西秦岭礼县新生代钾霞橄黄长岩系中的含钛透辉石

对西秦岭礼县新生代钾霞橄黄长岩系中的基质相含钛透辉石进行了矿物化学研究，根据透辉石中Ti和Al的含量划分出低Ti—透辉石和高Ti—铝透辉石两种基本类型，它们作为同源岩浆演化结晶的产物，结晶顺序前者先于后者。火山岩系的透辉石[Ca(Mg，Fe)Si2O6]结晶过程中广泛存在着CaTiAl2O6(钛辉石)分子替代，晚期熔体富Ti、Al贫Si、Mg。百草山岩筒是演化岩浆结晶的产物，熔体向富Ti、Al、Fe^3 、Na，贫Mg、Si趋势演化；在透辉石成分上表现为CaTiAl2O6和NaFe^3 Si2O6(锥辉石)端元分子对Ca(Mg，Fe)Si2O6的替代。本地区基质相透辉石与世界上典型地区的钾霞橄黄长岩系的透辉石具有不同程度的可比性，反映了这种特殊的岩浆熔体成分在一定程度上控制着透辉石的结晶过程和阳离子在矿物晶格中的占位。     

新疆伊吾县宝山铁矿床矽卡岩成因研究

宝山铁矿床位于东准噶尔库兰卡孜干-北塔山-纸房-琼河坝岛弧带东段。宝山铁矿中矽卡岩与铁矿体密切共生,是重要的找矿标志。研究区矽卡岩中石榴子石、透辉石单矿物电子探针分析结果显示,石榴子石属于钙铁榴石-钙铝榴石系列,透辉石属于透辉石-钙铁辉石系列。矽卡岩中高场强元素(如Nb、Ta、Zr、Hf)相对亏损,稀土元素表现出LREE富集,HREE亏损的特点。∑REE为39.90×10~(-6)~178.43×10~(-6),∑LREE/∑HREE比值1.64~7.53,(La/Yb)N比值为1.32~10.10,轻、重稀土元素分异程度较弱,与玄武质凝灰岩具有相似的地球化学特征,这说明矽卡岩是玄武质凝灰岩受后期岩浆热液改造形成,随着温度和压力降低,磁铁矿沉淀形成铁矿体。     

硅灰石、透辉石在陶瓷中的基本反应和作用

本文以硅灰石和高岭石、透辉石和高岭石为端元组分,推导了二元假相图。根据这两个假相图,提出了四个基本固相反应。用这些基本反应以及硅灰石、透辉石的矿物学性质,说明了它们对陶瓷坯体工艺性能的作用。     

论姑山铁矿床的形成条件

On the basis of geological characteristics the Gushan iron deposit should be assigned to volcano-hydruthermal type with hematite qusrtz as its principal mineral assemblage.Iron concentration of the ore-forming fluid has been estimated from the ratio of hematite to quartz in the ores. By using experimental and thermodynamic data the soinbilities of iron minerals at elevated temperatures and pressures are calculated in the system FeO-Fe2O3-NaCl-HCl-H2O. The effect of T, P, pH, fe2 and total concentration of chlorine on the solubilities of iron minerals are discussed. Thermodynamic calculations based on presumed physicochemical conditions for the ore-forming solutions are in good agreement with geological observation. The calculation shows that iron minerals were deposited at log fo2=-21--25, log(mKCl mbl^ ) =-2,5--3, P=1-0.75 (or 0.5) Kb,T=400-350℃. It is believed that the original fluid was an acid NaCl-bearing solution of magmatic derivation. However, iron in the solution was enriched with falling temperature by dissolving pre-exist iron minerals in the consolidated rocks rather than extracted directly from the magma. Either decreasing temperature (below 400℃) or pressure is capable of depositing iron minerals from the solution, but the ratio of Fe to Si in the ore is dependent mainly upon the pH. The widespread silica vein at later stages is a reflection of decreasing acidity of the solution. Increase in fo2 will also favor the deposition of iron minerals. The hypabyssal occurrence and the existance of the Huangmaqing shale contribute greatly to the formation of hematite.     

滇西鹤庆地区六合透辉石正长斑岩锆石SHRIMP U-Pb年龄及其意义

鹤庆县六合透辉石正长斑岩中的锆石有2种成因类型:一是岩浆锆石,二是具有老核新壳的岩浆复合锆石。用锆石SHRIMP U-Pb定年法,测定了岩浆锆石和岩浆复合锆石的新壳2部分,其年龄为37.8Ma±1.1Ma,属于喜马拉雅早期,相当于早渐新世。结合前人的资料,对斑岩的属性、源区及岩浆复合锆石的老核等问题进行了探讨。     

钾镁煌斑岩的标志之一——透辉石特征

西澳大利亚州钾镁煌斑岩含金刚石较高,而透辉石的矿物学特征是识别钾镁煌斑岩的主要标志。西澳大利亚州钾镁煌斑岩主要造岩矿物透辉石具有长柱状、长宽比为3—9,无色或纯白色, c∧Ng40°—41°,正延长,(110)与(110)解理面交角≈90°,有(100)聚片双晶,底面为六边形短锥,光性正2V≈60°的特征。特别是短双锥状底面可以做为钾镁煌斑岩矿物学一种特有标志。     

基于假三元模型的透辉石-硬玉固溶体热力学性质计算

自然界中矿物多以固溶体形式存在,据其晶体化学特征计算热力学性质是开展矿物成因理论研究的基础。本文引入描述二元矿物固溶体热力学性质的假三元模型,计算得到了透辉石-硬玉固溶体系列的热力学性质。该模型通过构造一种高度有序的中间相,同时考虑长程和短程有序效应,基于热力学平衡态矿物固溶体自由能最低的规律,可以计算特定组分下矿物的平衡自由能、焓和熵等热力学参数。本文针对透辉石-硬玉固溶体体系,取绿辉石为其中间有序态,计算了其活度-成分关系和温度-组分相图等,发现绿辉石随温度升高的有序无序相变为一级相变,相变温度为1 148±25 K,与实验研究结果一致。本文获得的透辉石-绿辉石-硬玉体系的热力学参数可用于视剖面图方法研究MORB成分的岩石的榴辉岩相变质作用过程。