Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

基于噪声谱比法的内蒙古西部地区台站场地响应研究

利用内蒙古西部12个台站的地脉动噪声数据，采用噪声谱比法研究台站的场地响应情况。分析表明，台站场地响应按曲线形态可分为3类，且可能受地形地貌、局部构造和台基状况等条件影响。对比分析噪声谱比法与Moya方法的场地响应结果发现，场地响应曲线形态基本一致，只有极少数台站存在明显差异。结果表明，内蒙古西部区域大部分台站的台基状况总体较好，场地响应曲线较为平坦，无明显频率放大点。     

Chemical alteration of tephra in the depositional environment: theoretical stability modelling

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.     

The Roche Limit

The role of tides in deforming and possibly disrupting a secondary body orbiting about a primary body has been known for a considerable time. This was first inspired by the observations of ocean tides on Earth and then seen as playing an important role in the formation and evolution of the Earth–Moon system. Finally, in the beginning of the 20th century it was generally thought to have a significant role in the formation of the solar system through the tidal disruption of the Sun. Here, an overview of the historical developments of the ideas concerned with tidal disruption of a secondary body that can lead to mass loss is given. Some discussion of possible extensions to consider more realistic situations where the secondary body may not be moving on a circular orbit and may not rotate so as to maintain the phase-on configuration to the primary body is also given.     

板翅式换热器综合性能优化的设计方法

应用给定换热器结构材料而使换热量最大的两侧换热表面的最佳匹配准则和使可用能损失率最小的最佳运行参数准则。利用两个准则间的关系 ,采用迭代的方式完成换热器的优化设计 ,使换热器的设计达到材料省、换热效果好及运行费用低的目的 ,且能在设计阶段实现。     

柴达木盆地东北缘古元古代变质镁铁—超镁铁质岩的地质特征及成因探讨

1:5万区域地质调查工作中,在柴达木陆块北缘首次发现古元古代变质镁铁—超镁铁质岩,获得成岩年龄为1952±15Ma,其岩石化学、地球化学特征反映出岩浆来源于亏损地幔,反映出该地区克拉通在古元古代(19亿年)发生了一次强烈的裂解(洋)事件,对于研究柴达木盆地北缘元古代结晶基底地质构造演化及进一步探讨柴达木盆地的起源及构造演化过程提供了重要地质线索。     

Wolf-Rayet stars

Summary Recent literature on Population I Wolf-Rayet star research extending from the Milky Way to blue compact dwarf galaxies is reviewed, broken down into inventory, basic parameters and galactic distribution, atmospheres, binaries, intrinsic variability, mass loss, enrichment and evolution. Also the incidence of Wolf-Rayet stars with variable non-thermal radio emission, excess X-ray fluxes, and episodic/periodic IR excesses is reviewed. These phenomena appear to be associated with wind-wind interaction in wide long-period WR+OB binaries and with wind-compact object interaction in WR+c binaries, with orbit sizes of the order of magnitude of the WR radio photosphere sizes or larger.     

Observations of hydrogen deficient binary Upsilon sagittarii

The absolute magnitudeM _v of the hydrogen deficient binary υ Sgr has been estimated as -4.8 ± 1.0 from the distribution of the interstellar reddening, polarization and interstellar lines of the surrounding stars. From the ANS observations obtained at the time of the secondary eclipse, it appears that the hotter secondary is surrounded by a disc with colours of a B8-B9 star. The λ 1550 CIv absorption line arising in the stellar wind does not show any change in strength during the secondary minimum. The upper limit to the mass-loss rate from the high temperature wind is estimated as ≤ 5 × 10^-7 M⊙ yr^-1 from the 2 cm and 6 cm radio observations. Based on observations obtained with the Astronomical Netherlands Satellite and VLA. The National Radio Astronomy Observatory’s Very Large Array at Socorro, New Mexico is operated by Associated Universities Inc. under contract with the National Science Foundation.     

塔中4号油藏渗透率分布的非均质性及渗流方向研究

研究油藏内部油水渗流方向时,主要考虑渗透率影响,引入两个水平方向渗透率比、水平与垂向渗透率比参数来分析。前者反映样品所在储层平面上两个水平方向渗流能力的差异,后者反映样品所在储层水平与垂向渗流能力的差异,并经小柱样测试和全岩心测试两种方法确定两个参数。通过对塔中4号油藏CⅠ油组9口井2306个样品两种渗透率比值分布直方图分析,研究了CⅠ油组渗透率的非均质性及其渗流方向:CI油组储层在水平方向的渗流能力有很大差异,具有明显的方向性。储层垂向渗流能力明显小于水平方向的渗流能力。     

Some integrable cases of the two-body problem with mass depending both on time and distance

an extension of the Gylden-Meshcherskii problem when the mass depends both on time and distance between two bodies is considered. certain mass loss laws as well as the Meshcherskii position vector and time transformation are used to convert the problem into the cases with equations of motion arising from integrable potentials.