Water and power networks and urban fragmentation in Los Angeles: Rethinking assumed mechanisms

Los Angeles is often described as the epitome of urban fragmentation, a notion which in this context is frequently connected to, or even conflated with urban sprawl. At the same time, the city features integrated water and power networks which have been under public ownership for over 70 years. We thus have an apparent paradox in the context of the debate on ‘splintering urbanism’, between socio-spatial fragmentation and the integration of networks. In discussing the idea that deregulation of infrastructural networks exacerbates urban fragmentation, the authors use the case of Los Angeles in order to highlight the central role of private interests in management decisions concerning infrastructure networks. The authors carry out their analysis in an historical perspective, revealing that network integration and universal access can often serve private interests more than the public good. Urban fragmentation in Los Angeles, they conclude, is the result of a complex process of instrumentalisation of network development and management.     

我国海洋测井技术回顾与展望

地球物理测井是利用各种现代物理学的方法（包括电学、声学、核物理、热学、光学、磁学、力学等）对储层空间的油气水特性、沉积环境、地层层序、构造地质等现象进行定量研究，逐步形成的一门理论性、实用性很强的边缘学科．海洋测井作业环境更为特殊而复杂，不但投资大、作业风险大，而且具有技术高度密集、技术难度大的特点．发展海洋石油勘探事业，必须加强对海洋测井技术的研究，利用现代高新科学技术，开拓海洋测井新领域，为海洋石油勘探提供更丰富、更准确的地质信息．     

Effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite

In situ X-ray diffraction measurements of Fe- and Al-bearing MgSiO₃-rich perovskite (FeAl-Pv), which was synthesized from a natural orthopyroxene, were performed at pressures of 19–32 GPa and temperatures of 300–1,500 K using a combination of a Kawai-type apparatus with eight sintered-diamond anvils and synchrotron radiation. Two runs were performed using a high-pressure cell with two sample chambers, and both MgSiO₃ perovskite (Mg-Pv) and FeAl-Pv were synthesized simultaneously in the same cell. Thus we were able to measure specific volumes (V/V ₀) of Mg-Pv and FeAl-Pv at the same P−T conditions. At all the measurement conditions, values of the specific volume of FeAl-Pv are consistent with those of Mg-Pv within 2 Standard Deviation, strongly suggesting that effect of incorporation of iron and aluminum on the thermoelastic properties of magnesium silicate perovskite is undetectable in this composition, pressure, and temperature range. Two additional runs were performed using a high-pressure cell that has one sample chamber and unit-cell volumes of FeAl-Pv were measured at pressures and temperatures up to 32 GPa and 1,500 K, respectively. All the unit-cell volume data of FeAl-Pv perovskite were fitted to the high temperature Birch–Murnaghan equation of state and a complete set of thermoelastic parameters of this perovskite was determined with an assumption of K′ _300,0 = 4. The determined parameters are K _300,0 = 243(3) GPa, (∂K _T,0/∂T) _P = −0.030(8) GPa/K, a ₀ = 2.78(18) × 10⁻⁵ K⁻¹, and b ₀ = 0.88(28) × 10⁻⁸ K⁻², where a ₀ and b ₀ are the coefficients of the following expression describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. The equation-of-state parameters of FeAl-Pv are in good agreement with those of MgSiO₃ perovskite at the conditions corresponding to the uppermost part of the lower mantle.     

我国的地球系统科学研究向何处去

近15年来,全球变化与地球系统科学研究在中国广泛开展,我国科学家越来越积极地参加各项国际计划。当前,一些重大的国际计划正在进入其新阶段（如IGBP-II,IODP）,恰好我国也正在制定科技发展中长期规划,迫切需要回顾我国地球系统科学的现状并探讨其今后方向。尽管中国作者的国际论文数量在增长,我国地球系统科学落后于国际的差距仍有拉大的趋势：国际前沿的许多热点问题,在中国尚未提上日程;中国学者在国际计划中早期多有贡献,但在项目总结中却很少有份。为此,提出 3点建议：（1）中国地球科学家应当扩大视野、立足本国、面向全球;（2）应当注意国际前沿动向,促进地学与生命科学在分子水平上的结合;（3）中国的地球科学,应当从以描述为主向探索理的方向发展。我们不应当满足于向国际学术界输出"原料",而要积极参加地球系统科学中关键问题的理论探讨。     

Behaviour of Fe-oxides relevant to contaminant uptake in the environment

The behaviour of Fe-oxides was investigated during precipitation and co-precipitation, phase transformation and dissolution, while their ability to adsorb and incorporate trace components was examined. Some samples were synthesised and studied under controlled laboratory conditions and other samples were taken from experiments designed to test the effectiveness of waste treatment strategies using iron. Surface-sensitive and high-resolution techniques were used to complement information gathered from classical, macroscopic methods.

Adsorption isotherms for Ni²⁺ uptake on synthetic ferrihydrite (Fe₅HO₈·4H₂O, often written simply Fe(OH)₃), goethite (-FeOOH), hematite (-Fe₂O₃) and magnetite (Fe₃O₄) were all similar, increasing as expected at higher pH. Desorption behaviour was also similar, but one third or more of the Ni²⁺ failed to return to solution. In the past, “irreversible sorption” has been blamed on uptake into micro-fractures or pores, but during examination (using Atomic force microscopy, AFM) of hundreds of Fe-oxide particles, no evidence for such features could be found, leading to the conclusion that Ni²⁺ must become incorporated onto or into the solids. When solutions of Fe(II) are oxidised in controlled laboratory conditions or during treatment of ash from municipal waste incinerators, two-line ferrihydrite forms rapidly and on never-dried samples, AFM shows abundant individual particles with diameter ranging from 0.5 to several tens of nanometers. Aging in solution at 70°C promotes growth of the particles into hematite and goethite and their identification (by X-ray powder diffraction, XRPD, with Rietveld refinement) becomes possible at the same aging stage as mineral morphology becomes recognisable by AFM. In other experiments that were designed to mimic natural attack by organic acids, colloidal lepidocrocite (γ-FeOOH) was observed in situ by AFM, while reductive dissolution removed material on specific crystal faces. Lath ends are eroded fastest while basal planes are more stable.

In order to help elucidate mechanisms of contaminant immobilisation by Fe-oxides, we examined samples from a reactive barrier made with 90% quartz sand, 5% bentonite and 5% zero-valent iron filings that had reacted with a solution typical of leachate from coal-burning fly ash using time-of-flight secondary ion mass spectroscopy (TOF-SIMS). Fe(0) oxidised to Fe(III), while soluble and toxic Cr(VI) was reduced to insoluble Cr(III). Chemical maps show Fe-oxide coatings on bentonite; Cr is associated with Fe-oxides to some extent but its association with Ca in a previously undescribed phase is much stronger. Other samples taken from municipal waste incinerator ash that had been treated by aeration in Fe(II) solutions were examined with transmission electron microscopy (TEM), selected area electron diffraction (SAED) and energy dispersive X-ray spectroscopy (EDS). Pb and some Zn are seen to be dispersed throughout two-line ferrihydrite aggregates, whereas Sn and some Zn are incorporated simply as a result of entrainment of individual ZnSn-oxide crystallites.

Geochemical speciation models that fail to account for contaminant uptake in solid solutions within major phases or as thin coatings or entrained crystals of uncommon phases such as those described here risk to underestimate contaminant retardation or immobilisation.     

我国海洋测井技术回顾与展望

地球物理测井是利用各种现代物理学的方法（包括电学、声学、核物理、热学、光学、磁学、力学等）对储层空间的油气水特性、沉积环境、地层层序、构造地质等现象进行定量研究,逐步形成的一门理论性、实用性很强的边缘学科．海洋测井作业环境更为特殊而复杂,不但投资大、作业风险大,而且具有技术高度密集、技术难度大的特点．发展海洋石油勘探事业,必须加强对海洋测井技术的研究,利用现代高新科学技术,开拓海洋测井新领域,为海洋石油勘探提供更丰富、更准确的地质信息．