矿物的导电类型与矿物形成温度的关系

通过杂质对导电类型的影响的研究,得出了同种矿物的不同导电类型与矿物形成温度的规律:电子型(n型)导电矿物的形成温度大于电子与空穴混合型导电矿物的形成温度,又大于空穴型(p型)导电矿物的形成温度,绝缘体矿物的形成温度低于上述三种导电类型矿物。应用矿物热电图谱仪,天然金刚石半导体测试仪对闪锌矿、黄铁矿、金刚石等矿物的导电类型进行了测试,并探讨了导电类型成因,证实了上述规律的正确性。     

Ultrahigh pressure macro diamonds from Copeton (New South Wales, Australia), based on Raman spectroscopy of inclusions

Mining of Cenozoic alluvial deposits at Copeton and Bingara (Eastern Australia) has produced two million macrodiamonds (0.25 ct median size). Raman spectroscopy is used to identify included minerals within uncut Copeton diamonds, with sealed chamber remnant pressures of 31.7 to 35.6 kbar for coesite, 13.6 and 22.7 kbar for clinopyroxene, and 7.6 kbar for grossular garnet. Assuming elastic behaviour, these values generate inclusion entrapment PT loci which intersect, restricting diamond formation conditions: from 250 °C, 43 kbar to 800 °C, 52 kbar. Larger than error (± 100 °C and ± 4 kbar), this range shows a systematic variation in inclusion composition with diamond zoning and N properties. Published research shows 1) Copeton and Bingara diamonds are unique, and 2) modern alluvium in the Bingara district carries mantle-formed garnet, captured by post-tectonic alkali basalt from an extensive diamondiferous ultrahigh pressure (UHP) terrane that stalled at depth because it is dominated by mafic eclogite. The combined Raman and geological results indicate two sets of subduction UHP diamond formation conditions/protolith are required, firstly cooler oceanic slab and secondly including higher temperature continental crust. The Copeton and Bingara stones are UHP macrodiamonds, and Carboniferous ⁴⁰Ar/³⁹Ar age dates on clinopyroxene inclusions should be interpreted as ages of crystallisation, representing the termination of subduction. The characteristic features of ruptured inclusions and etched percussion marks on Copeton and Bingara diamond indicate volcanic delivery to the earth's surface. Alluvial deposits elsewhere in Eastern Australia may carry similar diamond along with diamond of different origin.     

我国西部特殊景观区化探方法研究进展

西部特殊景观区的化探方法研究一直是中国化探界的一个研究热点和难点.在岩石出露、水系发育地区可以沿用传统的水系沉积物化探方法,但在覆盖景观区,常规化探方法效果并不理想.目前,谢学锦和王学求所提出的深穿透地球化学方法,经过一系列的实验研究,证明其能在覆盖区达到快速有效地圈定战略靶区的作用,具有广泛的应用前景.要做好西部特殊景观区的化探工作,化探科研人员必需采取新方法、新思路,继续系统地开展化探方法技术研究,通过不懈的努力最终找到一套适合中国西部特殊景观区特别是覆盖区的行之有效的化探方法.     

云南潞西大矿山铅锌矿

矿体产于花岗岩以上断层附近大理岩中,大理岩与花岗岩接触部位是主要的矿化部位,在大矿山、小石林、灰窑等地见有强褐铁矿化、弱铅锌矿化的厚大矿化层。通过勘查工作,认为矿区具有寻找中-大型规模矿山的前景。     

安徽池州铜山铜矿深部找矿实践与启示

铜山铜矿资源储量日益枯竭。危机矿山接替资源勘查中,采用地质、物探综合手段圈定异常区,经深部钻探验证,取得突破。     

大岭子金矿地质特征及选矿浸出率

大岭子金矿V1矿体赋存于中元古界高黎贡山群变质岩中,受韧性剪切带控制,矿石类型以氧化矿石为主。提出选矿依据。     

富宁阳文冲-广南菜子垣热液淋滤卡林型金矿区

金矿区构造活动具有多期性：加里东期及海西期在矿区形成的薄弱角度不整合面、近南北向平行的滑脱断层,是含矿热液的运移、沉淀的通道和空间。金矿床应属地下热液淋滤卡林型金矿床。     

云南永胜宝坪浅源热液改造型铜矿地质及成因

宝坪铜矿赋存于三叠系下统腊美组中。矿体呈似层状,少量脉状,严格受北北西-北西向构造控制。矿床成因类型属浅源热液改造型铜矿床。     

Decarbonation reaction of magnesite in subducting slabs at the lower mantle

High-pressure and temperature experiments (28–62 GPa, and 1,490–2,000 K, corresponding to approximately 770–1,500 km depth in the mantle) have been conducted on a MgCO₃ + SiO₂ mixture using a laser-heated diamond anvil cell combined with analytical transmission electron microscope observation of the product phases to constrain the fate of carbonates carried on the subducting basalt into the lower mantle. At these conditions, the decarbonation reaction MgCO₃ (magnesite) + SiO₂ (stishovite) → MgSiO₃ (perovskite) + CO₂ (solid) has been recognized. This indicates that above reaction takes place as a candidate for decarbonation of the carbonated subducting mid ocean ridge basalts in the Earth’s lower mantle.     

Synchrotron IR study of hydrous ringwoodite (γ-Mg2SiO4) up to 30 GPa

High-pressure synchrotron infrared (IR) absorption spectra were collected between 650 and 4,000 cm⁻¹ at ambient temperature for hydrous Mg-ringwoodite (γ-Mg₂SiO₄) up to 30 GPa. The main feature in the OH⁻ stretching region is an extremely broad band centred at 3,150 cm⁻¹. The hydrogen bond is strong for most protons and the most probable site for protonation is the tetrahedral edge. With increasing pressure, this band shifts downward while decreasing its integrated intensity until disappearance at a pressure of 25 GPa. Only one band at 2,450 cm⁻¹ and an absorption plateau persist with a maximum wavenumber of 3,800 cm⁻¹. This behaviour is reversible upon pressure release. We interpret this as a second-order phase transition occurring in hydrated Mg-ringwoodite at high pressure (beyond ∼ 25 GPa). This result is compatible with the observation by Kleppe et al. (Phys Chem Miner 29:473–476, 2002a) who suggested the presence of Si–O–Si linkages and/or partial increase in the coordination of Si. Beyond the phase transition, the protons are delocalized and their environment on the ringwoodite structure is probably quite different from that at low pressure. Data obtained in situ at high pressures and temperatures are needed to better understand the effect of protonation on the structure and to better constrain this phase transition.