Recommended Values of 239Pu, 240Pu and 239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.     

Instrumental Neutron Activation Analysis of Estuarine Sediment as a Proposed Reference Material for Environmental Studies

The International Atomic Energy Agency (IAEA) Marine Environmental Studies Laboratory (MEL) organised an intercomparison exercise, through its Analytical Quality Control Services (AQCS), for the determination of trace elements in estuarine sediment IAEA-405, well suited for the characterisation of sediments. The instrumental neutron activation analysis technique (INAA) was developed using a 27 kW low power research reactor. Forty elements in the sediment were determined with a measurement precision varying from 1.8% to 12.3%. IAEA reference materials SL-1 and SD-M-2/TM were analysed throughout this work as quality assurance samples.     

Molecular hydrogen emission in Cygnus A

We present J , H and K -band spectroscopy of Cygnus A, spanning 1.0–2.4 μm in the rest-frame and hence several rovibrational H₂, H recombination and [Fe  ii ] emission lines. The lines are spatially extended by up to 6 kpc from the nucleus, but their distinct kinematics indicate that the three groups (H, H₂ and [Fe  ii ]) are not wholly produced in the same gas. The broadest line, [Fe  ii ] λ 1.644, exhibits a non-Gaussian profile with a broad base (FWHM≃1040 km s⁻¹), perhaps because of the interaction with the radio source. Extinctions to the line-emitting regions substantially exceed earlier measurements based on optical H recombination lines.
Hard X-rays from the quasar nucleus are likely to dominate the excitation of the H₂ emission. The results of Maloney, Hollenbach & Tielens are thus used to infer the total mass of gas in H₂ v=1–0 S(1)-emitting clouds as a function of radius, for gas densities of 10³ and 10⁵ cm⁻³, and stopping column densities N _H=10²²–10²⁴ cm⁻². Assuming azimuthal symmetry, at least 2.3×10⁸ M_⊙ of such material is present within 5 kpc of the nucleus, if the line-emitting clouds see an unobscured quasar spectrum. Alternatively, if the bulk of the X-ray absorption to the nucleus inferred by Ueno et al. actually arises in a circumnuclear torus, the implied gas mass rises to ∼10¹⁰ M_⊙. The latter plausibly accounts for 10⁹ yr of mass deposition from the cluster cooling flow, for which within this radius.