Characteristics of Kd （490） around Nansha Islands in the South China Sea

The diffusion attenuation coefficient for downwelling irradiance, Ka(490), is an important optical parameter of seawater. The optical property, Kd(490), around Nansha Islands in the South China Sea was analyzed based on optical data profiles measured with SPMR (SeaWiFS Profiling Multichannel Radiometer) and SMSR ( SeaWiFS Multichannel Surface Reference ) instrument in April and May, 1999. The results show that Kd(490) is closely correlated with chlorophyll-a concentration, Ccgka, and that the vertical distribution of Kd(490) shows the strong stratification of the water column in this area. Kd(490) has a similar vertical co-variation as KL(490), the diffusive attenuation coefficient for upwelling radiance.Both coefficients increase with depth in the upper layer, where KL(490) is greater than Kd(490); and after a depth, approximatively at the chlorophyll maximum, they decrease with depth, with the former being smaller than the latter.     

基于GOCI静止水色卫星数据的长江口及邻近海域Kd(490)遥感反演及其在机载激光测深预评估中的应用

长江口水下三角洲地形地貌对于长江口航道安全、生态环境、海岸带工程等均具有重要意义,本次研究拟采用世界上第一颗静止水色卫星GOCI(Geostationary Ocean Color Imager)开展长江口Kd(490)的季节和潮汐变化规律研究,以期为采用机载激光测深提供预评估信息。研究得到结论如下:长江口及邻近海域水体为典型的二类水体,悬浮泥沙含量最高可由杭州湾内几千mg/L迅速降低至10 mg/L以下,因此,分段式的漫衰减系数反演算法适用于研究区域;Kd(490)反演结果表明长江口及邻近海域的Kd(490)值的季节变化特征表现为冬高夏低,春秋居中,长江冲淡水流量和季风是影响其季节变化的主要因素,而在一个潮周期内,Kd(490)值总体表现为低潮期低于高潮期,悬浮泥沙浓度和潮水的潮位是长江口及邻近海域的Kd(490)值的重要影响因素;研究指出,长江口及杭州湾内激光可探测深度约在5~22 m范围内,夏季退潮低潮位最适合激光雷达观测。由此可见,GOCI 8景/d,1景/h的分辨率可以实现Kd(490)的动态变化监控,而且可以实现在相同潮位下更为合理地描述Kd(490)值的季节变化,为机载激光雷达探测的进一步开展提供了技术支持。     

渤海近岸水体漫衰减系数Kd(490)遥感反演模型

利用2005年渤海近岸水体生物光学数据集, 建立了基于水体遥感反射率光谱Rrs(λ)数据的490nm波段水体漫衰减系数Kd(490)经验反演模型, 经实测数据检验, 模型反演结果的平均相对误差为18.4%, 均方根误差(对数坐标下)为0.094m-1, 相关系数R2 (对数坐标下)为0.902。分析了模型的噪声敏感性, 在输入端引入±5%误差的情况下, 模型反演结果的平均相对误差波动在9%以内, 均方根误差的变化在0.035m-1以内, 模型是稳定可靠的。以ENVISAT MERIS数据为例, 进行了模型的示范应用, 给出了渤海Kd(490)的空间分布。     

成都平原农田区土壤重金属元素环境基准值初步研究

土壤重金属污染已成为制约人类社会发展及危害人类健康的重要因素,制定土壤重金属元素的环境基准值对控制土壤重金属污染及保护生态安全具有重要意义。以成都平原农田区为例,以保护地下水安全为目的,以室内模拟淋溶实验为手段,尝试性地计算了研究区不同类型土壤重金属元素的环境基准值。研究结果表明:(1)不同类型土壤各元素在土壤—水间的分配系数差异较大;(2)不同类型土壤Hg和Cd环境基准值差异不大,Hg环境基准值平均为0.3μg/g,Cd的变化范围为0.3～0.5μg/g;As和Pb环境基准值差异较大,As的变化范围为18～24μg/g;Pb的变化范围为24～41μg/g;(3)研究区土壤基本处于保护饮用水的安全范围之内,但黄壤中Pb、紫色土中Cd和Pb、棕壤中Hg和Pb具有潜在的影响地下水安全的生态风险。这对研究区进行风险评估具有重要的参考价值。     

Geology and age model of the Lower Pleistocene Nojima,Ofuna, and Koshiba Formations of the middle Kazusa Group,a forearc basin‐fill sequence on the Miura Peninsula,the Pacific side of central Japan

We present field and core observations, nannofossil biostratigraphy, and stable oxygen isotope fluctuations in foraminiferal tests to describe the geology and to construct an age model of the Lower Pleistocene Nojima, Ofuna, and Koshiba Formations (in ascending order) of the middle Kazusa Group, a forearc basin‐fill succession, exposed on the northern Miura Peninsula on the Pacific side of central Japan. In the study area, the Nojima Formation is composed of sandy mudstone and alternating sandy mudstone and mudstone, the Ofuna Formation of massive mudstone, and the Koshiba Formation of sandy mudstone, muddy sandstone, and sandstone. The Kazusa Group contains many tuff beds that are characteristic of forearc deposits. Thirty‐six of those tuff beds have characteristic lithologies and stratigraphic positions that allow them to be traced over considerable distances. Examination of calcareous nannofossils revealed three nannofossil datum planes in the sequences: datum 10 (first appearance of large Gephyrocapsa), datum 11 (first appearance of Gephyrocapsa oceanica), and datum 12 (first appearance of Gephyrocapsa caribbeanica). Stable oxygen isotope data from the tests of the planktonic foraminifer Globorotalia inflata extracted from cores were measured to identify the stratigraphic fluctuations of oxygen isotope ratios that are controlled by glacial–interglacial cycles. The observed fluctuations were assigned to marine isotope stages (MISs) 49–61 on the basis of correlations of the fluctuations with nannofossil datum planes. Using the age model obtained, we estimated the ages of 24 tuff beds. Among these, the SKT‐11 and SKT‐12 tuff beds have been correlated with the Kd25 and Kd24 tuff beds, respectively, of the Kiwada Formation on the Boso Peninsula. The Kd25 and Kd24 tuff beds are widely recognized in Pleistocene strata in Japan. We used our age model to date SKT‐11 at 1573 ka and SKT‐12 at 1543 ka.     

有机组分土-水分配系数的确定(英文)

有机组分的土水分配系数(Kd)是描述有机组分在地下系统中吸附特征的重要参数。同时,它也是物质运移模拟和环境评价中的主要参数之一。影响Kd的因素可概括为三个方面:土壤性质、有机组分本身特征及水相的物理化学性质。一般而言,对于非极性和弱极性有机组分,土壤中的有机质含量(foc )是影响Kd的最主要因素。但是,对于极性有机组分(POCs), 特别是在土壤有机质含量较低的情况下,土壤中矿物的种类和含量、水化学组分特征(pH、离子力等)经常在吸附过程中起重要作用。实验室内测定Kd的方法包括批实验和柱实验方法。批实验法适用于研究Kd较高情况下的吸附。在Kd较低的情况下,如低有机质土壤对极性有机污染物的吸附,土柱色谱法(SCC)是更适宜的选择。另外,可用土柱色谱法快速了解各种因素对吸附过程的影响,并获取详细的吸附和解吸信息。应用土柱色谱法时应当注意非平衡吸附和可能的柱堵塞问题。很多文献中提到结合柱实验和已有的吸附数据来预测土壤有机碳标准化的分配系数Koc(=Kd/foc)。但是,如果没有考虑吸附中特定的作用过程(如矿物吸附),对极性有机组分Koc的预测将会产生很大的误差。在环境评价中,将从一种土壤测定的Koc 应用到不同性质的土壤中,可能会导致错误的认识。在进行室内实验时,应把标准土(如Eurosoi     

基于浮标观测的东海赤潮高发区秋、冬季漫射衰减系数的反演

浮标测量的光学数据时间序列长、分辨率高, 能可靠地测量快速变化的漫射衰减系数(K_d)。东海赤潮高发区水体中的浮游植物生物量及悬浮泥沙含量存在较大的变化, 光学性质复杂。文章利用2013年9月至2014年1月的海洋光学浮标数据, 获得了该海域水体的表观光学特性, 基于K_d(490)与遥感反射比[R_rs(λ)]的相关关系建立了K_d(490)的经验算法, 并与已有7种反演算法进行了比较。结果表明, 该海域的K_d(λ)及R_rs(λ)具有显著的Ⅱ类水体光谱特征, 其中, K_d(490)的范围为0.01~4.31m^-1, 水体的浑浊程度变化大。K_d(490)与R_rs比值的相关性较好, 据此建立了以R_rs(650)/R_rs(510)、R_rs(555)/R_rs(510)作为自变量的K_d(490)双比值经验算法。将新建算法反演获得的K_d(490)与实测K_d(490)相比, 均方根误差、平均相对误差百分比和线性回归的决定系数分别为0.27m^-1、27.08%和0.77, 优于其他7种算法。算法精度的提高源于新建算法选择的R_rs能充分反映水体信息, 并适应水体组分的变化, 可为东海赤潮高发区K_d(490)的反演提供较好的选择, 并为海洋光学浮标在水体环境监测中的应用提供示例。     

Effects of calcium and magnesium on strontium distribution coefficients

 The effects of calcium and magnesium on the distribution of strontium between a surficial sediment and simulated wastewater solutions were measured as part of an investigation to determine strontium transport properties of surficial sediment at the Idaho National Engineering Laboratory (INEL), Idaho. The investigation was conducted by the U.S. Geological Survey and Idaho State University, in cooperation with the U.S. Department of Energy. Batch experimental techniques were used to determine strontium linear sorption isotherms and distribution coefficients (K _d's) using simulated wastewater solutions prepared at pH 8.0±0.1 with variable concentrations of calcium and magnesium. Strontium linear sorption isotherm K _d's ranged from 12±1 to 85±3 ml/g, increasing as the concentration of calcium and magnesium decreased. The concentration of sorbed strontium and the percentage of strontium retained by the sediment were correlated to aqueous concentrations of strontium, calcium, and magnesium. The effect of these cation concentrations on strontium sorption was quantified using multivariate least-squares regression techniques. Analysis of data from these experiments indicates that increased concentrations of calcium and magnesium in wastewater discharged to waste disposal ponds at the INEL increases the availability of strontium for transport beneath the ponds by decreasing strontium sorption to the surficial sediment. Received: 8 November 1996 · Accepted: 6 January 1997     

Solid-solution partitioning of arsenic （As） in the paddy soil profiles in Chengdu Plain, Southwest China

To predict the long-term behavior of arsenic(As) in soil profiles,the solid-solution partitioning of As was studied in four paddy soil profiles obtained from agricultural areas in Chengdu Plain,Southwest China.Paddy soil profile samples were collected and soil solution samples were extracted.Total As contents in soil solution and soil solid were analyzed,along with the soil solid phase properties.The As in soil solution was significantly higher in the upper layer(0—20 cm) and had a definite tendency to decrease towards 40 cm regardless of the sampling locations.When the concentration of arsenic in soil solution decreased,its content in solid phase increased.Field-based partition coefficient(K_d) for As was determined by calculating the ratio of the amount of As in the soil solid phase to the As concentration in the soil solution.K_d values varied widely in vertical samples and correlated well with soil pH,total organic carbon(TOC) and total As. The results of this study would be useful for evaluating the accumulation trends of arsenic in soil profiles and in improving the management of the agricultural soils.