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碳质陆源火山岩层中常产有大型金矿床,目前对研究黑色页岩层的含金性给予很大的注意。本文研究了西伯利亚地台元古代盆地中金矿田碳质陆源岩石内金的分布和含铜的碳质陆源建造内岩石的金分布,还收集了地球上其他地区有关碳质生成物的本底含金性。在此基础上,发现具有不同矿化黑色页岩建造的地球化学差异,以及地壳不同构造单元内同类型碳质岩石中金含量的时代变异性。 相似文献
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日本NKK公司准备开展土壤改善业务。该公司已签订了有关使用美国BioGenesis Enterprises公司开发的工艺技术的协议。据NKK报道,该工艺使用高压水粉碎土壤,并应用生物降解表面活性化学试剂,来消除土壤中的有害物质。对基本生产流程的部分设备重新配置,该系统就能重新组合用于去除重金属、挥发性有机化合物、多氯联苯、石油污染物和Dioxins。该车载装置能去除小于70μm的土壤污染物,日均清除190m^3土壤。据BioGenesis报道,这项技术能去除85%-99%的土壤污染物,且剩余部分可采用生物降解作用再净化,去污成本从每吨40美元到每吨200美元。一旦净化作业完毕,就可将处理后的土壤送回其原处。 相似文献
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Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24
The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales (Peng et al., 2004), the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals: V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios (Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr) and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks. 相似文献
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YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献