High-frequency monitoring of hydrological and biogeochemical fluxes in forested catchments of southern Chile

The variability of rainfall-dependent streamflow at catchment scale modulates many ecosystem processes in wet temperate forests. Runoff in small mountain catchments is characterized by a quick response to rainfall pulses which affects biogeochemical fluxes to all downstream systems. In wet-temperate climates, water erosion is the most important natural factor driving downstream soil and nutrient losses from upland ecosystems. Most hydrochemical studies have focused on water flux measurements at hourly scales, along with weekly or monthly samples for water chemistry. Here, we assessed how water and element flows from broad-leaved, evergreen forested catchments in southwestern South America, are influenced by different successional stages, quantifying runoff, sediment transport and nutrient fluxes during hourly rainfall events of different intensities. Hydrograph comparisons among different successional stages indicated that forested catchments differed in their responses to high intensity rainfall, with greater runoff in areas covered by secondary forests (SF), compared to old-growth forest cover (OG) and dense scrub vegetation (CH). Further, throughfall water was greatly nutrient enriched for all forest types. Suspended sediment loads varied between successional stages. SF catchments exported 455 kg of sediments per ha, followed by OG with 91 kg/ha and CH with 14 kg/ha, corresponding to 11 rainfall events measured from December 2013 to April 2014. Total nitrogen (TN) and phosphorus (TP) concentrations in stream water also varied with rainfall intensity. In seven rainfall events sampled during the study period, CH catchments exported less nutrients (46 kg/ha TN and 7 kg/ha TP) than SF catchments (718 kg/ha TN and 107 kg/ha TP), while OG catchments exported intermediate sediment loads (201 kg/ha TN and 23 kg/ha TP). Further, we found significant effects of successional stage attributes (vegetation structure and soil physical properties) and catchment morphometry on runoff and sediment concentrations, and greater nutrients retention in OG and CH catchments. We conclude that in these southern hemisphere, broad-leaved evergreen temperate forests, hydrological processes are driven by multiple interacting phenomena, including climate, vegetation, soils, topography, and disturbance history.     

Predicting quantiles of water quality from catchment characteristics

Water quality is often highly variable both in space and time, which poses challenges for modelling the more extreme concentrations. This study developed an alternative approach to predicting water quality quantiles at individual locations. We focused on river water quality data that were collected over 25 years, at 102 catchments across the State of Victoria, Australia. We analysed and modelled spatial patterns of the 10th, 25th, 50th, 75th and 90th percentiles of the concentrations of sediments, nutrients and salt, with six common constituents: total suspended solids (TSS), total phosphorus (TP), filterable reactive phosphorus (FRP), total Kjeldahl nitrogen (TKN), nitrate-nitrite (NO_x), and electrical conductivity (EC). To predict the spatial variation of each quantile for each constituent, we developed statistical regression models and exhaustively searched through 50 catchment characteristics to identify the best set of predictors for that quantile. The models predict the spatial variation in individual quantiles of TSS, TKN and EC well (66%–96% spatial variation explained), while those for TP, FRP and NO_x have lower performance (37%–73% spatial variation explained). The most common factors that influence the spatial variations of the different constituents and quantiles are: annual temperature, percentage of cropping land area in catchment and channel slope. The statistical models developed can be used to predict how low- and high-concentration quantiles change with landscape characteristics, and thus provide a useful tool for catchment managers to inform planning and policy making with changing climate and land use conditions.     

A dated cave sediment record of Pleistocene transgressions on Berry Head,Southwest England

Berry Head, a limestone headland in Torbay, southwest England, exhibits a series of subaerial marine erosion platforms and raised beaches spanning an altitude range of 97 m. Solution caves on the headland show preferred horizontal development at elevations that are correlated with the marine erosion platforms, and developed in a marine/freshwater mixing zone whose position was controlled by high sea-level still-stands. Corbridge Cave in Berry Head Quarry lies below the raised beaches in Torbay, and contains evidence of three marine transgressions in the form of fine-grained marine ponding deposits with a marine microfauna. Uranium-series dating of intercalated speleothems indicates that a transgression during oxygen isotope stage 5e reached an elevation of 5.8 m OD, while an earlier transgression (probably during stage 7) reached at least 7.2 m OD. These findings are used to constrain possible interpretations of the aminostratigraphy of raised beaches in Southwest Britain, and a correlation of the Unnamed Stage of Bowen, Sykes, Reeves, Miller, Andrews, Brew and Hare with oxygen isotope stage 5e is proposed.     

River sediments,great floods and centennial‐scale Holocene climate change

A new analysis of all 346 published ¹⁴C dated Holocene alluvial units in Britain offers a unique insight into the regional impacts of global change and shows how surprisingly sensitive British rivers have been to relatively modest but repeated changes in climate. Fourteen major but probably brief periods of flooding are identified bracketed within the periods 400–1070, 1940–3940, 7520–8100 and at ca. 10 420 cal. yr BP. There is a strong correspondence between climatic deteriorations inferred from mire wet shifts and major periods of flooding, especially at ca. 8000 cal. yr BP and since ca. 4000 cal. yr BP. The unusually long and complete British record also demonstrates that alterations in land cover have resulted in a step change in river basin sensitivity to variations in climate. This has very important implications for assessing and mitigating the impact of increasing severe flooding. In small and medium‐sized river basins land use is likely to play a key role in either moderating or amplifying the climatic signal. Copyright © 2003 John Wiley & Sons, Ltd.     

The solubility of iron sulphides in synthetic and natural waters at ambient temperature

A critical evaluation of literature values for the solubility products, K _sp ^NBS = [Fe²⁺][HS^–] Fe²⁺ HS^– (H _NBS ⁺ )^–1, of various iron sulphide phases results in consensus values for the pKs of 2.95 ± 0.1 for amorphous ferrous sulphide, 3.6 ± 0.2 for mackinawite, 4.4 ± 0.1 for greigite, 5.1 ± 0.1 for pyrrhotite, 5.25 ± 0.2 for troilite and 16.4 ± 1.2 for pyrite.Where the analogous ion activity products have been measured in anoxic freshwaters in which there is evidence for the presence of solid phase FeS, the values lie within the range of 2.6–3.22, indicating that amorphous iron sulphide is the controlling phase. The single value for a groundwater of 2.65 (2.98 considering carbonate complexation) agrees. In seawater four values range between 3.85 to 4.2, indicating that mackinawite or greigite may be the controlling phase. The single low value of 2.94 is in a situation where particularly high fluxes of Fe (II) and S (–II) may result in the preferential precipitation of amorphous iron sulphide. Formation of framboidal pyrite in these sulphidic environments may occur in micro-niches and does not appear to influence bulk concentrations. Calculations show that the formation of Fe₂S₂ species probably accounts for very little of the iron or sulphide in most natural waters. Previously reported stability constants for the formation of Fe (HS)₂ and (Fe (HS)₃)^– are shown to be suspect, and these species are also thought to be negligible in natural waters. In completely anoxic pore waters polysulphides also have a negligible effect on speciation, but in tidal sediments they may reach appreciable concentrations and lead to the direct formation of pyrite. Concentrations of iron and sulphide in pore waters can be controlled by the more soluble iron sulphide phase. The change in the IAP with depth within the sediment may reflect ageing of the solid phase or a greater flux of Fe (II) and S (–II) nearer the sediment surface. This possible kinetic influence on the value of IAPs has implications for their use in geochemical studies involving phase formation.     

The Lower Permian Wasp Head Formation,Sydney Basin: high‐latitude,shallow marine sedimentation following the late Asselian to early Sakmarian glacial event in eastern Australia

The Lower Permian Wasp Head Formation (early to middle Sakmarian) is a ～95 m thick unit that was deposited during the transition to a non‐glacial period following the late Asselian to early Sakmarian glacial event in eastern Australia. This shallow marine, sandstone‐dominated unit can be subdivided into six facies associations. (i) The marine sediment gravity flow facies association consists of breccias and conglomerates deposited in upper shoreface water depths. (ii) Upper shoreface deposits consist of cross‐stratified, conglomeratic sandstones with an impoverished expression of the Skolithos Ichnofacies. (iii) Middle shoreface deposits consist of hummocky cross‐stratified sandstones with a trace fossil assemblage that represents the Skolithos Ichnofacies. (iv) Lower shoreface deposits are similar to middle shoreface deposits, but contain more pervasive bioturbation and a distal expression of the Skolithos Ichnofacies to a proximal expression of the Cruziana Ichnofacies. (v) Delta‐influenced, lower shoreface‐offshore transition deposits are distinguished by sparsely bioturbated carbonaceous mudstone drapes within a variety of shoreface and offshore deposits. Trace fossil assemblages represent distal expressions of the Skolithos Ichnofacies to stressed, proximal expressions of the Cruziana Ichnofacies. Impoverished trace fossil assemblages record variable and episodic environmental stresses possibly caused by fluctuations in sedimentation rates, substrate consistencies, salinity, oxygen levels, turbidity and other physio‐chemical stresses characteristic of deltaic conditions. (vi) The offshore transition‐offshore facies association consists of mudstone and admixed sandstone and mudstone with pervasive bioturbation and an archetypal to distal expression of the Cruziana Ichnofacies. The lowermost ～50 m of the formation consists of a single deepening upward cycle formed as the basin transitioned from glacioisostatic rebound following the Asselian to early Sakmarian glacial to a regime dominated by regional extensional subsidence without significant glacial influence. The upper ～45 m of the formation can be subdivided into three shallowing upward cycles (parasequences) that formed in the aftermath of rapid, possibly glacioeustatic, rises in relative sea‐level or due to autocyclic progradation patterns. The shift to a parasequence‐dominated architecture and progressive decrease in ice‐rafted debris upwards through the succession records the release from glacioisostatic rebound and amelioration of climate that accompanied the transition to broadly non‐glacial conditions.     

Structural characterization of deep-water deposits in a foreland basin, Silla Syncline (Chilean Patagonia), with applications to depositional processes

Based on our detailed structural characterization, we examine possible relationships between thrust faults and strike-slip faults and thrust-cored folds and depositional units in the Silla Syncline, a 4 km wide fold composed of fine-grained mudstone, coarse sandstone and conglomerate deposits of the Cerro Toro Formation in the Magallanes foreland basin, Chilean Patagonia. The syncline is bounded on its western flank by an asymmetric anticline and on its eastern flank by a broad zone of thrust faults and associated folds, which are oriented sub-parallel to the syncline axis. Deposition of the coarse-grained units of the Silla Syncline appears to have taken place in this structurally defined trough controlled primarily by thrust fault related growth structures flanking the syncline.The syncline and surrounding area have also been deformed by two sets of strike-slip faults, one right-lateral and one left-lateral. The strike-slip and thrust faulting operated contemporaneously for much of their active periods, although it appears that thrust faulting, confined within the fine-grained units, initiated slightly earlier than strike-slip faulting. In addition, younger igneous intrusions at high angle to bedding generally localize along the strike-slip faults. The cross-cutting relationships among the intrusions, strike-slip faults, and flexural slip faults show that all these structures were active during the same period, which extends beyond mid-Miocene.These conclusions support the premise that structures in deep-water sediments are important for understanding not only the deformation of a foreland basin, but also its depositional architecture.     

Paleomagnetism and Detrital Zircon Geochronology of the Upper Vindhyan Sequence, Son Valley and Rajasthan, India: A ca. 1000 Ma Closure age for the Purana Basins?

The utility of paleomagnetic data gleaned from the Bhander and Rewa Groups of the “Purana-aged” Vindhyanchal Basin has been hampered by the poor age control associated with these units. Ages assigned to the Upper Vindhyan sequence range from Cambrian to the Mesoproterozoic and are derived from a variety of sources, including ⁸⁷Sr/⁸⁶Sr and δ ¹³C correlations with the global curves and Ediacara-like fossil finds in the Lakheri–Bhander limestone. New analyses of the available paleomagnetic data collected from this study and previous work on the 1073 Ma Majhgawan kimberlite, as well as detrital zircon geochronology of the Upper Bhander sandstone and sandstones from the Marwar SuperGroup suggest that the Upper Vindhyan sequence may be up to 500 Ma older than is commonly thought. Paleomagnetic analysis generated from the Bhander and Rewa Groups yields a paleomagnetic pole at 44°N, 214.0°E (A95 = 4.3°). This paleomagnetic pole closely resembles the VGP from the well-dated Majhgawan intrusion (36.8°N, 212.5°E, α₉₅ = 15.3°).Detrital zircon analysis of the Upper Bhander sandstone identifies a youngest age population at 1020 Ma. A comparison between the previously correlated Upper Bhander sandstone and the Marwar sandstone detrital suites shows virtually no similarities in the youngest detrital suite sampled. The main 840–920 Ma peak is absent in the Upper Bhander. This supports our assertion that the Upper Bhander is older than the 750–771 Ma Malani sequence, and is likely close to the age of the 1073 Ma Majhgawan kimberlite on the basis of the paleomagnetic similarities. By setting the age of the Upper Vindhyan at 1000–1070 Ma, several intriguing possibilities arise. The Bhander–Rewa paleomagnetic pole allows for a reconstruction of India at 1000–1070 Ma that overlaps with the 1073 ± 13.7 Majhgawan kimberlite VGP. Comparisons between the composite Upper Vindhyan pole (43.9°N, 210.2°E, α₉₅ = 12.2°) and the Australian 1071 ± 8 Ma Bangamall Basin sills and the 1070 Ma Alcurra dykes suggest that Australia and India were not adjacent at this time period.     

A late Neoproterozoic paleomagnetic pole for the Congo craton: Tectonic setting, paleomagnetism and geochronology of the Nola dike swarm (Central African Republic)

New structural, geochronological and paleomagnetic data were obtained on dolerite dikes of the Nola region (Central African Republic) at the northern border of the Congo craton. In this region, metavolcanic successions were thrust southward onto the craton during the Panafrican orogenic events. Our structural data reveal at least two structural klippes south of the present-day limits of the Panafrican nappe suggesting that it has once covered the whole Nola region, promoting the pervasive hydrothermal greenschist metamorphism observed in the underlying cratonic basement and also in the intrusive dolerite dikes. Paleomagnetic measurements revealed a stable dual-polarity low-inclination magnetization component in nine dikes (47 samples), carried by pyrrhotite and magnetite. This component corresponds to a paleopole at 304.8°E and 61.8°S (dp = 5.4, dm = 10.7) graded at Q = 6. Both metamorphism and magnetic resetting were dated by the ⁴⁰Ar/³⁹Ar method on amphibole grains separated from the dikes at 571 ± 6 Ma. The Nola pole is the first well-dated paleomagnetic pole for the Congo craton between 580 and 550 Ma. It marks a sudden change in direction of the Congo craton apparent polar wander path at the waning stages of the Panafrican orogenic events.     

Multiple discriminant analysis of the Drava River alluvial plain sediments

Three discriminant function models are raised and cross-compared in order to distinguish geochemical patterns characteristic for the Drava River floodplain sediments. Based on data representing total element concentrations in samples collected from alluvium (A), terrace (T), and unconsolidated bedrock (B) at the border of a floodplain, four element clusters emerged accounting for discrimination between the referred groups of sediments. The most prominent is contaminant/carbonate cluster characteristic for alluvium. The other two are: silicate cluster typical for unconsolidated geological substrate (Neogene sedimentary rocks); and naturally dispersed heavy metal cluster separating terrace from the former two groups. Models introducing depth intervals and single profiles as grouping criteria reveal identical sediment-heavy metal matrices. The second important issue of this paper is possibility of reclassification of samples originally assigned to one of the a priori defined groups of sediments, based on established geochemical pattern. The mapped geological units can be reconsidered by the post hoc assignments to a different group if geological border between alluvium and terrace or between terrace and bedrock can not be established geologically with absolute certainty.