An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Crystal-Melt Separation and the Development of Isotopic Heterogeneities in Hybrid Magmas

If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with⁸⁷Sr/⁸⁶Sr of 0·7058, whereas the complementary crystal-poorsample has ⁸⁷Sr/⁸⁶Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite     

Crystal chemical significance of chemical zoning in dissakisite-(Ce)

Dissakisites from Trimouns dolomite mine, France, have two kinds of single crystals: chemical-zoned and homogeneous types. Back-scattered electron microprobe (BSE) images of these dissakisites reveal both Ca–Al rich dark zones and Fe-ΣREE rich bright zones. Crystal structures of three dark and two bright zones in a chemical-zoned dissakisite and of a homogeneous zone in unzoned dissakisite were refined to individual R indices (about 3.0–5.0%) based on 1,400 observed [|F ₀| > 4σF ₀] reflections measured with MoKα X-radiation using the single crystal diffractometer. The differences in brightness between their BSE images arise from those in coupled substitutions of the elements occupying A2 and M3 sites. The main reason for these differences is that ten-coordinated A2 polyhedra and M3 octahedra are directly linked through their shared edge, which creates a great potential for making this coupled substitution. This zoning indicates that formation of the whole zoned crystal, where each zone could be grown steadily with its crystallographic axes mutually parallel to each other, may be identified as autoepitaxy.     

Si diffusion in zircon

Self-diffusion of Si under anhydrous conditions at 1 atm has been measured in natural zircon. The source of diffusant for experiments was a mixture of ZrO₂ and ³⁰Si-enriched SiO₂ in 1:1 molar proportions; experiments were run in crimped Pt capsules in 1-atm furnaces. ³⁰Si profiles were measured with both Rutherford backscattering spectrometry (RBS) and nuclear reaction analysis with the resonant nuclear reaction ³⁰Si(p,γ)³¹P. For Si diffusion normal to c over the temperature range 1,350–1,550°C, we obtain an Arrhenius relation D = 5.8 exp(−702 ± 54 kJ mol⁻¹/RT) m² s⁻¹ for the NRA measurements, which agrees within uncertainty with an Arrhenius relation determined from the RBS measurements [62 exp(−738 ± 61 kJ mol⁻¹/RT) m² s⁻¹]. Diffusion of Si parallel to c appears slightly faster, but agrees within experimental uncertainty at most temperatures with diffusivities for Si normal to c. Diffusion of Si in zircon is similar to that of Ti, but about an order of magnitude faster than diffusion of Hf and two orders of magnitude faster than diffusion of U and Th. Si diffusion is, however, many orders of magnitude slower than oxygen diffusion under both dry and hydrothermal conditions, with the difference increasing with decreasing temperature because of the larger activation energy for Si diffusion. If we consider Hf as a proxy for Zr, given its similar charge and size, we can rank the diffusivities of the major constituents in zircon as follows: D _Zr < D _Si << D _{O, dry} < D _{O, ‘wet’}.     

云贵高原湖泊沉积物─水界面碱度扩散通量研究

于1991-1995年间5次在云贵高原泸沽湖、洱海湖和贵州阿哈湖、百花湖的湖心采集沉积物柱芯、界面水和湖水样品，通过其pH值和HCO-3浓度剖面及界面碱度扩散通量的研究，首次定量评估高原湖泊界面扩散作用上覆水体碱度的影响程度。研究结果表明，云贵高原某些湖水寄宿时间相对较长、湖水深度相对小的湖泊，界面扩散作用是水体碱度的重要来源之一;湖水寄宿时间较短、深度较小的湖泊，界面扩散对上覆水体的影响可以忽略不计。     

云贵高原湖泊沉积物─水界面碱度扩散通量研究

于１９９１－１９９５年间５次在云贵高原泸沽湖，洱海湖和贵州阿哈湖，百花湖的湖心采集沉积物柱芯，界面水和湖水样品，通过其ｐＨ值和ＨＣＯ３浓度剖面及界面碱度扩散通量的研究，首次定量评估高原湖泊界面扩散作用上不体碱度的影响程度，研究结果表明，云贵高原某些湖水寄宿时间对较长，湖水深度相对小的湖泊，界面扩散作用是水体碱度的重要来源之一，湖水寄宿时间较短，深度较小的湖泊，界面扩散对上覆水体的影响可以忽略不地。     

胶州湾东岸滩涂环境的遥感监测

利用低潮位陆地卫星TM影像对胶州湾东岸碱厂白水分布与扩散进行监测。对研究区的子区影像在ENVI中进行增强、变换处理，提取白水、白泥分布与扩散信息，制作大比例尺影像地图，在GIS软件中计算其面积。结合实地验证和历史数据，分析表明，该污染源10多年来面积扩大了4倍，     

底部边界层颗粒态物质迁移特征的放射性核素分析方法

利用颗粒态放射性核素携带的颗粒物历经过程信息,我们提出用泥沙扩散方程和颗粒态放射性核素扩散方程联解底部边界层颗粒态物质迁移参数的方法。分析实例的样品取自荷兰Waden Sea南部Balgzand潮滩(砂坪)和Mok湾潮滩(泥坪)的两个站位(BG1和Mok2)。示踪核素为~(234)Th,~(210)Pb和~(137)Cs,其放射性比度由r能谱测出。     

黔西北威-赫-纳-织-水地区铅锌(铜)矿带上 重力异常反映的地质信息

研究黔西北威宁—赫章—纳雍—织金—水城地区,铅锌(铜)矿带上分布的1∶20万区域重力异常特征,及其与地质、构造、岩体、化探等异常的对应规律及其关系,能对该区此类矿产的成矿规律、成矿部位和成矿特点的研究有所帮助,提出下一步找矿方向上的参考建议。     

陕西太白双王角砾岩型金矿的角砾岩特征

双王金矿床是秦岭泥盆系地层中一种类型独特富钠角砾岩型金矿床,在分析研究矿床赋矿地层、角砾岩带、角砾岩体的矿化及分带特征的基础上,阐述了该矿床的分带特征与金矿化的关系。