Geochemistry and environmental effect of cadmium in the super-large Jinding Pb-Zn deposit,Yunnan Province,China

The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment.     

云南省兰坪县凤岩山铅锌铜多金属矿地质特征及成因探讨

凤岩山铅锌铜多金属矿位于兰坪断陷盆地中部,是云南省乃至全国重要的铅锌成矿区之一,具有良好的成矿条件和找矿前景。本文通过对矿区地质背景条件、地质特征、地球化学异常特征、矿体特征、矿石特征的分析的研究,认为矿床成因应为后期热卤水为主改造叠加形成的,属沉积-改造层控型矿床。     

滇西沘江流域水体中重金属元素的地球化学特征

通过测定流经兰坪金顸铅锌矿区的沘江水体中Pb、Zn、Cd、As的含量和底泥中重金属元素的化学形态的含量,分析了重金属元素的分布和化学形态的变化。结果表明,沘江水遭到了Cd污染,底泥已经成为重金属元素的蓄积库,以国家土壤环境质量标准（Ⅲ级）衡量,Pb、Zn、Cd和舡分别超标3．4倍、15．8倍、106倍和2．6倍。沘江水中重金属元素含量的峰值在矿山附近的下游,而底泥中重金属元素的峰值在矿山下游30-50km的地方,矿业活动、水流变缓、pH等水体环境条件的变化都能影响水和底泥中重金属元素的含量。底泥中的Pb以碳酸盐结合态为主,Zn和Cd以铁锰氧化物结合态为主,而As以残渣态为主。Pb、Cd、Zn三种元素的环境有效态含量比较高,对沘江流域生态环境具有潜在的巨大的危害。     

REE Geochemistry of the Lead—Zinc Ores from the Jinding Lead—Zinc Deposit,Lanping,Yunnan

Nineteen volcanic and magmatic rock samples were collectecd from the Jinding leadzinc deposit and its surrounding areas in Yunnan.The ICP and AES analyses,feferred to the previous results,show that the metal minerals and altered rocks in the Jinding lead-zinc deposit display a decreasing trend of ∑REE from the early to late stages of mineralization,and similarities in REE distribution patterns,indicating that the ore fluids are characterized by high LREE enrichment,markedly negative δCe anomaly and slight δEu anomaly.These REE distribution paterns exhibit striking similarities to those of the Pliocene trachyte in the study area,both of which are similar in ∑REE,LREE/HREE ratio,δEu and δCe.The ore fluids besides the basin fluids in the deposit are also closely related to those associated with Pliocene trachyte magmas.     

云南兰坪北部铜多金属矿化区成矿流体流动与矿化分带——流体包裹体和稳定同位素依据

滇西兰坪盆地北部发育了一类受逆冲推覆构造控制的浅成热液Cu—Ag—Pb-Zn矿化，形成了白秧坪、富隆厂、吴底厂、麻栗坪及金满、科登涧等大-中型矿床和矿点，并存在矿化分带。文章利用这些矿化脉体的流体包裹体和热液方解石的碳氧同位素组成资料，研究成矿流体与矿化分带的关系。结果表明，成矿流体主要属于NaCl-H2O成分体系，盐度ω(NaCleq)为2％～11％，形成温度为170～300℃，形成于1．8～3．8km深度内，这些相似性说明这类矿化的发生具有相似的流体性质和沉淀机制。热液方解石在δ^13C-δ^18O图解中呈近水平线展布的型式，指示流体源自地壳浅部的地下水系统，与海相灰岩等围岩作用形成了溶解碳以[HCO3^]-为主的成矿流体，流体与岩石的相互作用可能是成矿流体沉淀的主要机理。从西到东，流体包裹体的盐度-温度由高到低变化与矿化分带和逆冲推覆构造的根带→中带→锋带相配套，显示重力驱动流动可能是主要的流体流动机制。成矿流体在不同构造部位流动的通畅及流体．岩石系统的封闭-开放程度等流体流动性质与矿化发生的强度和规模有关，兰坪北部逆冲推覆构造中带的流体通畅地流动及沉淀时处于相对开放状态，有利于该区形成较大规模的浅成热液多金属矿化。     

兰坪白秧坪铜银多金属矿床成矿物质来源的铅和硫同位素示踪

白秧坪铜银多金属矿床主要产于白垩系下统景星组石英砂岩、粉砂岩中，矿石铅同位素组成特征与景星组砂岩的铅同位素组成比较接近，表明壳源物质参与了成矿作用。作ZartMan图解和△γ—△β图解表明，矿石铅属于壳幔混合来源。矿石铅μ值介于9．43—9．65之间，Th/U比值介于3．72—3．87之间，表明矿石铅为壳幔混合铅。该矿床硫同位素组成表明，硫来源于深部地幔硫遭受地壳硫的混入。该矿床的成矿作用发生于开放体系之中，成矿物质来源为深部幔源物质混合了壳源物质。     

滇西兰坪盆地金顶铅锌矿盐构造发育特征及其与成矿关系

滇西兰坪中新生代盆地广泛发育盐岩层系。通过对金顶超大型铅锌矿区的露天采厂和地下采坑的最新野外调查及大量钻孔资料的综合分析,研究区盐岩层系具有多期、多阶段运动的特点,厚度分布极不均一,它们作为区域推覆构造作用的滑脱层,对盐上层构造变形起着重要控制作用,形成一系列储矿构造。研究表明,矿区盐构造主要包括盐枕、盐背斜、盐焊接、盐穿刺、盐推覆、盐岩滑脱-断层相关褶皱组合等多种盐构造变形样式。这些盐构造的形成演化及变形机制主要受到推覆挤压缩短作用、基底断层作用和塑性流动汇聚作用、盐下和盐上层断裂滑脱作用等控制,主要沿推覆断裂构造带呈串珠状分布。金项矿区盐构造分为两个阶段:古新世–始新世挤压–拗陷层内变形阶段,形成盐枕、隆升较低的盐背斜等整合型盐构造;渐新世的逆冲推覆–盐岩滑脱阶段,受强烈的挤压推覆作用而形成盐墙、盐株等盐穿刺型构造。盐构造不同阶段的变形演化对金属元素富集成矿起到关键作用,其流动变形而形成的盐构造圈闭促使了金属聚集成矿。     

滇西马登地区晚二叠世-早三叠世地层组合及年代学:火山岩锆石U-Pb定年证据

在西南"三江"造山带中段的兰坪盆地内,由于露头状况不好,盆地基底岩石出露状况不详,导致地层划分、归属相当混乱。详细的野外地质调查揭示,盆地东缘马登地区出露的基底岩石主要由2个构造地层单元组成,上部为火山-沉积序列,下部为浅海相泥岩、灰岩及生物碎屑灰岩。上部火山-沉积序列出露厚约1200m,可分为4个喷发-沉积韵律,由英安质熔岩、流纹质熔岩与晶屑凝灰岩、火山集块岩、火山角砾岩、流纹质凝灰岩、火山碎屑岩及少量泥岩相间组成。火山岩锆石LAICP-MS U-Pb法测年数据显示,岩浆活动始于250Ma,持续至244Ma,总体处于早三叠世,构成江达-维西-云县弧火山岩带的一部分。强烈变形的海相地层与火山岩二者呈断层接触,其时代老于250Ma。结合砂岩中碎屑锆石年龄结果(大于260Ma)判定,这套沉积岩应属于晚二叠世,其与早三叠世-中三叠世火山岩一起组成兰坪盆地的基底岩石。     

Metallogeny of the Baiyangping Lead‐Zinc Polymetallic Ore Concentration Area,Northern Lanping Basin of Yunnan Province,China

The Lanping Basin in the Nujiang‐Lancangjiang‐Jinshajiang (the Sanjiang) area of northeastern margin of the Tibetan Plateau is an important part of eastern Tethyan metallogenic domain. This basin hosts a number of large unique sediment‐hosted Pb‐Zn polymetallic deposits or ore districts, such as the Baiyangping ore concentration area which is one of the representative ore district. The Baiyangping ore concentration area can be divided into the east and west ore belts, which were formed in a folded tectogene of the India‐Asia continental collisional setting and was controlled by a large reverse fault. Field observations reveal that the Mesozoic and Cenozoic sedimentary strata were outcropped in the mining area, and that the orebodies are obviously controlled by faults and hosted in sandstone and carbonate rocks. However, the ore‐forming elements in the east ore belt are mainly Pb‐Zn‐Sr‐Ag, while Pb‐Zn‐Ag‐Cu‐Co elements are dominant in the west ore belt. Comparative analysis of the C‐O‐Sr‐S‐Pb isotopic compositions suggest that both ore belts had a homogeneous carbon source, and the carbon in hydrothermal calcite is derived from the dissolution of carbonate rock strata; the ore‐forming fluids were originated from formation water and precipitate water, which belonged to basin brine fluid system; sulfur was from organic thermal chemical sulfate reduction and biological sulfate reduction; the metal mineralization material was from sedimentary strata and basement, but the difference of the material source of the basement and the strata and the superimposed mineralization of the west ore belt resulted in the difference of metallogenic elements between the eastern and western metallogenic belts. The Pb‐Zn mineralization age of both ore belts was contemporary and formed in the same metallogenetic event. Both thrust formed at the same time and occurred at the Early Oligocene, which is consistent with the age constrained by field geological relationship.