我国高碘卤水分布规律及其形成

根据国内外大量实际资料,从碘的分布情况及其所处的地质条件,结合石油和天然气形成过程、油气藏类型及其分布特点,探讨高碘卤水分布的规律及其形成条件,在此基础上指出了我国的找碘方向。     

新疆对中亚五国的外贸结构,问题及对策

本文在分析新疆对中亚五国的外贸结构基础上，阐述了目前在与中亚五国的贸易中存在的一些问题，提出相应的对策建议，以推动新疆与中亚五国外贸发展的良性循环。     

生态足迹模型在山区生态可持续评价中的初步应用--以1999年北京西部山区为例

在剖析生态足迹分析法的理论基础上，进一步考虑不同消费水平对生态足迹时空变异的影响，划分农村居民和城镇居民两类不同的消费群体，分别计算各自的生态足迹，其次进一步细化模型中人均水资源足迹，从而构建生态足迹与生态容量平衡模型。根据平衡模型计算出生态盈亏，得出区域生态持续性评价结果。并以1999年北京西部山区门头沟区为例，进行模型计算和生态可持续评价，结果表明1999年门头沟区处于生态赤字状态，说明该区生态系统处于不可持续状态。在对门头沟区的初步研究基础上，指出生态足迹作为山区生态可持续评价指标的优点及当前存在的缺点。     

Iodine budget in surface waters from Atacama: Natural and anthropogenic iodine sources revealed by halogen geochemistry and iodine-129 isotopes

Iodine enrichment in the Atacama Desert of northern Chile is widespread and varies significantly between reservoirs, including nitrate-rich “caliche” soils, supergene Cu deposits and marine sedimentary rocks. Recent studies have suggested that groundwater has played a key role in the remobilization, transport and deposition of iodine in Atacama over scales of millions-of-years. However, and considering that natural waters are also anomalously enriched in iodine in the region, the relative source contributions of iodine in the waters and its extent of mixing remain unconstrained. In this study we provide new halogen data and isotopic ratios of iodine (¹²⁹I/I) in shallow seawater, rivers, salt lakes, cold and thermal spring water, rainwater and groundwater that help to constrain the relative influence of meteoric, marine and crustal sources in the Atacama waters. Iodine concentrations in surface and ground waters range between 0.35 μM and 26 μM in the Tarapacá region and between 0.25 μM and 48 μM in the Antofagasta region, and show strong enrichment when compared with seawater concentrations (I = ∼0.4 μM). In contrast, no bromine enrichment is detected (1.3–45.7 μM for Tarapacá and 1.7–87.4 μM for Antofagasta) relative to seawater (Br = ∼600 μM). These data, coupled to the high I/Cl and low Br/Cl ratios are indicative of an organic-rich sedimentary source (related with an “initial” fluid) that interacted with meteoric water to produce a mixed fluid, and preclude an exclusively seawater origin for iodine in Atacama natural waters. Iodine isotopic ratios (¹²⁹I/I) are consistent with halogen chemistry and confirm that most of the iodine present in natural waters derives from a deep initial fluid source (i.e., groundwater which has interacted with Jurassic marine basement), with variable influence of at least one atmospheric or meteoric source. Samples with the lowest isotopic ratios (¹²⁹I/I from ∼215 to ∼1000 × 10⁻¹⁵) strongly suggest mixing between the groundwater and iodine storage in organic-rich rocks (with variable influence of volcanic fluids) and pre-anthropogenic meteoric water, while samples with higher values (∼2000–93,700 × 10⁻¹⁵) indicate the input of anthropogenic meteoric fluid. Taking into account the geological, hydrologic and climatic features of the Atacama region, we propose that the mean contribution of anthropogenic ¹²⁹I is associated with ¹²⁹I releases during nuclear weapon tests carried out in the central Pacific Ocean until the mid 1990's (¹²⁹I/I = ∼12,000 × 10⁻¹⁵). This source reflects rapid redistribution of this radioisotope on a global scale. Our results support the notion of a long-lived continental iodine cycle in the hyperarid margin of western South America, which is driven by local hydrological and climate conditions, and confirm that groundwater was a key agent for iodine remobilization and formation of the extensive iodine-rich soils of Atacama.     

微波消解―ICP―MS法测土壤和水系沉积物样品中的碘

介绍了用微波消解处理土壤和水系沉积物样品,用电感耦合等离子质谱仪(ICP-MS)快速高效测试碘的方法。方法的检出限为0. 012μg/g。所选的12个土壤和水系沉积物国家一级标准物质12次测定,除GBW07307a的RSD小于10%外,其余RSD值均小于5%,12次测试的平均值和标准值对数差绝对值均小于0. 05。方法加标回收率在98. 6%104. 6%之间。     

近50多年来淮河流域气候水分盈亏时空变化

水分盈亏是区域干湿气候划分的重要依据。基于淮河流域63个气象台站1957—2014年逐日观测数据,运用累积距平、Mann-Kendall突变分析、Morlet小波分析及ArcGIS反权重空间插值法,结合Penman-Monteith蒸散计算模型获得淮河流域水分盈亏量的周期特征、突变特征及其时空分布特征,并分析其主要影响因子。结果表明:(1)水分盈亏月变化基本符合5月最低,7月最高。(2)从季节分布来看,水分亏缺面积秋季春季冬季夏季,亏缺程度春季最强。从平均年水分盈亏量分布来看,水分盈亏量由南向北递减。且不论季节还是年状况,山地及河流对区域水分盈亏量的南北递减存在滞后作用。(3)从各因子气候倾向率的时空分布来看,江苏东南部、山东西部、河南大部、湖北中部水分盈亏量变化的主导因子为潜在蒸散量,其他区域的主导因子为降雨量。(4)淮河流域水分盈亏量存在周期特征,第一主周期为10 a。     

MODIS数据的水浇地提取

水浇地是土地覆盖分类系统中的一个重要类型, 依据水分亏缺指数(WDI)与土壤水分的相关性, 计算了监测时间内WDI的变化情况, 用降雨资料去除了由于降雨引起的WDI的变化, 进而提取了研究区的水浇地分布。结果表明：(1)提取出的水浇地在数量上与统计资料相比, 除山西省偏差相对较大外, 其余各省偏差均小于7%, 提取出的结果与统计资料具有可比性。(2)提取出的水浇地在空间上多成片出现在河流、湖泊、水库附近、灌区和绿洲上, 与已知的水浇地集中区一致。(3)利用TM影像对提取结果进行了初步判断, 其中山西省的正确率较低, 只有64%, 其余各省正确率均在70%以上, 新疆的正确率最高为92%。     

长江流域蒸发皿蒸发量的区域变化特征及影响因素

基于长江流域148个气象站1980—2017年的蒸发皿观测数据,将旋转经验正交函数（REOF）和模糊C均值聚类（FCM）相结合,对流域蒸发皿蒸发量（PE）进行分区,然后运用Modified Mann-Kendall检验和多元逐步回归等方法,分析各子区域PE的变化特征并识别其主要影响因子。结果表明：1) REOF的前4个空间模态显示流域PE存在5个主要的异常敏感区,基于这4个空间模态,流域PE在空间上可划分为9个子区域。2）在年尺度上,各区PE呈不同程度的增加趋势,其中中部盆地区上升速率最大（111.28 mm/10 a）,西部高原区上升速率最小（12.5 mm/10 a）;而在季节尺度上,秋、冬季流域PE呈显著上升趋势,春、夏季PE的变化具有明显的区域差异性,部分地区PE为下降趋势。3）影响PE变化的主要因子因地而异,但大多子区域的PE变化与平均气温和饱和水汽压差的变化显著相关。     

Further Studies Of Atmospheric Turbulence In Layers Near The Surface: Scaling The Tke Budget Above The Roughness Sublayer

The second of two experimental studies of the TKE budget conducted on sites of different roughness is described, and results are compared. The first took place within a shallow layer above a small field of mostly bare, cultivated soil; the second was carried out above a roughness sublayer of significant depth on an extensive plain of tall dry grass. Budget terms observed in the second study were scaled with a modified u which compensated for effects of an unusually large stress gradient and ensured that the _m functions would be collinear. By showing that the modification becomes negligible in smaller gradients, it is demonstrated that in normal conditions, budgets observed above significant roughness sublayers should be normalized by scaling in terms of the unreduced Reynolds stress at the sublayer's upper surface. This procedure is shown to be consistent with the expectation that TKE budgets in layers near the surface all scale in fundamentally the same way.Other findings include: (1) the fact that most _m functions previously reported are not quite collinear is attributed to a type of overspeeding known to affect three-cup anemometers; (2) revised _m functions, collinear and largely free of the effects of overspeeding, are determined from a well-established characteristic of the linear _m relation for the stable case; (3) data that define collinear _m functions can also be represented with single hyperbolic curves; (4) dissipation is found to be 10 to 15% too small to balance total TKE production in unstable and neutral conditions and to decrease with increasing z/L in thestable regime; and (5) new relations for based on the observed behaviour of the dissipation deficit provide an improved closure for the set of equations that express the budget terms as functions of _m and z/L.     

Iodine concentrations of soils near Trabzon, Turkey: a region of endemic goiter

Iodine contents of soils developed over the major rock formations of the northern zone of the Eastern Pontide Tectonic Belt (Northeastern Turkey) have been investigated with respect to soil-parent rock relationship, effect of topography, elevation, and climate to construe its effect on the health of the local population. Samples were collected from the A and B horizons of the soils developed over the major stratigraphic units constituting the eastern Pontides, including the Lower Basic Complex of Jurassic-Lower Cretaceous age, the Berdiga limestone (Jurassic-lower Cretaceous), the Dagbasi granitoid (Upper Cretaceous), volcano-sedimentary sequence of Upper Cretaceous age, ore-bearing and barren dacites of Upper Cretaceous age, and Neogene alkaline basalts. Chemical analyses of soil samples indicate significantly lower iodine abundances for all the soils studied (5–28 ppm) in comparison to the average abundance of iodine in analogous soils of other parts of the world (22–93 ppm). The concentration of iodine in soils developed over the same geologic formation decrease with increasing elevation. In certain cases, this decrease may reach up to 70%. Goiter is highly common throughout this region in Turkey. The results of this study suggest that the iodine deficiency of region’s soils may be a principal underlying cause for this area of Turkey being an endemic goiter region.