平凉隐伏岩溶水环境同位素研究

地下水资源可持续利用的一个急待解决的重要问题,是对地下水补给和更新能力的评价.利用环境同位素技术研究地下水的补给和可更新性是当前较为新颖的方法之一.在西北干旱、半干旱的隐伏岩溶地区,地下水埋藏条件复杂,常规的地质勘探方法所能提供的水文地质信息有限,环境同位素方法在研究地下水的补给及可更新能力方面发挥了优势,可对传统方法进行补充和验证.其结果表明,研究区隐伏岩溶水形成较早,且有大量现代水的混入,平均混入量为54%.说明区内隐伏岩溶水的补给和更新能力较好.环境同位素分析结果还显示,大岔河隐伏岩溶水为一相对独立、半开放的水文地质单元,其补给来源部分为流域内大气降水、地表水的补给,部分为东南部三道沟岩溶地下水的补给;根据环境同位素EPM模型计算,地下水的滞留时间为36 a.地下水储存量为1.314×108 m3; 储水系数为7.29×10-3.这一结果与传统勘探方法的计算结果基本吻合,说明环境同位素方法的实用性.     

新疆阿尔泰哈巴河一带古生代火山岩的形成与演化

文中详细地论述了新疆阿尔泰哈巴河一带古生代火山岩的地质、岩石化学、稀土元素地球化学特征。将其分为三个类型，认为火山岩是在陆缘裂陷槽的区域构造背景下发生和演化的。对各类型火山岩岩浆来源，上升模式也做了初步讨论。     

西南极纳尔逊岛Stansbury半岛火山岩地质特征初论

纳尔逊岛Stansbury半岛被玄武质、玄武安山质熔岩和火山碎屑岩以及沉积火山碎屑岩所覆盖。区域火山岩地层对比证明其是在形成长城站地区火山岩的同一火山作用下发育起来的。据地质接触关系和岩石组合特点,初步认为该半岛火山岩地层可以进一步划分为三个岩性段,分别形成于两期火山作用。该半岛的主要构造线方向平行于菲尔德斯海峡,这在地貌特征及次火山岩的分布上得到了证实。     

The stable isotope signature of kilometre-scale fracturedominated metamorphic fluid pathways, Mary Kathleen, Australia

Abstract Large calcite veins and pods in the Proterozoic Corella Formation of the Mount Isa Inlier provide evidence for kilometre-scale fluid transport during amphibolite facies metamorphism. These 10- to 100-m-scale podiform veins and their surrounding alteration zones have similar oxygen and carbon isotopic ratios throughout the 200 × 10-km Mary Kathleen Fold Belt, despite the isotopic heterogeneity of the surrounding wallrocks. The fluids that formed the pods and veins were not in isotopic equilibrium with the immediately adjacent rocks. The pods have δ¹³C_calcite values of –2 to –7% and δ¹⁸O_calcite values of 10.5 to 12.5%. Away from the pods, metadolerite wallrocks have δ¹⁸O_whole-rock values of 3.5 to 7%. and unaltered banded calc-silicate and marble wallrocks have δ¹³C_calcite of –1.6 to –0.6%, and δ¹⁸O_calcite of 18 to 21%. In the alteration zones adjacent to the pods, the δ¹⁸O values of both metadolerite and calc-silicate rocks approach those of the pods. Large calcite pods hosted entirely in calc-silicates show little difference in isotopic composition from pods hosted entirely in metadolerite. Thus, 100- to 500-m-scale isotopic exchange with the surrounding metadolerites and calc-silicates does not explain the observation that the δ¹⁸O values of the pods are intermediate between these two rock types. Pods hosted in felsic metavolcanics and metasiltstones are also isotopically indistinguishable from those hosted in the dominant metadolerites and calc-silicates. These data suggest the veins are the product of infiltration of isotopically homogeneous fluids that were not derived from within the Corella Formation at the presently exposed crustal level, although some of the spread in the data may be due to a relatively small contribution from devolatilization reactions in the calc-silicates, or thermal fluctuations attending deformation and metamorphism. The overall L-shaped trend of the data on plots of δ¹³C vs. δ¹⁸O is most consistent with mixing of large volumes of externally derived fluids with small volumes of locally derived fluid produced by devolatilization of calc-silicate rocks. Localization of the vein systems in dilatant sites around metadolerite/calc-silicate boundaries indicates a strong structural control on fluid flow, and the stable isotope data suggest fluid migration must have occurred at scales greater than at least 1 km. The ultimate source for the external fluid is uncertain, but is probably fluid released from crystallizing melts derived from the lower crust or upper mantle. Intrusion of magmas below the exposed crustal level would also explain the high geothermal gradient calculated for the regional metamorphism.     

Petrogenesis of Adakitic Intrusive Rocksin Xu-Huai Area, Eastern China

1IntroductionAdakite has specially sense in the resuming structure background of rock formed,because of its distinctive geochemistry feature and implying partic-ular petrogenesis and ore genesis mechanism (De-fant and Drummond,1990),as a result,it arouses numerous researchers widely concern. After adakite conception was drawn by Chinese (Wang etal.,2000), it was widely concerned by domestic re-searchers (Wang etal.,2000,2001a,2001b;Xu etal.,2000;Pan etal.,2001;Qian,2001;Xu etal.,2001;X…     

Structural Evolution of the Eastern Margin of Eurasia in Late Mesozoic and Cenozoic

This paper features the structural evolution of the eastern margin of Eurasia in Late Mesozoic and Cenozoic.It is characterized by three stages of development: the riftogenic stage (Jurassic-Early Cretaceous), the platform stage (Late Cretaceous) and the neotectonic one (Paleogene-Quarternary). The boundaries between these stages are distinctly fixed by the geological time limits of planetary range. It is demonstrated that the riftogenic and neotectonic stages were characterized by a high degree of geodynamic activity, and the platform one by a decrease in contrast of tectonic movements. The main river net was formed in the Early Cretaceous and in the Neogene. It experienced a serious reconstruction accompanied by the formation of the Amur River valley being similar to the modem one.     

The Cenozoic Volcanoes in Northeast China

There are more than 600 Cenozoic volcanic cones and craters with abeut 50 000 km2of lava flows in northeast China, which formed many volcanic clusters and shown the features of the continental rift - type volcanoes. Most volcanic activities in this area, especially in the east part of Songliao graben, were usually controlled by rifts and faults with the main direction of NE / NNE in parallel and become younger from the central graben towards its both sides, especially to the east continental margin. It is revealed that the volcanism occurred in northeast China was as strong as that occurred in Japan during the Miocene and the Quaternary. The Quaternary basalt that is usually distributed along river valley is called "valley basalt"while Neogene basalt usually distributed in the top of mounts is called "high position basalt". These volcanoes and volcanic rocks are usually composed of alkaline basalts with ultramafic inclusions, except Changbaishan volcano that is built by trachyte and pantellerite.     

宁远保安地区基性─超基性火山岩基本特征

本文论述了保安地区火山岩的地质、岩石、副矿物、岩石化学、微量元素、稀土元素、稳定同位素、火山岩相及火山机构等特征。并对其演化规律、形成机制与成矿作用的关系，作了初步探讨。     

滇西北保山核桃坪铅锌矿床成矿流体来源的同位素地球化学证据

滇西北核桃坪铅锌矿是保山地块内沿澜沧江断裂带发育的一个大型铅锌多金属矿床,矿体严格受近SN向的断裂带及层间破碎带控制,赋存于上寒武统核桃坪组和沙河厂组大理岩化灰岩及矽卡岩中。文章在分析矿床地质特征的基础上,通过对V1矿体的氢、氧、碳、硫、硅和铅同位素地球化学的示踪研究,探讨了成矿溶液中水、碳、硅、硫和铅的来源以及成矿流体的演化问题。研究表明,V1矿体中矿石的石英δ18O水值变化范围为6·1‰~7·6‰,平均为6·7‰,其δDV-SMOW值变化范围为-100‰~-108‰,平均为-104‰,说明成矿流体主要来自深部岩浆分异水,并在后期成矿作用过程中有地层建造水和大气降水的加入;矿石中方解石的δ13CV-PDB和δ18O水值分别为-6·6‰~-5·9‰和5·0‰~5·2‰,反映成矿流体的碳、氧具有深部流体与围岩发生交代反应的特征。硅、硫和铅同位素具深部岩浆或地幔来源的特点,但遭受后期壳源物质的混染。据此提出该矿床是与深部岩浆热液或幔源流体贯入有关的构造热液脉型矿床,其成矿作用受控于深部过程的驱动和控制,可为指导地质找矿提供依据。     

Origin and mechanisms of K–Si-metasomatism of ca. 3.4–3.3 Ga volcaniclastic deposits and implications for Archean seawater evolution: Examples from cherts of Kittys Gap (Pilbara craton, Australia) and Msauli (Barberton Greenstone Belt, South Africa)

The effects of K–Si-metasomatism during the formation of Early Archean replacement cherts have been quantified in this study by the investigation of two well-known stratigraphic sections: the Msauli chert (MC, Barberton greenstone belt, South Africa) and the Kittys Gap chert (KGC, Pilbara craton, Western Australia). The KGCs have a dacitic precursor similar to Duffer Formation dacites (Pilbara craton), while the MCs are derived from Al-depleted komatiites similar to those from the Weltevreden Formation (Barberton greenstone belt). Mass balance calculations reveal that the volcaniclastic deposits had initial porosities of up to 85 vol.% for the KGC and of 65 vol.% for the MC. Secondary porosities (27 vol.%: MC, 8 vol.%: KGC) produced during K-metasomatism are proportional to the dissolution of Fe, Ca, Mg-rich glass and precursor minerals. Komatiites have a higher chemical exchange potential than dacites, each gram releasing 1.2 mmol Fe²⁺, 2.8 mmol Mg²⁺, 1.4 mmol Ca²⁺ and 1.1 mmol Na⁺ to seawater, together with 4.4 mmol O²⁻. K-metasomatism of 1 g of komatiite further implies an uptake of 0.67 mmol of K⁺ and 2.7 mmol of H⁺. The highest silica uptake is achieved for the KGC (82 mmol/g of precursor). This silica enrichment most likely operated in the water column and at the sediment–water interface by sorption mechanisms on the surface of detrital particles and particulate organic matter, as a result of seawater silica-saturation. Acidic conditions (pH 5.5–6.5) and hot temperatures (>70 °C) favored the formation of K-rich phyllosilicates by interaction with seawater during the early diagenetic alteration of the volcaniclastic particles. The widespread occurrence of K–Si-metasomatism in volcanic and sedimentary rocks can be regarded as a general alteration process of the Early Archean seafloor, with a major influence on seawater composition. The highly K-selective metasomatism confirms previous studies suggesting that the Archean ocean was acidic and probably in equilibrium with a CO₂-rich atmosphere.