SO4^2-改性铁铝复合层柱粘土的制备及其催化性能研究

由共聚法制得的铁铝复合交联剂交换钠基蒙脱石层间的水合钠离子,再经SO42-改性处理制备了铁铝复合层柱粘土固体超强酸催化剂.利用xRD、FT-IR和BET法对催化剂的结构进行了表征.以乙酸正丁酯的合成反应为探针反应对催化剂的活性进行了测试.通过正交实验确定了铁铝复合交联粘土SO42-改性最佳工艺条件.研究了催化剂对探针反应的选择性及重复使用情况.结果表明:在由实验确定的最佳改性工艺条件下,乙酸的转化率达92.2%,反应中无副产物产生,催化剂具有较好的重复使用性能.     

Experimental Seasonal Forecast of Monsoon 2005 Using T170L42 AGCM on PARAM Padma

As a part of the Experimental Extended Range Monsoon Prediction Experiment, ensemble mode seasonal runs for the monsoon season of 2005 were made using the National Centre for Environmental Prediction (NCEP), T170L42 AGCM. The seasonal runs were made using six initial atmospheric conditions based on the NCEP operational analysis and with forecast monthly sea-surface temperature (SST) of the NCEP Coupled forecast system (CFS). These simulations were carried out on the PARAM Padma supercomputer of Centre for Development of Advanced Computing (C-DAC), India. The model climatology was prepared by integrating the model for ten years using climatological SST as the lower boundary. The climatology of the model compares well with the observed, in terms of the spatial distribution of rainfall over the Indian land mass. The model-simulated rainfall compares well with the Tropical Rainfall Measuring Mission (TRMM) estimates for the 2005 monsoon season. Compared to the model climatology (7.81 mm/day), the model had simulated a normal rainfall (7.75 mm/day) for the year 2005 which is in agreement with the observations (99% of long-term mean). However, the model could not capture the observed increase in September rainfall from that of a low value in August 2005. The circulation patterns simulated by the model are also comparable to the observed patterns. The ensemble mean onset is found to be nearer to the observed onset date within one pentad.     

以T42产品为因子用卡尔曼滤波方法作温度预报

本文以Ｔ４２数据预报产品为因子，用卡尔曼滤波方法建立可更新系数的预报方程作南京和芜湖的温度预报。从１９９４年１月至４月共８４次试报中，用完全相同的因子卡尔曼滤波方法比回归分析方法预报结果精度提高０．５度。     

中国区域逐日融合降水数据集与国际降水产品的对比评估

中国国家气象信息中心基于2400多个国家级台站观测日降水量和CMORPH卫星反演降水产品,采用概率密度匹配和最优插值相结合的两步数据融合方法,研制了中国区域1998年以来的0.25°×0.25°分辨率的逐日融合降水产品(CMPA_Daily)。通过该数据集与广泛应用于中国天气气候领域的两种国际上降水融合产品TRMM 3B42(Tropical Rainfall Measuring Mission, 3B42)和GPCP(Global Precipitation Climatology Project, 1 degree daily)的对比评估,考察CMPA_Daily产品的质量,评价其能否合理体现中国降水的天气气候特征。首先利用2008—2010年5—9月独立检验数据定量对比了CMPA_Daily、TRMM 3B42和GPCP 三种降水产品的误差,结果表明,在误差的时间变化和空间分布上,CMPA_Daily均具有最高的相关系数和最小的平均偏差及均方根误差,TRMM 3B42其次,GPCP的误差相对较大。CMPA_Daily只低估了大暴雨,TRMM 3B42低估了大雨以上量级的降水,而GPCP低估了除小雨以外的所有降水。CMPA_Daily产品因融入了更多的站点观测信息,不论在中国东部沿海,还是中西部地形复杂区,其精度均优于TRMM 3B42和GPCP产品,即使在站点稀疏的青藏高原地区,CMPA_Daily降水量也更加接近站点观测,呈现明显的高相关。CMPA_Daily与独立检验数据的高相关在地形起伏时效果也较稳定,TRMM和GPCP的相关系数则随着地形变化幅度陡变而非常明显地降低。进一步通过对比分析各降水产品1998—2012年的气候平均降水特征表明,3种资料对中国区域气候平均降水量、降水强度、频率分布以及年际变化的总体描述基本一致,因有效融入了更多的中国站点观测信息,不论降水空间分布还是降水量,CMPA_Daily与地面观测均最为接近,在中国的中东部大部分地区对降水的估计精度明显更高,而在站点分布较稀疏的青藏高原地区,CMPA_Daily的降水分布型与TRMM、GPCP卫星融合资料类似,较地面站点插值产品更能体现出合理的降水分布。对中国强降水事件监测对比表明,CMPA_Daily产品可以更加准确地描述降水的强度变化,细致刻画降水空间分布,在把握降水小尺度特征上具有明显的优势,体现出高分辨率、高精度降水产品的特点。     

An Updated Coupled Model for Land-Atmosphere Interaction. Part Ⅰ: Simulations of Physical Processes

A new two-way land-atmosphere interaction model (R42_AVIM) is fulfilled by coupling the spectral at- mospheric model (SAMIL_R42L9) developed at the State Key Laboratory of Numerical Modeling for Atmo- spheric Sciences and Geophysical Fluid Dynamics, Institute of Atmospheric Physics, Chinese Academy of Sci- ences (LASG/IAP/CAS) with the land surface model, Atmosphere-Vegetation-Interaction-Model (AVIM). In this coupled model, physical and biological components of AVIM are both included. Climate base state and land surface physical fluxes simulated by R42_AVIM are analyzed and compared with the results of R42_SSIB [which is coupled by SAMIL_R42L9 and Simplified Simple Biosphere (SSIB) models]. The results show the performance of the new model is closer to the observations. It can basically guarantee that the land surface energy budget is balanced, and can simulate June-July-August (JJA) and December-January- February (DJF) land surface air temperature, sensible heat flux, latent heat flux, precipitation, sea level pressure and other variables reasonably well. Compared with R42_SSIB, there are obvious improvements in the JJA simulations of surface air temperature and surface fluxes. Thus, this land-atmosphere coupled model will offer a good experiment platform for land-atmosphere interaction research.     

A wavelet method for detecting S‐waves in seismic data

Seismic signals consist of several typically short energy bursts, called phases, exhibiting several patterns in terms of dominant frequency, amplitude and polarisation. We present a fast algorithm to detect the so‐called S‐phase in a three‐component seismic signal. This new approach combines traditional S‐phase detection methods and the discrete wavelet transform. This revised version was published online in July 2006 with corrections to the Cover Date.     

TRMM卫星降水反演数据在珠江流域的适用性研究——以东江和北江为例

为评估最新一代TRMM 3B42-V7卫星降水反演数据产品在珠江流域的精度和适用性,选取位于珠江流域下游的东江和北江流域为研究区域,基于地面雨量站点数据评估了该产品的精度和适用性,并结合可变下渗容量（Variable Infiltration Capacity,VIC）水文模型进行了水文模拟验证。对比分析结果表明,在网格尺度上,大多数网格日尺度相关系数达到0.60以上,月尺度相关系数达到0.90以上,3B42-V7产品表现出较好的精度,在区域尺度上精度得到了进一步提高;水文模拟验证分两种情景下进行,情景Ⅰ的结果表明,当水文模型由地面雨量站点数据率定时,3B42-V7产品数据的水文模拟效果不佳,个别区间内存在对洪峰流量明显的低估;情景Ⅱ的结果表明,由3B42-V7产品数据重新率定水文模型时径流模拟效果有了较大改善,说明该产品可在一定程度上作为资料缺乏地区的降水数据来源。     

Anthropogenic Sulfate and Nitrate Signals in Snow from Bogda Glacier, Eastern Tianshan

A 1.2 m snow pit was recovered on July 29th, 2009 from the Bogda Glacier, eastern Tianshan (天山). The sample site temperature of -9.6 ℃ indicates that the unique glaciochemical re-cord was well preserved and suitable for the reconstruction of air pollution levels in this previously un-explored region. Samples were analyzed for major ions (Na+, K+, Ca2+, Mg2+, NH4+, Cl-, SO42-, NO3-, HCOO-, and CH3COO-). NO3- and SO42- were characterized by significant high levels of pollution con-centration. Most air masses ...     

中国东北44 Ma/42 Ma火山事件的出现及其地质找矿意义

中国东北地区古近纪玄武岩浆喷发火山事件从48 Ma~32 Ma,每1 Ma内至少有一处或数处,以K-Ar测年数据记录了其活动的存在.唯44 Ma/42 Ma间,火山事件间隔时间超过1 Ma,即全区该时段近60个测年数据,未发现有43 Ma±的测年记录.此时,正是太平洋板块由NNW向运动转向NW-NWW向运动,也是太平洋天皇海岭-夏威夷海山火山链活动从NNW向转向NW-NWW向活动的转折时间.东北大陆边缘从拉分-张裂的区域应力场转换为NW向的拉伸（或伸展）应力场.陆缘裂谷或叠加于早期的拉分-张裂盆地之上,或出现新的裂谷盆地,形成了晚始新世石油、油页岩、煤等含矿岩系,并成为古近纪沉积盆地该类资源的主含矿层.