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Gerrit de Leeuw Lucinda Spokes Tim Jickells Carsten Ambelas Skjth Ole Hertel Elisabetta Vignati Susanne Tamm Michael Schulz Lise-Lotte Srensen Britta Pedersen Laura Klein K. Heinke Schlünzen 《Continental Shelf Research》2003,23(17-19):1743
The ANICE (Atmospheric Nitrogen Inputs into the Coastal Ecosystem) project addressed the atmospheric deposition of nitrogen to the North Sea, with emphasis on coastal effects. ANICE focused on quantifying the deposition of inorganic nitrogen compounds to the North Sea and the governing processes. An overview of the results from modelling and experimental efforts is presented. They serve to identify the role of the atmosphere as a source of biologically essential chemical species to the marine biota. Data from the Weybourne Atmospheric Observatory (UK) are used to evaluate the effect of short episodes with very high atmospheric nitrogen concentrations. One such episode resulted in an average deposition of 0.8 mmol N m−2 day−1, which has the potential to promote primary productivity of 5.3 mmol C m−2 day−1. This value is compared to long-term effects determined from model results. The total calculated atmospheric deposition to the North Sea in 1999 is 948 kg N km−1, i.e. 0.19 mmol N m−2 day−1 which has the potential to promote primary productivity of 1.2 mmol C m−2 day−1. Detailed results for August 1999 show strong gradients across the North Sea due to adjacent areas where emissions of NOx and NH3 are among the highest in Europe. The average atmospheric deposition to the southern part of the North Sea in August 1999 could potentially promote primary production of 2.0 mmol C m−2 day−1, i.e. 5.5% of the total production at this time of the year in this area of the North Sea. For the entire study area the atmospheric contribution to the primary production per m2 is about two-third of this value. Most of the deposition occurs during short periods with high atmospheric concentrations. This atmospheric nitrogen is almost entirely anthropogenic in origin and thus represents a human-induced perturbation of the ecosystem. 相似文献
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It has been several years since the Greenhouse Gases Observing Satellite (GOSAT) began to observe the distribution of CO2 and CH4 over the globe from space. Results from Thermal and Near-infrared Sensor for Carbon Observation-Cloud and Aerosol Imager (TANSO-CAI) cloud screening are necessary for the retrieval of CO2 and CH4 gas concentrations for GOSAT TANSO-Fourier Transform Spectrometer (FTS) observations. In this study, TANSO-CAI cloud flag data were compared with ground-based cloud data collected by an all-sky imager (ASI) over Beijing from June 2009 to May 2012 to examine the data quality. The results showed that the CAI has an obvious cloudy tendency bias over Beijing, especially in winter. The main reason might be that heavy aerosols in the sky are incorrectly determined as cloudy pixels by the CAI algorithm. Results also showed that the CAI algorithm sometimes neglects some high thin cirrus cloud over this area. 相似文献
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Renee J. Perez Maurice Shevalier Ian Hutcheon Bernhard Mayer 《Journal of Geochemical Exploration》2006,89(1-3):326
We derive a thermodynamic model useful for calculating the partitioning of gases in brine–oil closed systems. We assumed real binary mixtures of all components, and solved a set of equilibrium equations relating the solubility of gases in brines to the solubility of gases in petroleum liquids. We applied the model to understand the distribution of gases in the IEA-GHG Weyburn CO2 Monitoring and Storage Project, in Saskatchewan, Canada, throughout the first and second year after commencement of CO2 injection. Results indicate that a free-gas phase formed in the south-east of the field 363 days after injection, which increased in size and volume with time, but did not correlate with zones showing excess CO2 production. We also observed overlaps between areas of 13C depleted HCO3− and areas with free-vapor phase. We conclude that gas injection leads to short-term CO2 dissolution in liquids, followed by the creation of a CO2-rich vapor phase. 相似文献
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中国休眠火山区岩浆来源气体地球化学特征 总被引:6,自引:1,他引:5
中国休眠火山区岩浆来源气体的最主要成分是CO2,含量占80%~99%;其它气体组分还有CH4、He、H2、N2、Ar、O2、H2S、SO2、CO等,其中CH4和He是CO2以外最值得重视的直接来自地幔岩浆体的气体组分。He的同位素组成(^3He/^4He比值)是休眠火山区最可靠的幔源物质的指示性参数;岩浆来源的CO2和CH4也具有特征的区别于浅源气体的稳定同位素组成(δ^13C值)。长白山火山区近期CO2和CH4的碳同位素分馏监测结果显示,2002年汪清7.2级深震虽然可能引发了深部岩浆的局部扰动,但是它可能并没有产生特别大量的、持续不断的上地幔岩浆物质流的上升迁移。这意味着,长白山天池火山区近期可能没有火山喷发活动的现实危险。 相似文献
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Columnar observations of liquid water and of radar echo intensity in cloud were carried out, using a microwave radiometer and a vertically pointing radar respectively, in Ny-Ålesund, Svalbard. Chemical concentrations were also measured in aerosols, gases and snowfalls. Clouds with a large proportion of liquid water moved over the site after snow clouds, with a much lower liquid water content, had been present for about 16 h. The mass concentrations of most chemical species in snowfalls were lower from the first set of clouds than the second. The NO3− and SO42− concentrations in gases and aerosols associated with the first set of clouds were higher than in the second set, but Cl− concentration was less for the first set than the second. 相似文献
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Gerrit de Leeuw Leo Cohen Lise Marie Frohn Gary Geernaert Ole Hertel Bjarne Jensen Tim Jickells Laura Klein Gerard J. Kunz Soren Lund Marcel Moerman Frank Müller Britta Pedersen Knut von Salzen K. Heinke Schlünzen Michael Schulz Carsten A. Skjth Lise-Lotte Sorensen Lucinda Spokes Susanne Tamm Elisabetta Vignati 《Continental Shelf Research》2001,21(18-19)
The aim of the atmospheric nitrogen inputs into the coastal ecosystem (ANICE) project is to improve transport–chemistry models that estimate nitrogen deposition to the sea. To achieve this, experimental and modelling work is being conducted which aims to improve understanding of the processes involved in the chemical transformation, transport and deposition of atmospheric nitrogen compounds. Of particular emphasis within ANICE is the influence of coastal zone processes. Both short episodes with high deposition and chronic nitrogen inputs are considered in the project. The improved transport–chemistry models will be used to assess the atmospheric inputs of nitrogen compounds into the European regional seas (the North Sea is studied as a prototype) and evaluate the impact of various emission reduction strategies on the atmospheric nitrogen loads. Assessment of the impact of atmospheric nitrogen on coastal ecosystems will be based on comparisons of phytoplankton nitrogen requirements, other external nitrogen inputs to the ANICE area of interest and the direct nitrogen fluxes provided by ANICE. Selected results from both the experimental and modelling components are presented here. The experimental results show the large spatial and temporal variability in the concentrations of gaseous nitrogen compounds, and their influences on fluxes. Model calculations show the strong variation of both concentrations and gradients of nitric acid at fetches of up to 25 km. Aerosol concentrations also show high temporal variability and experimental evidence for the reaction between nitric acid and sea salt aerosol is provided by size-segregated aerosol composition measured at both sides of the North Sea. In several occasions throughout the experimental period, air mass back trajectory analysis showed connected flow between the two sampling sites (the Weybourne Atmospheric Observatory on the North Norfolk coast of the UK and Meetpost Noordwijk, a research tower at 9 km off the Dutch coast). Results from the METRAS/SEMA mesoscale chemistry transport model system for one of these cases are presented. Measurements of aerosol and rain chemical composition, using equipment mounted on a commercial ferry, show variations in composition across the North Sea. These measurements have been compared to results obtained with the transport–chemistry model ACDEP which calculates the atmospheric inputs into the whole North Sea area. Finally, the results will be made available for the assessment of the impact of atmospheric nitrogen on coastal ecosystems. 相似文献
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The Soufrière Hills Volcano, Montserrat, erupting since 18 July 1995, intensified its degassing in early 1996 with the continuing
growth of the lava dome inside the summit crater. During this period of increased activity, between 11 and 18 March 1996,
we measured gases and particles within the visible plume to determine whether at that time it posed a health risk to the population
of Plymouth, the capital town, which is 5 km southwest (downwind) and was then still occupied. Gravimetric measurements were
made of total suspended particles (TSP) and particles having an aerodynamic diameter of less than 10 μm (PM10). Measurements were made of sulphur dioxide (SO2), hydrochloric acid (HCl), hydrofluoric acid (HF), nitric acid (HNO3), acetic acid (CH3COOH), formic acid (HCOOH), and particulate sulphate (SO4
2–), chloride (Cl–), nitrate (NO3
–), fluoride (F–), methanesulphonate (CH3SO3
–), acetate (CH3COO–), formate (HCOO–), ammonium (NH4
+), sodium (Na+) and acidity (H+). Trace metals having human health implications [chromium (Cr), nickel (Ni), cobalt (Co), copper (Cu), zinc (Zn), arsenic
(As), selenium (Se), cadmium (Cd), tin (Sn), mercury (Hg) and lead (Pb)] were also determined. Mean concentrations of HCl,
SO2 and HF obtained in the town of Plymouth were 14.0, 5.9 and 0.8 ppbv, respectively. Corresponding concentrations in the mixed
plume on the crater edge were 533, 168 and 22 ppbv. There were no direct emissions of HNO3, although nitrate was detected in coarse particles at the source. Higher concentrations of CH3COOH and HCOOH were measured close to the crater. Mean TSP and PM10 were 64 and 15 μg m–3 in Plymouth, and 455 and 47 μg m–3 on the upper volcano slope. Aerosols were highly acidic at the source but rapidly neutralised during transport. Trace metals
were enriched in the aerosol relative to crater surface material. The concentrations of the acid gases, sulphur dioxide in
particular, and particles were found to be too small to pose a health hazard at the time of these measurements, when relatively
modest volcanic activity was occurring.
Received: 9 September 1998 / Accepted: 29 August 1999 相似文献
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