eu-anomalies, typical of magmatic zircon. Migmatite leucosomes are folded and parallel with or slightly discordant to the fabric. They contain a small population of zircon with cores and metamorphic rims, which are interpreted as xenocrysts incorporated in the leucosome during melting of the mesosome. CL-bright metamorphic embayments and rims on xenocrysts reflect 1.01±0.05 Ga Sveconorwegian metamorphic reworking. Ce-anomalies are nearly absent and Eu-anomalies are reduced relative to igneous spots. This is probably a feature of fluid controlled environments where Ce and Eu oxidation states are buffered by the metamorphic fluid. From this and discordant rims from the mesosome we also conclude that the rims formed by reworking of the older zircon where the Pb-loss was also fluid induced. In the leucosome veins, magmatic acicular zircon gives 0.92±0.01 Ga, ascribed to the crystallisation of the veins. They originated by local melting, probably augmented by magma that formed at a deeper level. Widespread granitic and noritic late-Sveconorwegian magmatism close to 0.92 Ga in other parts of the Western Segment has equivalents in the Norwegian sectors of the Sveconorwegian Province. Leucosome formation was therefore part of a regional event related to exhumation of the Sveconorwegian Eastern Segment. We also provide the first unequivocal evidence for ductile deformation related to late-Sveconorwegian magmatism.     

Spatial distribution of melt-bearing structures in anatectic rocks from Southern Brittany, France: implications for melt transfer at grain- to orogen-scale

In this study, we present quantitative spatial information on the one- and two-dimensional distribution of inferred melt-bearing structures in anatectic supracrustal rocks of the Southern Brittany Migmatite Belt, south of the transcurrent South Armorican Shear Zone (SASZ); based on these data, we infer the mechanism of melt extraction from partially molten crust. Former melt-bearing structures include foliation-parallel leucosomes and cross-cutting granitic leucosomes that infill inter-boudin partitions and extensional shear surfaces, as well as discordant dykes of granite. Petrographic (i.e., mineralogical and microstructural) continuity of granite from structure to structure suggests that they once formed a continuous melt-bearing network. Measurements along one-dimensional line traverses perpendicular to layering of stromatic migmatite exposed in clean, sub-horizontal outcrop surfaces provide information about thickness and spacing distributions of foliation-parallel leucosomes. Most leucosome thicknesses fall in the range of 1–10 mm, with upper limits around 20–30 mm. The number of thicker layers decreases abruptly with increasing thickness, which is inconsistent with scale-invariance. This suggests that leucosome formation was controlled by short-range melt movement along grain boundaries to form melt-rich layers constrained by pre-existing compositional layering. Spacing distributions also are not scale-invariant; however, the large percentage of leucosomes (40–60%) in these line traverses suggests that spacing distributions may be controlled in part by impingement of leucosomes, making it difficult to derive genetic information from these data. Qualitative observation of inferred melt-bearing structures in mutually perpendicular two-dimensional exposures from the same outcrop reveals anisotropy of the leucosome network related to a well-developed sub-horizontal quartz–feldspar lineation reflecting stretching associated with transcurrent movement along the SASZ. Analysis of these two-dimensional distributions using the box-counting method corroborates the observed anisotropy, but indicates that leucosome morphology (and perhaps distribution) is not scale-invariant. The applicability of the box-counting method, or of fractal analysis, to understanding melt movement in migmatites is discussed in light of these results. Based on the anisotropy of melt-bearing structures, we infer that melt-movement in structures now represented by layer-parallel leucosomes was primarily sub-horizontal. These layers fed steeply dipping structures now represented by cross-cutting leucosomes, in particular those developed at inter-boudin partitions, and granite dykes. The formation and orientation of these steeply dipping structures was in part controlled by far-field stresses related to dextral displacement along the SASZ. Melt extraction is inferred to have occurred along these steeply dipping structures; extracted melt accumulated in plutons at higher crustal levels, such as the Quiberon, Sarzeau, and Guérande granites.     

Partial melting of ultrahigh-pressure metamorphic rocks at convergent continental margins: Evidences,melt compositions and physical effects

Ultrahigh-pressure(UHP) metamorphic rocks are distinctive products of crustal deep subduction,and are mainly exposed in continental subduction-collision terranes. UHP slices of continental crust are usually involved in multistage exhumation and partial melting, which has obvious influence on the rheological features of the rocks, and thus significantly affect the dynamic behavior of subducted slices. Moreover,partial melting of UHP rocks have significant influence on element mobility and related isotope behavior within continental subduction zones, which is in turn crucial to chemical differentiation of the continental crust and to crust-mantle interaction.Partial melting can occur before, during or after the peak metamorphism of UHP rocks. Post-peak decompression melting has been better constrained by remelting experiments; however, because of multiple stages of decompression, retrogression and deformation, evidence of former melts in UHP rocks is often erased. Field evidence is among the most reliable criteria to infer partial melting. Glass and nanogranitoid inclusions are generally considered conclusive petrographic evidence. The residual assemblages after melt extraction are also significant to indicate partial melting in some cases. Besides field and petrographic evidence, bulk-rock and zircon trace-element geochemical features are also effective tools for recognizing partial melting of UHP rocks. Phase equilibrium modeling is an important petrological tool that is becoming more and more popular in P-T estimation of the evolution of metamorphic rocks; by taking into account the activity model of silicate melt, it can predict when partial melting occurred if the P-T path of a given rock is provided.UHP silicate melt is commonly leucogranitic and peraluminous in composition with high SiO_2,low MgO, FeO, MnO, TiO_2 and CaO, and variable K_2 O and Na_2 O contents. Mineralogy of nanogranites found in UHP rocks mainly consists of plagioclase + K-feldspar + quartz, plagioclase being commonly albite-rich.Trace element pattern of the melt is characterized by significant enrichment of large ion lithophile elements(LILE), depletion of heavy rare earth elements(HREE) and high field strength elements(HFSE),indicating garnet and rutile stability in the residual assemblage. In eclogites, significant Mg-isotope fractionation occurs between garnet and phengite; therefore, Mg isotopes may become an effective indicator for partial melting of eclogites.     

Geochemistry and zircon U-Pb ages of adakitic rocks from the Dulan area of the North Qaidam UHP terrane, north Tibet: Constraints on the timing and nature of regional tectonothermal events associated with collisional orogeny

Geochemistry and U-Pb ages of leucosomes and tonalites in a high pressure granulite unit of the Dulan area have been determined to constrain the tectonothermal evolution related to collision and thickening of lower crust in the North Qaidam Mountains (NQD). Leucosomes and tonalites show a marked chemical resemblance to adakites: (1) high La/Yb and Sr/Y, and low Y and HREE; (2) high Al₂O₃ and low Mg^# values with obvious positive Eu anomalies; and (3) slightly positive ε_Nd(t) values. Zircon U-Pb analysis of leucosomes and tonalites yielded ²⁰⁶Pb/²³⁸U ages of 428-437 Ma and 436-437 Ma respectively, which constrain the emplacement ages of the adakitic rocks. Petrological, geochronological and geochemical characters indicate that the adakitic rocks may have been derived from partial melting of a thickened mafic lower crust (> 50 km), suggesting a dominating source regime of synchronous high-pressure mafic granulites. Contemporary magmatism in other units of the NQD shows evidence of a widespread tectonothermal event during early Silurian (420-450 Ma) that includes metamorphism, magmatism and anatexis related to collision and thickening of lower crust.     

Water-assisted migmatization of metagraywackes in a Variscan shear zone, Aiguilles-Rouges massif, western Alps

Migmatitic rocks developed in metagraywackes during the Variscan orogeny in the Aiguilles-Rouges Massif (western Alps). Partial melting took place 320 Ma ago in a 500 m-wide vertical shear zone. Three leucosome types have been recognised on the basis of size and morphology: (1) large leucosomes > 2 cm wide and > 40 cm long lacking mafic selvage, but containing cm-scale mafic enclaves; (2) same as 1 but with thick mafic selvage (melanosome); (3) small leucosomes < 2 cm and < 40 cm) with thin dark selvages (stromatic migmatites). Types 1 + 2 have mineralogical and chemical compositions in keeping with partial melting experiments. But Type 3 leucosomes have identical plagioclase composition (An_19–28) to neighbouring mesosome, both in terms of major- and trace-elements. Moreover, whole-rock REE concentrations in Type 3 leucosomes are only slightly lower than those in the mesosomes, unlike predicted by partial melting experiments. The main chemical differences between all leucosome types can be related to the coupled effect of melt segregation and late chemical reequilibration.

Mineral assemblages and thermodynamic modelling on bulk-rock composition restrict partial melting to  650 °C at 400 MPa. The large volume of leucosome (20 vol.%) thus generated requires addition of 1 wt.% external water. Restriction of extensive migmatization to the shear zone, without melting of neighbouring metapelites, also points to external fluid circulation within the shear zone as the cause of melting.     

The S-type Ladybird leucogranite suite of southeastern British Columbia: Geochemical and isotopic evidence for a genetic link with migmatite formation in the North American basement gneisses of the Monashee complex

The 62–52 Ma Ladybird granite (LBG) suite is a peraluminous, leucocratic, S-type, quartz monzonitic to granitic suite which occurs as batholiths, stocks, dikes, sills, and pegmatite veins predominantly in the high-grade rocks of the Shuswap complex, in southeastern British Columbia. The emplacement of the LBG was synchronous with the production of abundant migmatites within Thor–Odin dome of the Monashee complex, an exposure of North American basement, exhumed from depths of ca. 26–33 km by Eocene extensional faults. The LBG and the leucosome in migmatites from Thor–Odin dome have similar major and trace element patterns, and are both characterized by zircons which have inherited Precambrian cores. Whole rock Nd isotope compositions show a range of values for the LBG with εNd_{(55 Ma)} values from − 5.0 to − 17.2. The εNd_{(55 Ma)} for the leucosome samples range from − 9.5 to − 23.6, overlapping with those of the granitic suite. These data support the interpretation of a genetic link between formation of the LBG suite and melting of North American basement rocks, such as those exposed in the core of Thor–Odin dome. The leucosome samples have lower high field strength element (HFSE) concentrations and positive Eu anomalies, whereas the LBG samples have higher HFSE concentrations and negative Eu anomalies. The similar trace element characteristics suggest that the leucosome from the migmatites and the LBG are related, whereby most of the leucosome samples are cumulates and the LBG samples represent evolved or residual melts. The initial ⁸⁷Sr/⁸⁶Sr isotope values for both the LBG and leucosome samples have a large range. However, the initial Sr isotopic ratios for the LBG suite are lower than those of the leucosome samples, with ⁸⁷Sr/⁸⁶Sr_{(55 Ma)} ranging from 0.70603 to 0.73688 and 0.74256 to 0.76593, respectively. This isotopic discrepancy suggests either: a) isotopic disequilibrium during partial melting in the mid- to lower crust where the leucosome formed, b) the distribution of Sr during partial melting was controlled by different melt-producing reactions, and/or c) isotopic heterogeneity in the source rocks. At least part of the LBG suite likely formed via melting of North American basement rocks that were dominantly of sedimentary origin. Melting of the Proterozoic supracrustal metasedimentary rocks overlying North American basement may also have contributed to the formation of the different phases of the suite found at the regional scale. However, the abundant leucosomes in the basement rocks of Thor–Odin dome may mark the paths along which anatectic melt migrated in the structurally overlying Ladybird granites of the South Fosthall pluton.