Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

重庆地面最高气温与最大风速年极值的渐近分布

利用重庆1951-1990年间地面最高气温和1956-1990年间地面最大风速年极值的记录,采用韦伯分布和耿贝尔分布分别对其渐近分布进行拟合.通过统计推断,找出重庆地面最高气温和地面最大风速年极值遵循的最佳渐近分布--韦伯分布.     

AR（P）参数估计协方差方法与其改进型方法的对比研究

定性分析协方差方法及其改进型在ＡＲ（Ｐ）参数估计中的应用，提供了一种估计参数的计算机上机流程图，比较了协方差方法及其改进型谱估计结果。     

The Roche Limit

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.     

板翅式换热器综合性能优化的设计方法

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。     

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。     

关于网络用户经济效益评测模型的研究

着重讨论了网络用户经济效益的内涵以及用户的投入量和产出量，并提出了评价网络用户经济效益的指标体系，包括成本降低率，成本利润增长率、产品开发时间约率、市场占有增长率等系列指标。     

Wolf-Rayet stars

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.     

THE CORPORATE INTERVIEW AS A RESEARCH METHOD IN ECONOMIC GEOGRAPHY*

The open-ended corporate interview as a qualitative research method is proposed as a valuable component of an evidentiary strategy in economic geography. It is argued to be more sensitive than other survey methods to historical, institutional, and strategic complexity. The corporate interview method is particularly appropriate in periods of economic and social change that challenge traditional analytical categories and theoretical principles. Some problems inherent to the method, and strategies for minimizing their impact on the research project, are described.     

抗差估计的初值选择

对L1 范估计的平差值和LS估计的平差值作为抗差估计的初值进行了比较 ,指出在 ρ函数是严凸函数时 ,二者无明显的区别。因为LS估计简单且易于计算 ,因此建议用LS估计的平差值作为抗差估计的初值。