滇西潞西上芒岗卡林型金矿

上芒岗金矿赋存于二叠系沙子坡组碳酸岩和侏罗系勐戛组下段砂岩、灰岩中,明显受上芒岗断裂控制,与美国模式卡林型金矿极为相似,具有相同的物质来源和成因模式。上芒岗地区具有广阔的深部找矿前景。     

宁芜地区大平山铜矿、天台山黄铁矿与古火山机构关系的探讨

以大平山铜矿、天台山黄铁矿矿为例，阐述了该区的矿区、矿床地质及火山机构特征，并从成矿时间、空间及成因三个方面论述了矿床成矿与古火山机构的关系。     

Environmental geochemistry of Zarshuran Au-As deposit, NW Iran

Zarshuran deposit is the most famous and important As-Au mine in Iran. However, there is no information on the impact of mining activity on the surrounding environment, especially on water systems. This paper attempts to document the concentration of arsenic and associated elements in waters and sediments resulting from the mining history of Zarshuran, a period covering hundreds of years. Water and sediment samples collected from Zarshuran Stream indicate high content of some potentially toxic elements, especially of As which ranges from 0.028 to 40 ng/l in water and 182 to 36,000 mg/kg in sediment samples. Mining activity, exposure of a large volume of mining wastes to weathering, and the anomalously high background of trace metals in the mining area are considered to be the main sources of heavy metal pollution.     

Electrodialytic remediation of CCA-treated waste wood in pilot scale

When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m³ wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

东川铜矿硅质角砾40Ar-39Ar定年探讨

为探索热液成因含微量钾矿物＾４０Ａｒ－＾３９Ａｒ定年的最佳实验方案,从而获得可信的成矿年龄,本文进行了东川落雪铜矿稀矿山段落雪组角砾状矿石硅质角砾流体包裹体及其固体粉末的＾４０Ａｒ－＾３９Ａｒ对比实验;先采用真空击碎技术提取硅质角砾（ＣＤ－５－２）的流体包裹体进行＾４０Ａｒ－＾３９Ａｒ分析,接着对击碎后的固体粉末样品进行常规的＾４０Ａｒ－＾３９Ａｒ阶段加热分析（１７０～１８０℃）。与以往样品的流体     

Copper(II) humate mobility in kaolinite soil

An investigation of the influence of humate on the mobility of copper(II) ions in a kaolinite soil using leaching tests and electrokinetic experiments is reported. The data are interpreted in terms of humate–copper–clay interactions and humate electrical charge. Humate is mostly immobile below pH8 but is more mobile in alkaline conditions (sorption to kaolinite reduces its mobility in neutral conditions). Copper humate complexes are mobile in both acidic and alkaline conditions, but not in neutral conditions where they are sorbed. The dissolved copper humate complexes that form in acidic conditions are positively charged. The net effect of humate is to increase cupric ion mobility in kaolinite soil, especially in alkaline conditions.     

铅的成矿机理新探索

通过对铅及其氢化物的理化性质，铅矿床矿流体包裹体气液相成分、内生锡矿物的化学成分、铅矿物的共伴生矿物特征等相关问题的研究，认为铅氢化物，铅合金氢化物是铅成矿的主要迁移形式。在强还原、富氢、高压环境下，可随岩浆、热液、热气迁移至地壳浅部。在减压，贫氢，富硫的相对氧化环境；硫化成铅的硫化矿物及其硫盐矿物，或在氢逃逸氧化的贫硫环境；形成铅的单质及铅的合金矿物，并在长期地质事件中叠加，富集成铅矿床。     

个旧东区变基性火山岩型铜矿成因分析

有证据表明,个旧矿区矿产除与花岗岩密切相关外,基性火山或喷流沉积作用也较明显,变基性火山岩型铜矿的发现及研究增添不少理由。该型Cu矿层状、似层状,赋存于个旧组下段卡房段,矿层多,具同生沉积构造,从而对个旧矿区成矿理论增添新看法。     

龙湾套铜矿岩石学特征及矿床成因

泗水县龙湾套地区发育大面积新太古代角闪辉长岩,为在该区寻找赋存在角闪辉长岩中的岩浆熔离型铜矿床,曾开展过普查工作,最终发现了一小型铜矿床。探讨该区角闪辉长岩岩石学特征,对在该区进一步寻找同类型铜矿床有重要意义。