早古生代古亚洲洋俯冲记录:来自东天山卡拉塔格高镁安山岩的年代学、地球化学证据

吐哈盆地南缘荒草坡群大柳沟组火山岩出露于大草滩断裂以北的彩霞山、土屋铜矿北和卡拉塔格地区。该组火山岩主要为基性、中酸性熔岩及火山碎屑岩组合。LA-ICP MS锆石U-Pb分析获得安山岩和英安岩的年龄分别为434.8±3.8Ma和438.4±4.9Ma,表明大柳沟组火山岩形成于早志留世。安山岩Si O2含量为54.35%~60.70%;Al2O3含量为11.8%~16.3%,Mg O含量为4.94%~8.27%,Ti O2含量为0.38%~0.52%,Na2O和K2O的含量分别为0.50%~3.83%和0.08%~1.26%,铝饱和指数(A/CNK)为0.77~1.37,低ΣREE(43×10-6~70×10-6),为具有亏损源区特征的高镁安山岩。英安岩较安山岩Si O2含量高(63.74%~75.35%),具有相似的Al2O3(12.3%~16.0%%)和Ti O2(0.32%~0.52%)含量;Na2O和K2O含量分别为2.01%~5.53%和0.16%~2.19%,ΣREE含量较安山岩略高(61×10-6~84×10-6),铝饱和指数(A/CNK)为0.77~5.74。安山岩和英安岩均轻重稀土分异明显,具有中等的Eu负异常;富集大离子亲石元素(LILE),亏损高场强元素(HFSE),具有明显的Nb-Ta-Ti负异常。相似的岩石地球化学特征表明安山岩和英安岩可能为同源岩浆,英安岩是安山质岩浆经过角闪石等矿物结晶分异作用形成的,安山岩的母岩岩浆很可能来自亏损大洋岩石圈地幔。基于该组岩石组合、地球化学特征和区域地质资料,推测研究区高镁安山岩可能形成于洋内弧环境,这表明东天山吐哈盆地南缘卡拉塔格地区在早古生代已经存在古亚洲洋的俯冲。     

Metamorphic reactions in dry and aluminous granulites: a Perple_X <Emphasis Type="Italic">P–T</Emphasis> pseudosection analysis of the influence of effective reaction volume

In high-Mg, Al metapelites, monophase sapphirine corona occur around spinel–corundum aggregates in monomineralic cordierite layers, and bi-phase orthopyroxene–sillimanite aggregates replace locally warped sapphirine in polygonized cordierite aggregates. P–T phase topologies computed (Perple_X software) using compositions of cordierite-rich layers that host the reaction textures did not match the assemblages for the discontinuous reactions spinel + corundum + cordierite → sapphirine and sapphirine + cordierite → orthopyroxene + sillimanite. Instead, the reaction assemblages were reproduced using P–T pseudosection analysis for micro-domain reaction volumes estimated from compositions of product phases in the volume proportion they occur. The results are consistent with known phase relations deduced using Schreinmakers P–T grids. Apparently, the compositions of cordierite-rich layers that hosted the reaction textures were inadequate chemical proxies for determining P–T–X relations of phase-boundary controlled reactions influenced by compositions of the nearest-neighbor minerals in the proportion they react (effective composition), and not in the proportion they existed in the layer/bulk rock. In other words, P–T–X phase topologies and reconstructed P–T paths in dry and aluminous rocks may be best understood by thermodynamic modeling of reactions using effective reaction volume compositions rather than the bulk composition of the rock or the mineralogical layer that host the reaction textures.     

西藏班公湖-怒江缝合带中段侏罗纪高镁安山质岩石对中特提斯洋演化的制约

班公湖-怒江缝合带中段地区南北向分布了三条分支蛇绿岩亚带,它们记录了该地区中特提斯洋复杂的构造演化过程。目前对于该地区洋盆俯冲消减动力学过程一直缺乏有效制约。为探讨这一问题,本文对班公湖-怒江缝合带中段新近厘定的安山岩和闪长岩开展了系统的野外、岩石地球化学和锆石U-Pb年代学研究。安山岩主要呈不整合覆盖于晚三叠世沉积地层之上,或与侏罗纪俯冲增生杂岩和橄榄岩以断层接触,闪长岩主要呈岩脉体侵入于橄榄岩中。锆石U-Pb定年表明,安山岩和闪长岩均形成于中晚侏罗世(165～161Ma)。安山岩和闪长岩地球化学组成类似,它们大都具有高的MgO含量和Mg#值,这与高镁安山岩相类似。稀土和微量元素组成显示出典型的岛弧岩浆岩特征,富集轻稀土(LREE)和Rb、Th、U、Pb等元素,亏损Ba和高场强元素(HFSE; Nb,Ta和Ti)。同时,样品还显示出较低的Ba/Th和较高的(La/Sm)N比值,以及负的锆石εHf(t)值和古老的锆石Hf模式年龄。这些特征表明这些高镁安山岩和闪长岩是大洋板片俯冲沉积物部分熔融的熔体交代地幔楔的产物。结合区域地质和前人研究,认为这些岩石可能形成于靠近海沟的大陆边缘环境,是班公湖-怒江中特提斯洋中段北拉-拉弄分支洋盆初始俯冲消减的产物,该初始俯冲作用可能与安多微陆块和南羌塘地块碰撞导致的俯冲南向跃迁有关。     

西天山东塔尔别克金矿区安山岩LA-ICP-MS锆石U-Pb年代学、元素地球化学与岩石成因

东塔尔别克金矿区位于西天山吐拉苏盆地内阿希金矿区南侧,构造上属于伊犁-中天山微板块与准噶尔板块之间的博罗科努早古生代岛弧带西段。东塔尔别克矿区出露有一些安山岩,这些岩石具有典型高镁安山岩特征,如高硅（SiO₂=58.94%~63.85%),具有较高的MgO含量(3.75%~6.59%)和Mg^#(58~69)、高的Cr（94.2×10^-6~241×10^-6）、和Ni（54.5×10^-6~126 ×10^-6）含量,以及低的FeO^T/MgO比值。除了Sr含量略微偏低（235×10^-6~696×10^-6）之外,这些岩石基本显示了埃达克岩的地球化学特征：高的Al₂O₃（15.39%~16.65%）,低Y（9.86×10^-6~14.9×10^-6）含量,以及高的Sr/Y比值(23.8~48.1),无Eu异常,Nb、Ta、Ti亏损等。LA-ICP-MS锆石U-Pb测年结果显示安山岩的年龄为347.2±1.6Ma,为早石炭世。安山岩富集Rb、Th、U 等大离子亲石元素,相对亏损Nb、Ta、Ti等高场强元素,轻重稀土元素分馏明显,具有俯冲带岛弧岩浆的特征。东塔尔别克安山岩可能形成于岛弧环境中,并可能由俯冲的晚古生代北天山洋洋壳以及少量上覆沉积物熔融形成,产生的熔体在上升过程中与地幔橄榄岩发生了相互作用. 熔体-地幔相互作用对区内金矿的形成具有重要意义。     

华北克拉通新太古代板块俯冲作用:来自山西云中山地区变质高镁火成岩组合的证据

在华北克拉通中部的山西云中山地区,新太古代花岗闪长质片麻岩中存在一些超镁铁质岩-镁铁质岩块及由斜长角闪岩、角闪变粒岩、石英岩和石榴夕线黑云片岩等岩石类型构成的变质表壳岩残片,其中的超镁铁质-镁铁质岩、斜长角闪岩和角闪变粒岩构成一套高镁火成岩组合。超镁铁质岩已变质为橄榄绿泥阳起片岩等岩石类型,呈变余斑状结构,橄榄石斑晶仍有保存;岩石SiO_2含量为39.22%～44.99%,Al_2O_3为8.82%～13.47%,Mg O为19.24%～22.13%,Na_2O+K_2O=0.71%～1.11%,CaO为5.75%～8.42%;Al_2O_3/TiO_2=14.8～17.4,CaO/Al_2O_3=0.60～0.84;化学成分上与科马提岩有一定的相似性。与之紧密伴生的斜长角闪岩也具有高镁特征,Mg O含量为11.28%～15.09%,铝、硅和碱质均偏低,具正铕异常,显示堆晶辉长岩的特征。非高镁斜长角闪岩有相对高的铝、硅和碱质,其原岩应为钙碱性玄武岩。角闪变粒岩样品的SiO_2含量为54.21%～55.71%,Al_2O_3为14.24%～15.49%,Mg O为6.26%～8.28%,Fe OT/Mg O=1.11～1.58,高钠低钾,Na_2O+K_2O=3.7%～4.78%,Na_2O/K_2O=5.15%～13.13,Mg#=53.0～61.5,属于高镁安山岩。由超镁铁质质岩-斜长角闪岩-角闪变粒岩构成的变质高镁火山岩组合具有钙碱性系列趋势。超镁铁质岩稀土元素含量总量较低,具有轻稀土富集和重稀土亏损的稀土型式;斜长角闪岩与超镁铁质岩比较,除富集大离子亲石元素和Cr、Ni明显较低外,具有相似的微量元素图谱形态。三种岩石类型在微量元素蛛网图上均显示出Ta、Nb、Ti负异常和Pb正异常。野外产状和岩石地球化学特征表明超镁铁质岩和高镁斜长角闪岩属于阿拉斯加型杂岩体,角闪变粒岩属于赞岐岩质高镁安山岩。在Zr/Nb-Nb/Th和Nb/Y-Zr/Y构造环境判别图解上显示出与俯冲相关的演化趋势,在Hf-Th-Ta、Nb/La-(La/Sm)N和Th/Yb-Nb/Yb图解上也落在岛弧钙碱性岩石区域。以上特征表明高镁火成岩组合形成于与板块俯冲相关的岛弧构造背景。野外地质关系和锆石U-Pb年龄限定高镁火成岩组合形成时代在～2.5Ga。云中山地区阿拉斯加型镁铁质-超镁铁质杂岩与赞岐岩质高镁安山岩共生,表明该地区存在新太古代的板块俯冲作用,为太古宙存在板块构造机制提供了新证据。     

天山北部石炭纪埃达克岩-高镁安山岩-富Nb岛弧玄武质岩：对中亚造山带显生宙地壳增生与铜金成矿的意义

新疆天山北部地区存在有石炭纪的埃达克岩-高镁安山岩-富Nb玄武质岩组合，并且其中许多岩石与铜（金）矿床伴生（如达巴特、阿希、土屋-延东、赤湖，等等）。埃达克岩富钠、高Sr但亏损Y与Yb，无明显Eu-正Eu异常以及正Sr异常与Nb、Ti亏损。高镁安山（闪长）岩是本次研究首次报道的，这些岩石无明显Eu-正Eu异常以及Nb、Ti亏损，普遍具有高的MgO和Cr、Ni含量，其中阿希金矿区一些样品类似于日本西南新生代Setouchi弧火山岩带中的赞岐岩类。富Nb玄武质岩富钠贫钾，具有微弱负．正Ba、Nb和Ti异常以及高的Nb／La比值，不同于大多数正常岛弧玄武岩。天山北部地区石炭纪埃达克岩具有高的8Nd（t）（＋3．4-＋9．0）和低的（^87Sr／^86Sr）i（0．7032—0．7043）。富Nb玄武质岩具有变化的εNd（t）（＋3．6-＋11．6）和（^87Sr／^86Sr）；（0．7007—0．7067）。我们的研究表明，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合可能是“埃达克岩交代的岛弧岩浆岩系列”。埃达克岩最有可能由石炭纪北天山洋的年轻洋壳在俯冲过程中熔融形成。另外，俯冲板片产生的熔体以及所释放的少量流体在上升过程中可能交代地幔楔橄榄岩或与其发生反应：一方面，触发地幔楔橄榄岩发生熔融形成富Nb岛弧玄武质岩；另一方面，地幔组分迅速进入到板片熔体中，导致其地幔组分增加，乃至形成高镁安山岩。因此，天山北部地区石炭纪埃达克岩-高镁安山岩-富Nb玄武质岩组合表明：（1）天山北部地区石炭纪可能为岛弧环境而非裂谷环境；（2）天山地区石炭纪的地壳生长可能以侧向增生为主；（3）除了亏损地幔之外，俯冲洋壳的熔融可能也在地壳的生长中发挥了重要的作用；（4）俯冲板片产生的埃达克质岩浆具有高的氧逸度，而其与地幔楔橄榄岩的强烈相互作用将导致地幔中的金属硫化物分解，成矿金属元素进入到岩浆中。这可能是新疆北部铜金矿化与一些埃达克岩、高镁安山（闪长）岩或富Nb岛弧玄武质岩密切共生的基本原因。     

Infant intra-oceanic arc magmatism due to initial subduction induced by oceanic plateau accretion: A case study of the Bangong Meso-Tethys,central Tibet,western China

The Meso-Tethyan oceanic plateaus are becoming conspicuous as giant units on the oceanic floor and have played important roles in both continental marginal orogenesis and Tethys oceanic evolution. In this study, we present mineralogical, geochronological, geochemical and Sm–Nd isotopic data for basaltic lavas from the Namco ophiolite and a high-Mg pillow lava–dyke–gabbro association from the Pengco ophiolite in central Tibet. Zircon U–Pb and Ar–Ar dating reveals that the Namco lavas erupted at ∼181 Ma while the Pengco boninitic association formed at ∼164 Ma. The Namco lavas display nearly flat rare-earth element (REE) patterns with no Nb–Ta depletions as well as high ε_Nd values, characteristic of oceanic plateau lava. In contrast, the Pengco high-Mg rocks exhibit low REE concentrations below the normal mid-ocean ridge basalt (N-MORB), ubiquitous Nb–Ta depletions and low ε_Nd values, and the dykes and gabbros are characterized by U-shape REE patterns, indicating that they could have derived from a depleted mantle source that was contaminated by sedimentary flux and marking a mid-Jurassic initial intra-oceanic arc magmatism erupted on the Early Jurassic Meso-Tethyan oceanic plateau represented by the Namco ophiolite. Our Pengco boninitic rocks, along with the literature data, indicate a 167–160 Ma boninitic-like initial intra-oceanic arc within the Bangong Meso-Tethys, running from the Shiquanhe area to the Naqu area with a length of ∼1000 km, which was uniformly built on the Early Jurassic Meso-Tethyan oceanic plateau. Our literature investigation also indicates a ∼175 Ma accretionary orogeny with distinct signature of the oceanic plateau involvements along the southern Qiangtang continental margin, which is manifested by regional metamorphic, magmatic and depositional records. We thus suggest that the accretion of the Early Jurassic Meso-Tethyan oceanic plateau onto the southern Qiangtang continental margin resulted in the extensive orogeny along the continental margin, jammed the subduction zone at ∼175 Ma and induced intra-oceanic subduction initiation as well as the intra-oceanic infant arc magmatism in the Meso-Tethys at ∼164 Ma.     

Petrogenesis of Shangyu gabbro-diorites in western Shandong: Geochronological and geochemical evidence

Chronology and geochemistry of the Shangyu gabbro-diorite in western Shandong were studied to understand their petrogenesis and the nature of the Mesozoic lithospheric mantle. The Shangyu intru-sion is mainly composed of a suite of gabbro-diorite. Zircons from the intrusion display eu-hedral-subhedral in shape and have high Th/U ratios (1.23―2.87), implying their magmatic origin. LA-ICP-MS zircon U-Pb dating results for two samples indicate that they were formed in the Early Cre-taceous, yielding weighted mean 206Pb/238U ages of 129±1Ma and 134±2Ma, respectively. Except for early cumulate such as sample QT-19, their SiO2 and MgO contents range from 50.12% to 56.37% and from 3.52% to 6.37%, respectively. Moreover, the gabbro-diorites are characterized by high Mg# (0.54―0.63), enrichment in Na (Na2O/K2O ratios more than 1), Cr (73×10-6―217×10-6) and Ni (34×10-6―241×10-6), and intensive enrichments in light rare earth elements (LREEs) and large ion lithophile elements (LILEs) and depletion in high field strength elements (HFSEs). Their initial 87Sr/86Sr ratios and ε Nd(t) values range from 0.70962 to 0.71081 and from-16.60 to-13.04, respectively. Taken together with the Early Creta-ceous high-Mg diorites and the mantle xenoliths from the Tietonggou and Jinling as well as basalts from the Fangcheng and Feixian, it is suggested that the primary magma for the Shangyu gab-bro-diorites should be derived from the enriched lithospheric mantle intensively modified by conti-nental crust. The Sr-Nd-Pb isotopic compositions for the Early Cretaceous high-Mg diorites in western Shandong display a trend of spatial variations, i.e., initial 87Sr/86Sr, 207Pb/204Pb and 208Pb/204Pb ratios de-creasing and ε Nd(t) values increasing from southeast to northwest in western Shandong, which is con-sistent with the tectonic model that the Yangtze Craton subducted beneath the North China Craton oriented in north-west direction in the Early Mesozoic.     

北祁连山东段银硐粱早古生代高镁埃达克岩：地球动力学及成矿意义

银硐粱早古生代花岗闪长岩分布在北祁连造山带东段屈吴山地区,侵入于原阴沟群和前寒武纪变质岩系中。它与米家山、扁强沟、清凹山以及南华山花岗岩类共同构成长约220千米的构造—花岗岩带,沿 NW-NWW 向展布。地球化学研究结果表明,银硐粱花岗闪长岩具有典型的高镁埃达克岩的地球化学特征,它们具有富 Na 贫 K,SiO_2>56%,Al_2O_3>15%,Na_2O>4.0%(4.51%～4.92%),K_2O(1.96～2.77%),Na_2O/K_2O=1.63～2.40,属钙碱性侵入岩;高 Sr(599～691×10~(-6)),低 Y(6.3～8.1×10~(-6)),Sr/Y>40(81～94),Y/Yb>10(Yb<1.9×10~(-6)),La/Yh>20(22～45)以及相对于典型的埃达克岩,具有更高的 Mg~#(58～64,平均59)和相容元素 Ni(31～38×10~(-6))和 Cr(35～43×10~(-6))含量;富集轻稀土元素(LREE),亏损重稀土元素(HREE),(La/Yb)_N>10(16～32),轻微负 Eu 异常(Eu/Eu*平均为0.94),∑REE(85～112)×10~(-6);微量元素蛛网图显示,岩石富集大离子亲石元素(Rb、Ba、Sr),Nb-Ta 和 Ti 负异常,相对于 Ce 和 Nd,Sr 为正异常。由于银硐粱高镁埃达克岩是俯冲洋壳部分熔融的产物,因此,它的存在表明,老虎山弧后洋盆在早古生代早期发生了向北的俯冲作用。银硐粱 Cu-Au 成矿作用与高镁埃达克岩关系密切,表明在北祁连构造带东段寻找与埃达克岩有关的 Cu-Au 矿床是一个新的找矿思路。     

High-Mg diorites derived from sanukitic HMA magmas, Kyushu Island, southwest Japan arc: evidence from clinopyroxene and whole rock compositions

High-Mg diorites that have similar whole rock composition to high-Mg andesites (HMAs) should not be simply interpreted as rocks solidified from the HMA magmas, because the high-Mg diorites may be mafic cumulates derived from a different magma from the HMAs.

The HMAs contain unique clinopyroxenes with higher Mg# and Si than those of other sub-alkaline series igneous rocks. The Mg# and Si are controlled by the source magma composition rather than its crystallized conditions such as pressure and temperature. The chemical composition of clinopyroxenes would present important information for the investigation of the source of high-Mg diorites.

We considered the source of Early Cretaceous high-Mg diorites on Kyushu Island, southwest Japan arc, based on their clinopyroxene and whole rock compositions. The clinopyroxenes have similar chemical characteristics to those in HMAs rather than those in other sub-alkaline rocks. Moreover, the whole rock compositions are equivalent to the sanukitic HMA and do not show features of mafic cumulates. This indicates that the high-Mg diorites solidified from sanukitic HMA magmas. It is generally believed that the sanukitic HMA magmas involve the subduction of a young and/or hot oceanic slab was situated in their genesis. Therefore, the occurrence of the high-Mg diorites suggests that Kyushu was situated in the tectonic setting of young and/or hot slab subduction in the Early Cretaceous.