Trace‐element signatures of apatites in granitoids from the Mt Isa Inlier,northwestern Queensland

The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser‐ablation inductively coupled plasma‐mass spectrometry (ICP‐MS) microprobe. The results indicate that the distribution of trace elements (especially rare‐earth elements (REE), Sr, Y, Mn and Th) in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace‐element concentrations of apatite are correlated with parameters such as the SiO₂ content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn²⁺substitutes directly for Ca²⁺. The La/Ce ratio of apatite is well‐correlated with the whole‐rock K²O and Na²O contents, as well as with the oxidation state and ASI. Because apatite trace‐element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.     

Constraining sequence stratigraphy in north Australian basins: SHRIMP U–Pb zircon geochronology between Mt Isa and McArthur River

Fifty‐five new SHRIMP U–Pb zircon ages from samples of northern Australian ‘basement’ and its overlying Proterozoic successions are used to refine and, in places, significantly change previous lithostratigraphic correlations. In conjunction with sequence‐stratigraphic studies, the 1800–1580 Ma rock record between Mt Isa and the Roper River is now classified into three superbasin phases—the Leichhardt, Calvert and Isa. These three major depositional episodes are separated by ～20 million years gaps. The Isa Superbasin can be further subdivided into seven supersequences each 10–15 million years in duration. Gaps in the geological record between these supersequences are variable; they approach several million years in basin‐margin positions, but are much smaller in the depocentres. Arguments based on field setting, petrography, zircon morphology, and U–Pb systematics are used to interpret these U–Pb zircon ages and in most cases to demonstrate that the ages obtained are depositional. In some instances, zircon crystals are reworked and give maximum depositional ages. These give useful provenance information as they fingerprint the source(s) of basin fill. Six new ‘Barramundi’ basement ages (around 1850 Ma) were obtained from crystalline units in the Murphy Inlier (Nicholson Granite and Cliffdale Volcanics), the Urapunga Tectonic Ridge (‘Mt Reid Volcanics’ and ‘Urapunga Granite’), and the central McArthur Basin (Scrutton Volcanics). New ages were also obtained from units assigned to the Calvert Superbasin (ca 1740–1690 Ma). SHRIMP results show that the Wollogorang Formation is not one continuous unit, but two different sequences, one deposited around 1730 Ma and a younger unit deposited around 1722 Ma. Further documentation is given of a regional 1725 Ma felsic event adjacent to the Murphy Inlier (Peters Creek Volcanics and Packsaddle Microgranite) and in the Carrara Range. A younger ca 1710 Ma felsic event is indicated in the southwestern McArthur Basin (Tanumbirini Rhyolite and overlying Nyanantu Formation). Four of the seven supersequences in the Isa Superbasin (ca 1670–1580 Ma) are reasonably well‐constrained by the new SHRIMP results: the Gun Supersequence (ca 1670–1655 Ma) by Paradise Creek Formation, Moondarra Siltstone, Breakaway Shale and Urquhart Shale ages grouped between 1668 and 1652 Ma; the Loretta Supersequence (ca 1655–1645 Ma) by results from the Lady Loretta Formation, Walford Dolomite, the upper part of the Mallapunyah Formation and the Tatoola Sandstone between ca 1653 and 1647 Ma; the River Supersequence (ca 1645–1630 Ma) by ages from the Teena Dolomite, Mt Les and Riversleigh Siltstones, and Barney Creek, Lynott, St Vidgeon and Nagi Formations clustering around 1640 Ma; and the Term Supersequence (ca 1630–1615 Ma) by ages from the Stretton Sandstone, lower Doomadgee Formation and lower part of the Lawn Hill Formation, mostly around 1630–1620 Ma. The next two younger supersequences are less well‐constrained geochronologically, but comprise the Lawn Supersequence (ca 1615–1600 Ma) with ages from the lower Balbirini Dolomite, and lower Doomadgee, Amos and middle Lawn Hill Formations, clustered around 1615–1610 Ma; and the Wide Supersequence (ca 1600–1585 Ma) with only two ages around 1590 Ma, one from the upper Balbirini Dolomite and the other from the upper Lawn Hill Formation. The Doom Supersequence (<1585 Ma) at the top of the Isa Superbasin is essentially unconstrained. The integration of high‐precision SHRIMP dating from continuously analysed stratigraphic sections, within a sequence stratigraphic context, provides an enhanced chronostratigraphic framework leading to more reliable interpretations of basin architecture and evolution.     

Palaeoproterozoic mid‐basin inversion in the northern Mt Isa terrane,Queensland

The Mellish Park Syncline is located in the northern part of the Mt Isa terrane. It has an axial trace that transects the remnants of the unconformity‐bounded Palaeoproterozoic Leichhardt and Isa Superbasins. The syncline is separated into a lower and upper component based upon variation in fold geometry across the basin‐bounding unconformity. The lower syncline, in the Leichhardt Superbasin, is tight and has an inclined west‐dipping axial plane. The upper syncline, in the Isa Superbasin, is open and upright. The geometry of the lower syncline is a consequence of a period of shortening and basin inversion which post‐dated the Leichhardt Rift Event (ca 1780–1740 Ma) and pre‐dated the Mt Isa Rift Event (ca 1710–1655 Ma), forming an open and upright north‐oriented syncline. Subsequent southeast tilting and half‐graben development during the Mt Isa Rift Event resulted in the lower syncline being tilted into its inclined geometry. Sequences of the Isa Superbasin were then deposited onto the eroded syncline. The geometry of the upper syncline reflects regional east‐west shortening during the Isan Orogeny (ca 1590–1500 Ma). The position of the upper syncline was largely controlled by the pre‐existing lower syncline. At this time the lower syncline was reactivated and tightened by flexural slip folding.     

Comparison of the ‘strike‐slip’ versus the ‘episodic rift‐sag’ models for the origin of the Isa Superbasin

In this paper we assess two competing tectonic models for the development of the Isa Superbasin (ca 1725–1590 Ma) in the Western Fold Belt of the Mt Isa terrane. In the ‘episodic rift‐sag’ tectonic model the basin architecture is envisaged as similar to that of a Basin and Range province characterised by widespread half‐graben development. According to this model, the Isa Superbasin evolved during three stages of the Mt Isa Rift Event. Stage I involved intracontinental extension, half‐graben development, the emergence of fault scarps and tilt‐blocks, and bimodal volcanism. Stage II involved episodic rifting and sag during intervening periods of tectonic quiescence. Stage III was dominated by thermal relaxation of the lithosphere with transient episodes of extension. Sedimentation was controlled by the development of arrays of half‐grabens bounded by intrabasinal transverse or transfer faults. The competing ‘strike‐slip’ model was developed for the Gun Supersequence stratigraphic interval of the Isa Superbasin (during stage II and the beginning of stage III). According to this model, sinistral movements along north‐northeast‐orientated strike‐slip faults took place, with oblique movements along northwest‐orientated faults. This resulted in the deposition of southeast‐thickening ramp sequences with local sub‐basin depocentres forming to the west and north of north‐northeast‐ and northwest‐trending faults, respectively. It is proposed that dilation zones focused magmatism (e.g. Sybella Granite) and transfer of strike‐slip movement resulted in transient uplift along the western margin of the Mt Gordon Arch. Our analysis supports the ‘episodic rift‐sag’ model. We find that the inferred architecture for the strike‐slip model correlates poorly with the observed structural elements. Interpretation is made difficult because there has been significant modification and reorientation of fault geometry during the Isan Orogeny and these effects need to be removed before any assertion as to the basin structure is made. Strike‐slip faulting does not explain the regional‐scale pattern of basin subsidence. The ‘episodic rift‐sag’ model explains the macroscopic geometry of the Isa Superbasin and is consistent with the detailed sedimentological analysis of basin facies architecture, and the structural history and geometry.     

Tectonic control on third‐order sequences in a siliciclastic ramp‐style basin: An example from the Roper Superbasin (Mesoproterozoic), northern Australia

TThe Roper Group is a cyclic, predominantly marine, siliciclastic succession of Calymmian (Early Mesoproterozoic) age. It has a distribution of at least 145 000 km² and a maximum known thickness of ～5000 m. In the Roper River district the middle part of the Roper Group (～1300 m thick) is characterised by the cyclical alternation of mudstone and sandstone units, and can be divided into six third‐order depositional sequences. A typical sequence is broadly progradational in aspect, and comprises a lower, mudstone‐rich, storm‐dominated shelf succession (up to 330 m thick), and a sequence‐capping unit dominated by tidal‐platform cross‐bedded sandstone (up to 80 m thick); both are interpreted as highstand systems tracts. Transgressive strata are poorly represented but where present are characterised by paralic to fluvial redbed assemblages that include ooidal ironstone. Roper Group sequences lack a distinct condensed section and sequence boundaries are mostly conformable. Erosional contacts separate mud‐rich shelf facies from sequence‐capping sandstones. We infer that these erosion surfaces were generated by episodic flexural tectonism, which also generated the accommodation and sediment supply for Roper sequences.     

Neoproterozoic (Cryogenian) stromatolites from the Wolfe Basin,east Kimberley,Western Australia: Correlation with the Centralian Superbasin

Linella avis, an early to middle Neoproterozoic (Tonian to Cryogenian) stromatolite, occurs in the Eliot Range Dolomite, part of the Ruby Plains Group in the Wolfe Basin, east Kimberley. Previously, this dolomite was assigned to the Mesoproterozoic Bungle Bungle Dolomite in the Osmond Basin, which contains a different suite of stromatolites. Linella avis, which also occurs in the Neoproterozoic Bitter Springs Formation of the Amadeus Basin, central Australia, appears to be restricted to rocks aged around 850 to 800 Ma. The presence of L. avis indicates that the Ruby Plains Group is a probable correlative of the Heavitree Quartzite and Bitter Springs Formation, and is probably much younger than the Bungle Bungle Dolomite. If the correlation suggested here is correct, the Wolfe Basin, together with the Amadeus and Ngalia Basins, formed part of the Centralian Superbasin.     

The Proterozoic,albitite-hosted,Valhalla uranium deposit,Queensland, Australia: a description of the alteration assemblage associated with uranium mineralisation in diamond drill hole V39

The Valhalla uranium deposit, located 40 km north of Mount Isa, Queensland, Australia, is an albitite-hosted, Mesoproterozoic U deposit similar to albitite-hosted uranium deposits in the Ukraine, Sweden, Brazil and Guyana. Uranium mineralisation is hosted by a thick package of interbedded fine-grained sandstones, arkoses and gritty siltstones that are bound by metabasalts belonging to the ca. 1,780 Ma Eastern Creek Volcanics in the Western Succession of the Mount Isa basin. Alteration associated with U mineralisation can be divided into an early, main and late stage. The early stage is dominated by laminated and intensely altered rock comprising albite, reibeckite, calcite, (titano)magnetite ± brannerite. The main stage of mineralisation is dominated by brecciated and intensely altered rocks that comprise laminated and intensely altered rock cemented by brannerite, apatite, (uranoan)-zircon, uraninite, anatase, albite, reibeckite, calcite and hematite. The late stage of mineralisation comprises uraninite, red hematite, dolomite, calcite, chlorite, quartz and Pb-, Fe-, Cu-sulfides. Brannerite has U–Pb and Pb–Pb ages that indicate formation between 1,555 and 1,510 Ma, with significant Pb loss evident at ca. 1,200 Ma, coincident with the assemblage of Rodinia. The oldest ages of the brannerite overlap with ⁴⁰Ar/³⁹Ar ages of 1,533 ± 9 Ma and 1,551 ± 7 Ma from early and main-stage reibeckite and are interpreted to represent the timing of formation of the deposit. These ages coincide with the timing of peak metamorphism in the Mount Isa area during the Isan Orogeny. Lithogeochemical assessment of whole rock data that includes mineralised and unmineralised samples from the greater Mount Isa district reveals that mineralisation involved the removal of K, Ba and Si and the addition of Na, Ca, U, V, Zr, P, Sr, F and Y. U/Th ratios indicate that the ore-forming fluid was oxidised, whereas the crystal chemistry of apatite and reibeckite within the ore zone suggests that F⁻ and were important ore-transporting complexes. δ¹⁸O values of co-existing calcite and reibeckite indicate that mineralisation occurred between 340 and 380°C and involved a fluid having δ¹⁸O_fluid values between 6.5 and 8.6‰. Reibeckite δD values reveal that the ore fluid had a δD_fluid value between −98 and −54‰. The mineral assemblages associated with early and main stages of alteration, plus δ¹⁸O_fluid and δD_fluid values, and timing of the U mineralisation are all very similar to those associated with Na–Ca alteration in the Eastern Succession of the Mount Isa basin, where a magmatic fluid is favoured for this style of alteration. However, isotopic data from Valhalla is also consistent with that from the nearby Mount Isa Cu deposit where a basinal brine is proposed for the transport of metals to the deposit. Based on the evidence to hand, the source fluids could have been derived from either or both the metasediments that underlie the Eastern Creek Volcanics or magmatism that is manifest in the Mount Isa area as small pegmatite dykes that intruded during the Isan Orogeny.     

Deformation history of the Naraku Batholith,Mt Isa Inlier,Australia: Implications for pluton ages and geometries from structural study of the Dipvale Granodiorite and Levian Granite

Plutons of the Naraku Batholith were emplaced into Proterozoic metasediments of the northern portion of the Eastern Fold Belt of the Mt Isa Inlier during two intrusive episodes approximately 200 million years apart. Structural relationships and geochronological data suggest that the older plutons (ca 1750 Ma) are contemporaneous with granites of the Wonga Batholith to the west. The Dipvale Granodiorite and the Levian Granite represent these older intrusive phases of the Naraku Batholith, and both contain an intense tectonic foliation, S₁, which is interpreted to have formed during the north‐south shortening associated with D₁ of the Isan Orogeny. The geometry of S₁ form surfaces at the southern end of the Dipvale Granodiorite, and of the previously unrecognised sheeted contact, defines a macroscopic, steeply south‐southwest‐plunging antiform, which was produced by the regional D₂ of the Isan Orogeny. S₁ form surfaces in the Levian Granite define open F₂ folds with wavelengths of several hundred metres. The structural age of emplacement of the Dipvale Granodiorite and the Levian Granite is interpreted to be pre‐ or syn‐ the regional D₁. An intense foliation present in some of the younger (ca 1505 Ma) granites that comprise the bulk of the Naraku Batholith is interpreted to represent S₃ of the Isan Orogeny. Foliations commonly have similar styles and orientations in both the pre‐D₁ and younger plutons. This emphasises the simplicity with which regional fabrics can be, and probably have been, miscorrelated in the Eastern Fold Belt, and that the classification of granites in general on the basis of structural and geometric criteria alone is fraught with danger.     

Coupled Process Models of Fluid Flow and Heat Transfer in Hydrothermal Systems in Three Dimensions

Geothermal fields and hydrothermal mineral deposits are manifestations of the interaction between heat transfer and fluid flow in the Earth’s crust. Understanding the factors that drive fluid flow is essential for managing geothermal energy production and for understanding the genesis of hydrothermal mineral systems. We provide an overview of fluid flow drivers with a focus on flow driven by heat and hydraulic head. We show how numerical simulations can be used to compare the effect of different flow drivers on hydrothermal mineralisation. We explore the concepts of laminar flow in porous media (Darcy’s law) and the non-dimensional Rayleigh number (Ra) for free thermal convection in the context of fluid flow in hydrothermal systems in three dimensions. We compare models of free thermal convection to hydraulic head driven flow in relation to hydrothermal copper mineralisation at Mount Isa, Australia. Free thermal convection occurs if the permeability of the fault system results in Ra above the critical threshold, whereas a vertical head gradient results in an upward flow field.     

On the role of buoyancy force in the ore genesis of SEDEX deposits: Example from Northern Australia

Finite element modeling on a highly conceptualized 2-D model of fluid flow and heat transport is un-dertaken to simulate the paleo-hydrological system as if the Mount Isa deposits were being formed in the Mount Isa basin, Northern Australia, and to evaluate the potential of buoyancy force in driving ba-sin-scale fluid flow for the formation of sedimentary-exhalative (SEDEX) deposits. Our numerical case studies indicate that buoyancy-driven fluid flow is controlled mainly by the fault penetration depth and i...