Graptolite biostratigraphy of the Lower Silurian (Llandovery and Wenlock) of Bohemia

Nearly 50 sections through the Llandovery and Wenlock black shales of the Barrandian area (Bohemia) have been examined bed by bed. This has made possible the compilation of an improved and well defined graptolite zonal scheme with much new biostratigraphic data included. A total of 268 graptolite species and subspecies have been found. Their stratigraphic distribution allows the recognition of 27 graptolite zones: ascensus–acuminatus, vesiculosus, cyphus, triangulatus–pectinatus, simulans, convolutus, sedgwickii, linnaei, turriculatus, crispus, griestoniensis, tullbergi, spiralis, grandis, insectus, centrifugus, murchisoni, riccartonensis, dubius, belophorus, rigidus, ramosus–perneri, lundgreni, parvus, nassa–frequens, praedeubeli–deubeli, ludensis, and several subzones. The biozones are defined by the vertical ranges of their ‘index’ species and are characterized by rich accompanying associations. The zonal scheme is correlated with graptolite sequences elsewhere.     

Evolution of geochemistry and depositional settings of Early Palaeozoic siliciclastics of the Barrandian (Teplá-Barrandian Unit,Bohemian Massif,Czech Republic)

Cambrian and Ordovician-Middle Devonian sequences of two successive Early Palaeozoic basins of the Barrandian unconformably overlie Cadomian basement in the Bohemian Massif NW interior (Teplá-Barrandian unit) which is the easternmost peri-Gondwanan remnant within the Variscides. Correlation of stratigraphy and geochemistry of the Early Palaeozoic siliciclastic rocks elucidated sediment provenances. Sandstones of the Middle Cambrian Píbram-Jince Basin were derived from a Cadomian Neoproterozoic island arc. The source area of the Ordovician shallow-marine siliciclastics of the successor Prague Basin is a dissected Cadomian orogen. Late Cambrian acid volcanics of the Barrandian and Cambrian (meta)granitoids emplaced in the W part of the Teplá-Barrandian Cadomian basement are also discernible in these sediments. Old sedimentary component increased during the Ordovician. Early Llandovery siliciclastic rocks show characteristics of an abruptly weakened supply of terrigenous material and an elevated proportion of synsedimentary basic volcanics as a result of Silurian transgression. Emsian siliciclastics (intercalated in the Late Silurian to Early Devonian limestone suite) presumably comprise an addition of coeval basic/ultrabasic volcaniclastics. Middle Devonian flysch-like siliciclastics indicate reappearance of Cadomian source near the Barrandian during early Variscan convergences of Armorican microplates that preceeded accretion of the Teplá-Barrandian unit within the Bohemian Massif terrane mosaic.Dr. Patoka deceased in July 2004.     

Facies development,depositional settings and sequence stratigraphy across the Ordovician–Silurian boundary: a new perspective from the Barrandian area of the Czech Republic

The Hirnantian and Llandovery sedimentary succession of the Barrandian area has been assigned to middle and outer clastic‐shelf depositional settings, respectively. Deposition was influenced by the remote Gondwanan glaciation and subsequent, long‐persisting, post‐glacial anoxia triggered by a current‐driven upwelling system. High‐resolution graptolite stratigraphy, based upon 19 formally defined biozones—largely interval zones—and five subzones, enabled a detailed correlation between 42 surface sections and boreholes, and enabled linking of the sedimentary record, graptoloid fauna dynamics, organic‐content fluctuations and spectral gamma‐ray curves. The Hirnantian and Llandovery succession has been subdivided into four biostratigraphically dated third‐order sequences (units 1–4). Time–spatial facies distribution recorded early and late Hirnantian glacio‐eustatic sea‐level lowstands separated by a remarkable mid‐Hirnantian rise in sea‐level. A major part of the post‐glacial sea‐level rise took place within the late Hirnantian. The highstand of Unit 2 is apparently at the base of the Silurian succession. Short‐term relative sea‐level drawdown and a third‐order sequence boundary followed in the early Rhuddanian upper acuminatus Zone. Early Aeronian and late Telychian sea‐level highstands and late Aeronian drawdown of likely eustatic origin belong to units 3 and 4. Sea‐level rise culminated in the late Telychian, which may also be considered as a highstand episode of a second‐order Hirnantian–early Silurian cycle. Facies and sequence‐stratigraphic analysis supports recent interpretations on nappe structures in the core part of the Ordovician–Middle Devonian Prague Synform of the Barrandian. Copyright © 2006 John Wiley & Sons, Ltd.     

Epigenetic dolomitization of the Přaídolí formation (Upper Silurian), the Barrandian basin,Czech Republic: implications for burial history of Lower Paleozoic strata

Stratabound epigenetic dolomite occurs in carbonate facies of the Barrandian basin (Silurian and Devonian), Czech Republic. The most intense dolomitization is developed in bioclastic calcarenites within the transition between micritic limestone and shaledominated Přídolí and Lochkov formations deposited on a carbonate slope. Medium-crystalline (100–400 μm), inclusion-rich, xenotopic matrix dolomite (δ ¹⁸O=−4.64 to −3.40‰ PDB;δ ¹³C=+1.05 to +1.85‰ PDB) which selectively replaced most of the bioclastic precursor is volumetrically the most important dolomite type. Coarse crystalline saddle dolomite (δ ¹⁸O=−8.04 to −5.14‰ PDB;δ ¹⁸C=+0.49 to +1.49 PDB) which precipitated in fractures and vugs within the matrix dolomite represents a later diagenetic dolomitization event. In some vugs, saddle dolomite coprecipitated with petroleum inclusion-rich authigenic quartz crystals and minor sulfides which, in turn, were post-dated by semisolid asphaltic bitumen. The interpretation of the dolomitization remains equivocal. Massive xenotopic dolomite, although generally characteristic of a deeper burial setting, may have been formed by a recrystallization of an earlier, possibly shallow burial dolomite. Deeper burial recrystallization by reactive basinal pore fluids that presumably migrated through the more permeable upper portion of the Přídolí sequence appears as a viable explanation for this dolomitization overprint. Saddle dolomite cement of the matrix dolomite is interpreted as the last dolomitization event that occurred during deep burial at the depth of the oil window zone. The presence of saddle dolomite, the fluid inclusion composition of associated quartz crystals, and vitrinite paleogeothermometry of adjacent sediments imply diagenetic burial temperatures as high as 160°C. Although high geothermal gradients in the past or the involvement of hydrothermally influenced basinal fluids can account for these elevated temperatures, burial heating beneath approximately 3-km-thick sedimentary overburden of presumably post-Givetian strata, no longer preserved in the basin, appears to be the most likely interpretation. This interpretaion may imply that the magnitude of post-Variscan erosion in the Barrandian area was substantially greater than previously thought.     

Emplacement depths and radiometric ages of Paleozoic plutons of the Neukirchen–Kdyn massif: differential uplift and exhumation of Cadomian basement due to Carboniferous orogenic collapse (Bohemian Massif)

The igneous complex of Neukirchen–Kdyn is located in the southwestern part of the Teplá–Barrandian unit (TBU) in the Bohemian Massif. The TBU forms the most extensive surface exposure of Cadomian basement in central Europe. Cambrian plutons show significant changes in composition, emplacement depth, isotopic cooling ages, and tectonometamorphic overprint from NE to SW. In the NE, the V epadly granodiorite and the Smr ovice diorite intruded at shallow crustal levels (<ca. 7 km depth) as was indicated by geobarometric data. K–Ar age data yield 547±7 and 549±7 for hornblende and 495±6 Ma for biotite of the Smr ovice diorite, suggesting that this pluton has remained at shallow crustal levels (T<ca. 350 °C) since its Cambrian emplacement. A similar history is indicated for the V epadly granodiorite and the Stod granite. In the SW, intermediate to mafic plutons of the Neukirchen–Kdyn massif (V eruby and Neukirchen gabbro, Hoher–Bogen metagabbro), which yield Cambrian ages, either intruded or were metamorphosed at considerably deeper structural levels (>20 km). The Teufelsberg ( ert v kámen) diorite, on the other hand, forms an unusual intrusion dated at 359±2 Ma (concordant U–Pb zircon age). K–Ar dating of biotite of the Teufelsberg diorite yields 342±4 Ma. These ages, together with published cooling ages of hornblende and mica in adjacent plutons, are compatible with widespread medium to high-grade metamorphism and strong deformation fabrics, suggesting a strong Variscan impact under elevated temperatures at deeper structural levels. The plutons of the Neukirchen area are cut by the steeply NE dipping Hoher–Bogen shear zone (HBSZ), which forms the boundary with the adjacent Moldanubian unit. The HBSZ is characterized by top-to-the-NE normal movements, which were particularly active during the Lower Carboniferous. A geodynamic model is presented that explains the lateral gradients in Cambrian pluton composition and emplacement depth by differential uplift and exhumation, the latter being probably related to long-lasting movements along the HBSZ as a consequence of Lower Carboniferous orogenic collapse.     

Subdivision of the Lochkovian Stage based on conodont faunas from the stratotype area (Prague Synform,Czech Republic)

Relatively rich conodont faunas from sections in the Prague Synform (Barrandian area, Czech Republic) include a number of indexes and other important guide conodonts that can be correlated with other regions, especially with Nevada and the Spanish Central Pyrenees. The collation and detailed correlation of conodont data from the Lochkovian in two parallel sections in the Požáry quarries, together with biostratigraphic control of additional data from several (incomplete) sections with changing facies development, is the basis for a new detailed regional biozonal scale for the Lochkovian in the Prague Synform. The new subdivision follows, with modification, the global threefold conodont subdivision of the Lochkovian. Data from the Prague Synform enable further detailed subdivision of the lower, middle and upper Lochkovian into small‐scale units. The conodont distribution shows a large proportional discrepancy between the late Lochkovian elsewhere; the conodont record in the latest Lochkovian in the Prague Synform area, which appears to be rather restricted and requires further discussion. Copyright © 2012 John Wiley & Sons, Ltd.     

How far did the Cadomian ʽterranesʼ travel from Gondwana during early Palaeozoic? A critical reappraisal based on detrital zircon geochronology

In this paper, laser ablation ICP-MS U–Pb detrital zircon ages are used to discuss provenance and early Palaeozoic palaeogeography of continental fragments that originated in the Cadomian–Avalonian active margin of Gondwana at the end of Precambrian, were subsequently extended during late Cambrian to Early Ordovician opening of the Rheic Ocean, and finally were incorporated into and reworked within the European Variscan belt. The U–Pb detrital zircon age spectra in the analysed samples, taken across a late Neproterozoic (Ediacaran) to Early/Middle Devonian metasedimentary succession of the southeastern Teplá–Barrandian unit, Bohemian Massif, are almost identical and exhibit a bimodal age distribution with significant peaks at about 2.1–1.9 Ga and 650–550 Ma. We interpret the source area as an active margin comprising a cratonic (Eburnean) hinterland rimmed by Cadomian volcanic arcs and we suggest that this source was available at all times during deposition. The new detrital zircon ages also corroborate the West African provenance of the Teplá–Barrandian and correlative Saxothuringian and Moldanubian units, questioned in some palaeogeographic reconstructions. Finally, at variance with the still popular concept of the Cadomian basement units as far-travelled terranes, we propose that early Palaeozoic basins, developed upon the Cadomian active margin, were always part of a wide Gondwana shelf and drifted northwards together before involvement in the Variscan collisional belt.     

Early Pragian conodont‐based correlations between the Barrandian area and the Spanish Central Pyrenees

Occurrences and distribution of extremely scarce eognathodontids do not facilitate reliable correlation across the European regions. The correlation of the traditional early Pragian of the Prague Synform (a part of the classical Barrandian area) and the Spanish Central Pyrenees (section Segre 1) is based on conodont taxa of the Icriodus steinachensis and the Pelekysgnathus serratus stocks. This correlation has the potential to be extended to other peri‐Gondwanan regions where this scarcity of eognathodontid faunas exists as well. Application of the morphotype subdivision in I. steinachensis enables approximation of the beginning of the Pragian in the Pyrenees. It is based on the entry of I. steinachensis beta morphotype; it enters together with early eognathodontid taxa in the Barrandian sections. These correlations show that routine application of certain zonal concepts can lead to misleading conclusions. Copyright © 2007 John Wiley & Sons, Ltd.     

Conditions for veining in the Barrandian Basin (Lower Palaeozoic), Czech Republic: evidence from fluid inclusion and apatite fission track analysis

The interplay between fracture propagation and fluid composition and circulation has been examined by deciphering vein sequences in Silurian and Devonian limestones and shales at Kosov quarry in the Barrandian Basin. Three successive vein generations were recognised that can be attributed to different stages of a basinal cycle. Almost all generations of fracture cements host abundant liquid hydrocarbon inclusions that indicate repeated episodes of petroleum migration through the strata during burial, tectonic compression and uplift.The earliest veins that propagated prior to folding were displacive fibrous “beef” calcite veins occurring parallel to the bedding of some shale beds. Hydrocarbon inclusions within calcite possess homogenisation temperatures between 58 and 68 °C and show that the “beef” calcites originated in the deeper burial environment, during early petroleum migration from overpressured shales.E–W-striking extension veins that postdate “beef” calcite formed in response to Variscan orogenic deformations. Based on apatite fission track analysis (AFTA) data and other geological evidence, the veins probably formed 380–315 Ma ago, roughly coinciding with peak burial heating of the strata, folding and the intrusion of Variscan synorogenic granites. The veins that crosscut diagenetic cements and low-amplitude stylolites in host limestones are oriented semi-vertically to the bedding plane and are filled with cloudy, twinned calcite, idiomorphic smoky quartz and residues of hardened bitumen. Calcite and quartz cements contain abundant blue and blue–green-fluorescing primary inclusions of liquid hydrocarbons that homogenise between 50 and 110 °C. Geochemical characteristics of the fluids as revealed by gas chromatography–mass spectrometry, particularly the presence of olefins and parent aromatic hydrocarbons (phenonthrene), suggest that the oil entrapped in the inclusions experienced intense but geologically fast heating that resulted in thermal pyrolysis of its hydrocarbons. This implies that the organic fluids in the fractures may have been partly influenced by heating associated with igneous intrusions that are hidden below the surface.Subvertical N–S-striking veins represent the most recent fracturing event(s). Some of these veins are only a few millimeters thick and sparsely mineralised with thin leaf-like quartz crystals that contain tiny blue and yellow–orange-fluorescing hydrocarbon inclusions. Most of the N–S veins, however, occur as thick calcite veins that generally crystallised at 70 °C or less from H₂O–NaCl solutions of variable salinity with admixture of petroleum. The origin of these fluids is interpreted in terms of deeply circulating meteoric waters that partially mixed with deep basinal fluids. Wider structural considerations combined with fission-track analysis of adjacent host sediments suggest that N–S veins formed during post-Mesozoic uplift of the area, probably in response to major Tertiary Alpine deformations transmitted far into the Bohemian Massif.