有机-锌络合物稳定性的实验研究

实验结果证明,天然腐殖酸对Pb、zn元素有很强的结合能力,如每克溶解的胡啡酸可结合487mg Pb、165mg Zn,每克溶解的河流胡敏酸可结合262mg、Pb、308mg Zn;有机-金属络合物具有较高的热分解温度,如在饱和蒸汽压条件下,胡啡酸-Zn络合物开始分解的温度为190±5D℃,乳酸-Zn络合物为180±5℃,EDTA-Zn为200±5℃以及苯醌-Zn为240±5℃。作者认为,在层控铅-锌矿床形成过程中,有机-金属络合物可能是一种重要的迁移形式。     

铜在海洋食物链中的积累与传递规律的研究

在实验室条件下，研究铜在海水及以扁藻、轮虫、对虾等生物组成的食物链中的积累与传递规律。结果表明，各种海洋生物都能直接从海水中吸收铜，铜可沿着海水→扁藻→轮虫→仔虾传递。文章还探讨了本食物链各环节积累铜的主要途径以及影响生物个体铜的累积量的诸因素。     

Study of Adsorption Isotherm Curves of Amino Acids on the Kaolinite

This paper studies the adsorption isotherm curves of four amino acids (glyucine,aspartic acid,glutamic acid and lysine)and the effects of existences of different concentrations of Cu(Ⅱ) on them.Both the adsorption isotherm of the amino acids on the kaolinite and that when the copper ion Cu(Ⅱ） exists belong to the Langmuir type.The slopes of these adsorption isotherm increase with the increasing concentrations of Cu(Ⅱ） added.It can be explained in terms of formation of the type(Ⅰ） ternary surface complexes in these systems.The regular pattern of the effects of copper ion Cu(Ⅱ) on the adsorption isotherm of amino acids on the kaolinite is identical with that of its effects on the exchange and adsorption percentage E(%)-pH on the kaolinite in the same system.