超基性岩中含铜、钴块状硫化物矿床——德尔尼铜矿成因新认识

长期以来对德尔尼铜矿的成因存在着不同认识。从矿石组成和结构、构造来看,应属典型的块状硫化物矿石,矿床亦应属于含铜黄铁矿型矿床。但从其地质产状来看又与一般的黄铁矿型矿床大不相同,与一般的岩浆熔离铜镍硫化物矿床也有较多差异。这就是本矿床类型独特之处。近年来通过工作又取得一些新资料,特别是超基性岩和矿石的同位素年龄数据。本文在综合新老资料基础上,提出新看法,认为该矿床形成于上地幔,再就位于地壳浅部。其成因类型暂定为:“深部熔离—构造侵位矿床”。鉴于本矿床与一般块状硫化物矿床相比有其独特性,建议命名为“德尔尼型”。     

SHRIMP zircon dating and Sm/Nd isotopic investigations of Neoproterozoic granitoids, Eastern Desert, Egypt

There is an increasing evidence for the involvement of pre-Neoproterozoic zircons in the Arabian–Nubian Shield, a Neoproterozoic crustal tract that is generally regarded to be juvenile. The source and significance of these xenocrystic zircons are not clear. In an effort to better understand this problem, older and younger granitoids from the Egyptian basement complex were analyzed for chemical composition, SHRIMP U–Pb zircon ages, and Sm–Nd isotopic compositions. Geochemically, the older granitoids are metaluminous and exhibit characteristics of I-type granites and most likely formed in a convergent margin (arc) tectonic environment. On the other hand, the younger granites are peraluminous and exhibit the characteristics of A-type granites; these are post-collisional granites. The U–Pb SHRIMP dating of zircons revealed the ages of magmatic crystallization as well as the presence of slightly older, presumably inherited zircon grains. The age determined for the older granodiorite is 652.5 ± 2.6 Ma, whereas the younger granitoids are 595–605 Ma. Xenocrystic zircons are found in most of the younger granitoid samples; the xenocrystic grains are all Neoproterozoic, but fall into three age ranges that correspond to the ages of other Eastern Desert igneous rocks, viz. 710–690, 675–650 and 635–610 Ma. The analyzed granitoids have (+3.8 to +6.5) and crystallization ages, which confirm previous indications that the Arabian–Nubian Shield is juvenile Neoproterozoic crust. These results nevertheless indicate that older Neoproterozoic crust contributed to the formation of especially the younger granite magmas.     

Chemical and boron-isotope variations in tourmalines from an S-type granite and its source rocks: the Erongo granite and tourmalinites in the Damara Belt,Namibia

Tourmaline is widespread in metapelites and pegmatites from the Neoproterozoic Damara Belt, which form the basement and potential source rocks of the Cretaceous Erongo granite. This study traces the B-isotope variations in tourmalines from the basement, from the Erongo granite and from its hydrothermal stage. Tourmalines from the basement are alkali-deficient schorl-dravites, with B-isotope ratios typical for continental crust (δ¹¹B average −8.4‰ ± 1.4, n = 11; one sample at −13‰, n = 2). Virtually all tourmaline in the Erongo granite occurs in distinctive tourmaline-quartz orbicules. This “main-stage” tourmaline is alkali-deficient schorl (20–30% X-site vacancy, Fe/(Fe + Mg) 0.8–1), with uniform B-isotope compositions (δ¹¹B −8.7‰ ± 1.5, n = 49) that are indistinguishable from the basement average, suggesting that boron was derived from anatexis of the local basement rocks with no significant shift in isotopic composition. Secondary, hydrothermal tourmaline in the granite has a bimodal B-isotope distribution with one peak at about −9‰, like the main-stage tourmaline, and a second at −2‰. We propose that the tourmaline-rich orbicules formed late in the crystallization history from an immiscible Na–B–Fe-rich hydrous melt. The massive precipitation of orbicular tourmaline nearly exhausted the melt in boron and the shift of δ¹¹B to −2‰ in secondary tourmaline can be explained by Rayleigh fractionation after about 90% B-depletion in the residual fluid. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

郯庐断裂带张八岭隆起南段花岗岩LA-ICP MS锆石U-Pb年龄及其构造意义

本文利用LA-ICP MS方法,对零星分布于郯庐断裂带张八岭隆起南段肥东-巢湖地区的一些花岗岩体进行了锆石U-Pb同位素年代学研究.结果表明,西徐村北岩体、尖山岩体、西花村岩体、永丰岩体和锦张村岩体的形成年龄分别为126.9 ±1.0Ma、114.8±1.3Ma、108.1 ±1.6Ma、103.0 ±0.9Ma和120.3 ±0.7Ma,这些花岗岩体均形成于早白垩世,但侵位时间有一定差异.与郯庐断裂带西侧的鲁西、徐淮、蚌埠地区同时代克拉通内部侵入岩相比,断裂带内岩浆活动持续的时间更长(～27Ma).这一结果不但指示郯庐断裂带上的岩浆活动是不均一的,各地岩浆在活动的强烈程度和时间特征上均有很大的差异,而且显示了断裂带内比克拉通内部岩浆活动结束时间较晚,暗示其下岩石圈可能有更为强烈的减薄程度和更长的减薄历史.     

花岗岩研究的误区——关于花岗岩研究的思考之五

本文在对花岗岩四大基石(混合作用、结晶分离作用、构造环境和源区)问题分析的基础上,指出花岗岩研究存在的三大误区: (1)不恰当地仿效玄武岩的理论和研究方法,忽视了花岗岩的复杂性。(2)不恰当地用板块构造学说解释大陆花岗岩问题。板块构造是地球演化到一定阶段的产物,并成功解释了与板块边界相联系的岩浆活动,但是,它不能解决主要来源于大陆的花岗岩的地质问题。(3)太过重视花岗岩的地球化学研究而忽视了对花岗岩基础地质的研究。作者指出,地球化学方法在花岗岩中的使用应当是有限制的,花岗岩研究陷入误区是我们缺少扎实的基础研究、对板块构造的理解不深和对花岗岩复杂性认识不足等三个方面的原因造成的。文中还批评了学术界存在的人云亦云的奴性思想,指出它严重地阻碍了我们的创新思维,是当前亟待改进和克服的。     

21世纪的花岗岩研究, 路在何方？——关于花岗岩研究的思考之六

21世纪的花岗岩怎样研究是一个需要探索的问题。作者认为,应当对现有的花岗岩理论、流行的说法以及术语等进行清理和反思,汲取其精华,剔除其糟粕,抛弃那些不科学、不符合实际、不符合逻辑的部分。例如,在花岗岩研究中摈弃结晶分离的理论,缩小花岗岩混合作用的意义,限制花岗岩构造环境理论的应用,取消幔源、壳源和壳幔混合源的术语等。作者指出,今后花岗岩研究应当着重解决两个问题: (1)花岗岩是怎样的？(2)它何以是这样的？文中提出5个方面的任务作为今后研究的重点,即: 开展花岗岩立典式的研究,将花岗岩研究与古老地壳的研究结合起来,将花岗岩物理性质研究与地球化学究结合起来,开展广泛的实验岩石学研究和创建新的“大陆构造学”理论。鉴于花岗岩研究目前存在的严重误区,现有的花岗岩理论几乎全面崩溃,由四大基石支撑的花岗岩大厦行将坍塌,花岗岩研究正面临全球大洗牌。为此,作者建议开展一场关于花岗岩的大辩论,目的是清理思路,认清问题,明确方向,找到出路。作者呼吁,我们应当加强学习,加速引进人才,克服急躁情绪和浮夸的学风,摈弃从众思想和奴性思想,不以SCI论英雄,改进我们的学习,改善我们的制度,以推进花岗岩研究迈上新台阶。     

Heat flow and crustal thermal structure in the Late Archaean Closepet Granite batholith,south India

The Late Archaean Closepet Granite batholith in south India is exposed at different crustal levels grading from greenschist facies in the north through amphibolite and granulite facies in the south along a ∼400 km long segment in the Dharwar craton. Two areas, Pavagada and Magadi, located in the Main Mass of the batholith, best represent the granitoid of the greenschist and amphibolite facies crustal levels respectively. Heat flow estimates of 38 mW m⁻² from Pavagada and 25 mW m⁻² from Magadi have been obtained through measurements in deep (430 and 445 m) and carefully sited boreholes. Measurements made in four boreholes of opportunity in Pavagada area yield a mean heat flow of 39 ± 4 (s.d.) mW m⁻², which is in good agreement with the estimate from deep borehole. The study, therefore, demonstrates a clear-cut heat flow variation concomitant with the crustal levels exposed in the two areas. The mean heat production estimates for the greenschist facies and amphibolite facies layers constituting the Main Mass of the batholith are 2.9 and 1.8 μW m⁻³, respectively. The enhanced heat flow in the Pavagada area is consistent with the occurrence of a radioelement-enriched 2-km-thick greenschist facies layer granitoid overlying the granitoid of the amphibolite facies layer which is twice as thick as represented in the Magadi area. The crustal heat production models indicate similar mantle heat flow estimates in the range 12–14 mW m⁻², consistent with the other parts of the greenstone-granite-gneiss terrain of the Dharwar craton.     

安徽董岭花岗岩类的构造特征及侵位机制

安徽怀宁董岭花岗岩类底辟滑覆构造体系是长江中下游地域独特的构造形式。花岗岩底辟构造是在中生代华北地块与扬子地块碰撞背景下通过气球膨胀机制侵位至盖层内(燕山期),形成了围绕董岭几何中心的环状或半环状接触变质和韧性变形岩块。该花岗岩类其内部变形明显,岩相分带、分期清晰,围岩顶盖保存完好,围岩变质均匀,变形强烈,滑覆断层发育,糜棱岩典型等为特征,是一个罕见的盖层中花岗岩类底辟构造。后期在其北侧和东侧被月山—白子山冲断岩块所超覆。     

The emplacement of intermediate volume ignimbrites: A case study from Roccamonfina Volcano,Southern Italy

A model is presented for the emplacement of intermediate volume ignimbrites based on a study of two 6 km³ volume ignimbrites on Roccamonfina Volcano, Italy. The model considers that the flows were slow moving, and quickly deflated from turbulent to non-turbulent conditions. Yield strength and density increased whereas fluidisation decreased with time and runout of the pyroclastic flows. In proximal locations, on the caldera rim, heterogeneous exposures including discontinuous lithic breccias, stratified and cross-stratified units interbedded with massive ignimbrite suggest deposition from turbulent flows. In medial locations thick, massive ignimbrite occurs associated with three types of co-ignimbrite lithic breccia which we interpret as being emplaced by non-turbulent flows. Multiple grading of different breccia/lithic concentration types within single flow units indicates that internal shear occurred producing overriding or overlapping of the rear of the flow onto the slower-moving front part. This overriding of different parts of non-turbulent pyroclastic flows could be caused by at least two different mechanisms: (1) changes in flow regime, such as hydraulic jumps that may occur at breaks in slope; and (2) periods of increased discharge rate, possibly associated with caldera collapse, producing fresh pulses of lithic-rich material that sheared onto the slower-moving part of the flow in front.We propose that ground surge deposits enriched in pumice compared with their associated ignimbrite probably formed by a flow separation mechanism from the top and front of the pyroclastic flow. These turbulent clouds moved ahead of the non-turbulent lower part of the flow to form stratified pumice-rich deposits. In distal regions well-developed coarse, often clast-supported, pumice concentrations zones and coarse intra-flow-unit lithic concentrations occur within the massive ignimbrite. We suggest that the flows were non-turbulent, possessed a relatively high yield strength and may have moved by plug flow prior to emplacement.     

Porphyroblast rotation during crenulation cleavage development: an example from the aureole of the Mooselookmeguntic pluton, Maine, USA

In the low‐pressure, high‐temperature metamorphic rocks of western Maine, USA, staurolite porphyroblasts grew at c. 400 Ma, very late during the regional orogenesis. These porphyroblasts, which preserve straight inclusion trails with small thin‐section‐scale variation in pitch, were subsequently involved in the strain and metamorphic aureole of the c. 370 Ma Mooselookmeguntic pluton. The aureole shows a progressive fabric intensity gradient from effectively zero emplacement‐related deformation at the outer edge of the aureole ～2900 m (map distance) from the pluton margin to the development of a pervasive emplacement‐related foliation adjacent to the pluton. The development of this pervasive foliation spanned all stages of crenulation cleavage development, which are preserved at different distances from the pluton. The spread of inclusion‐trail pitches in the staurolite porphyroblasts, as measured in two‐dimensional (2‐D) thin sections, increases nonlinearly from ～16° to 75° with increasing strain in the aureole. These data provide clear evidence for rotation of the staurolite porphyroblasts relative to one another and to the developing crenulation cleavage. The data spread is qualitatively modelled for both pure and simple shear, and both solutions match the data reasonably well. The spread of inclusion‐trail orientations (40–75°) in the moderately to highly strained rocks is similar to the spread reported in several previous studies. We consider it likely that the sample‐scale spread in these previous studies is also the result of porphyroblast rotation relative to one another. However, the average inclusion‐trail orientation for a single sample may, in at least some instances, reflect the original orientation of the overgrown foliation.