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1.
D. Gournis A. Lappas M. A. Karakassides D. Többens A. Moukarika 《Physics and Chemistry of Minerals》2008,35(1):49-58
Neutron powder diffraction measurements on lithium and cesium saturated montmorillonite samples before and after heat treatment
at 300°C are studied, in order to undertake a complete refinement of crystal structure and unravel the migration mechanism
for the interlayer cations of Li or Cs. Rietveld analysis of the corresponding diffraction patterns finds that montmorillonite
crystallizes in the C2/m space group with unit cell dimensions consistent with the size of the specific interlayer cation. We show that thermal treatment
affects the two types of samples in a different way. This is with respect to their unit cell dimensions and the migration
of Li from the 2b to the 2c clay lattice site, in constrast to the Cs positioning which remains effectively unchanged. 相似文献
2.
基于EOF分析对南海西北海域水体光谱特性的研究 总被引:1,自引:0,他引:1
This study presents an analysis of the spectral characteristics of remote sensing reflectance(R_(rs)) in northwestern South China Sea based on the in situ optical and water quality data for August 2018.R_(rs)was initially divided into four classes,classes A to D,using the max-classification algorithm,and the spectral properties of whole R_(rs) were characterized using the empirical orthogonal function(EOF) analysis.Subsequently,the dominant factors in each EOF mode were determined.The results indicated that more than 95% of the variances of R_(rs) are partly driven by the back-scattering characteristics of the suspended matter.The initial two EOF modes were well correlated with the total suspended matter and back-scattering coefficient.Furthermore,the first EOF modes of the four classes of R_(rs)(A-D R_(rs)-EOF_1) significantly contributed to the total variances of each R_(rs) class.In addition,the correlation coefficients between the amplitude factors of class A-D R_(rs)-EOF_1 and the variances of the relevant water quality and optical parameters were better than those of the unclassified ones.The spectral shape of class AR_(rs)-EOF_1 was governed by the absorption characteristic of chlorophyll a and colored dissolved organic matter(CDOM).The spectral shape of class B R_(rs)-EOF_1 was governed by the absorption characteristic of CDOM since it exhibited a high correlation with the absorption coefficient of CDOM(a_g(λ)),whereas the spectral shape of class C R_(rs)-EOF_1 was governed by the back-scattering characteristics but not affected by the suspended matter.The spectral shape of class D R_(rs)-EOF_1 exhibited a relatively good correlation with all the water quality parameters,which played a significant role in deciding its spectral shape. 相似文献
3.
4.
赤潮生物种类特征光谱获取技术 总被引:1,自引:0,他引:1
较为系统地研究了赤潮生物水体反射率曲线获取方法。通过对 2类反射率反演方法得出的反射率曲线与实际反射率曲线进行比较 ,得出在不具备大气环境参数的情况下 ,经验线性法的反演结果与实际反射率曲线最接近的结论 ,并进一步对正常海水和赤潮生物水体的光谱特性进行分析 ,提取出赤潮生物水体的特征光谱。这是进行赤潮监测和识别的重要前提 相似文献
5.
6.
Deep sea drilling in the Central Gulf of California, a young and active spreading centre, shows that the high heat flow typical of these regions causes extensive alteration of sediment organic matter, especially near sills and above magma chambers where hydrothermal activity is concentrated. Even on the nearby passive margin, where there are no sills, heat flow is moderately high and hydrocarbon generation has begun in immature sequences. Migrating light hydrocarbons are detected especially where hydrothermal activity is concentrated. Thermogenic methane is more widespread, though not in the passive margin bordering the spreading centre. Despite the incidence of hydrocarbon generation and migration, the amounts of hydrocarbons involved are relatively small and apparently do not lead to commercially significant accumulations of petroleum.The organic matter in these sediments is mostly marine because the Gulf of California generally has low runoff from land and highly productive surface waters. Turbidites rich in terrigenous organic material are locally abundant in the mainly pelagic section in the Guaymas Basin. The highest concentrations of organic matter are found in laminated diatomites deposited on the Guaymas passive margin within the oxygen minimum zone. 相似文献
7.
Joo Serdio Helena Coelho Snia Vieira Snia Cruz 《Estuarine, Coastal and Shelf Science》2006,68(3-4):547
The migratory response of intertidal microphytobenthos to changes in irradiance was studied on undisturbed estuarine sediments. Two non-destructive optical techniques were used to trace variations in vivo of surface biomass: PAM fluorometry, for measuring the minimum fluorescence level (Fo); and spectral reflectance analysis, for quantifying the normalized difference vegetation index (NDVI). Following the formation of a dense biofilm at the surface, replicated sediment samples were simultaneously exposed to six different irradiance levels, ranging from 50 to 1500 μmol m−2 s−1, during a period of 120 min. The migratory photoresponse of the biofilms was characterised by constructing biomass vs. light curves (BLC), relating the accumulation of microalgal biomass after that period (estimated by Fo or NDVI) to the irradiance level incident on the surface. BLCs allow characterising the main features of the migratory photoresponse of intact biofilms. Typical BLC showed a clear biphasic pattern, with an increase in microalgal accumulation under irradiances below 100 μmol m−2 s−1, maximum values under 100–250 μmol m−2 s−1, and a gradual decrease of surface biomass under higher irradiances, indicating a strong photophobic downward migratory response. Similar BLC patterns were obtained when measuring Fo or NDVI. The construction of BLCs for biofilms from intertidal sites with distinctive sediment characteristics and diatom taxonomic composition allowed to detected significant differences in the migratory photoresponse. Biofilms from a muddy sediment exhibited considerably larger amplitude in the migratory photoresponse than the biofilms from a sandy mud site, especially under high irradiances. The photophobic migratory response to high light was found to vary among diatom species, particularly in the case of the biofilms from the muddy sediments. 相似文献
8.
海中悬移质是决定海洋光学性质、海洋水质,河口海岸带演变动力过程的重要环境参数。本文利用模拟遥感反射比数据集建立人工神经网络反演悬移质浓度,并利用东中国海现场同步数据对该算法进行验证。 相似文献
9.
Combined subsidence and thermal 1D modelling was performed on six well-sections located in the north-western Mid-Polish Trough/Swell
in the eastern part of the Central European Basin system. The modelling allowed constraining quantitatively both the Mesozoic
subsidence and the magnitude of the Late Cretaceous–Paleocene inversion and erosion. The latter most probably reached 2,400 m
in the Mid-Polish Swell area. The modelled Upper Cretaceous thickness did not exceed 500 m, and probably corresponded to 200–300 m
in the swell area as compared with more than 2,000 m in the adjacent non-inverted part of the basin. Such Upper Cretaceous
thickness pattern implies early onset of inversion processes, probably in the Late Turonian or Coniacian. Our modelling, coupled
with previous results of stratigraphic and seismic studies, demonstrates that the relatively low sedimentation rates in the
inverted part of the basin during the Late Cretaceous were the net result of several discrete pulses of non-deposition and/or
erosion that were progressively more pronounced towards the trough axis. The last phase of inversion started in the Late Maastrichtian
and was responsible for the total amount of erosion, which removed also the reduced Upper Cretaceous deposits. According to
our modelling results, a Late Cretaceous heat-flow regime which is similar to the present-day conditions (about 50 mW/m2) was responsible for the observed organic maturity of the Permian-Mesozoic rocks. This conclusion does not affect the possibility
of Late Carboniferous–Permian and Late Permian–Early Triassic thermal events. 相似文献
10.
David J. A. Williams Beda A. Hofmann Ian G. Glasspool 《Swiss Journal of Geoscience》2008,101(3):651-658
Vitrinite reflectance (Rr), proximate analysis and carbon isotope composition (δ13C) have been used to characterise coal samples from two zones of Late Carboniferous sediments (Gastern and Ferden) in the Aar massif where they are penetrated by the Lötschberg base tunnel (constructed between 1999 and 2005). Samples are characterised by variable ash yields (21.7–93.9%; dry basis); those with ash yields of less than ~50% and with volatile matter content (V;dry ash-free basis) within the limits 2 < V% ≤ 8 are anthracite. Values of Rr range from 3.89% to 5.17% and indicate coalification to the rank of anthracite and meta-anthracite in both Gastern and Ferden Carboniferous zones. Samples of anthracite and shale from the Gastern Carboniferous exhibit a relatively small range in δ13C values (–24.52‰ to –23.38‰; mean: –23.86‰) and are lighter than anthracite samples from the Ferden Carboniferous (mean: –22.20‰). The degree of coalification in the Gastern and Ferden Carboniferous zones primarily depends on the maximum rock temperature (T) attained as a result of burial heating. Vitrinite reflectance based estimates of T range from ~290° –360 °C. For a proposed palaeogeothemal gradient of 25 ° C/km at the time of maximum coalification the required overburden is attributable to relatively thin autochtonous Mesozoic/Cenozoic sedimentary cover of the Aar massif and Gastern granite and deep tectonic burial beneath advancing Helvetic, Ultrahelvetic and Prealpine (Penninic) nappes in Early Oligocene to Miocene. 相似文献