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1.
该文对目前工业上生产纳米碳酸钙的方法作了较为详细的综述。对一步碳化法、两步碳化法、多段喷雾碳化法、旋转填充床碳化反应器碳化技术制备链形、纺锤形、球形、立方形等不同形状的纳米碳酸钙材料的方法进行了比较和总结 相似文献
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全新世/冰期西赤道太平洋边缘海碳酸钙沉积旋回及其古海… 总被引:2,自引:3,他引:2
本文所研究的区域是西赤道太平洋的两个边缘海盆-南中国海和苏禄海。分别对南中国海的GGC-6孔和苏禄海的GGC-29孔的CaCO3含量、浮游有孔虫动物群及氧同位素地层进行分析,并用浮游有孔虫转换函数方法对古温度进行分析,用以确定地层年代的气候分期。研究结果表明,本区CaCO3旋回模式与太平洋型相反,而与大西洋型一致。即冰期时CaCO3含量低,全新世冰后期CaCO3含量高。冰期陆源物质供应的加强是控制 相似文献
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YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
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The mode of occurrence of gold in the Yata micro-disseminated gold deposit is ap-proached through chemical phase studies coupled with ore-dressing monitoring and micro-beam analysis.The results showed that gold occurred for the most part as ultra-microscopic particles adsorbed on the surfaces or fracture planes of pyrite and other sulphides.The proportions of gold of different occurrences were estimated solutions containing nanometer-sized gold particles were prepared following the hydrolysis-reduction procedure and the adsorption of nanometer-sized gold on ordinary sulphides and rocks was experimentally determined.It is evident that sulphides are good adsorbents of gold and this is consistent with geological observations. 相似文献
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环氧树脂/沸石纳米昨合材料的制备及表征 总被引:1,自引:0,他引:1
提出了一种用原位插入法制取环氧树脂/沸石纳米复合材料的新方法,详细探讨了钠化,有机化,环氧树脂持入,固化及制备环氧树脂/沸石纳米复合材料的条件,有实验的基础上确定了最佳条件,制成了纳米复合材料,并用XRD和TEM对其结构进行了表征,发现纳米复合平衡粒径在50-60nm之间,同时力学性能有明显提高,可用于高性能的工程塑料和高品质的粘合剂。 相似文献
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分析了采用细胞自动机研究波动问题的建模方法,针对一维、均匀、各向同性固体介质中弹性纵波的微观机制,借用一经典弹簧振子模型、细胞自动机格子气模型,以及量子力学中的无限深势阱模型,建立了一个细胞自动机有限深势阱模型,从量子力学角度出发,基于介观物理和纳米概念,以微观精子的德布罗意假设为基础,利用薛定谔方程,讨论了该模型中粒子(分子组)的振动速度与粒子物质波波速之间的联系,给出了模型中的波动方程,得出ζ=Vp(ζ为粒子振动速度,Vp为物质波纵波波速)。同时还讨论了模型中粒子的大小和能量传递问题,引入引力场,得出了能量及引力势的量子化条件,另外,对声波速度、格子气粒子振动速度和本文模型中分子组振动速度进行了比较;还对本文模型中的粒子能量分布作了分析。 相似文献
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Stanislav FRANCISKOVIC-BILINSKI Halka BILINSKI Delko BARISIC Nada HORVATINCIC Institute Ruder BoSkovi POB HR- Zagre Croati E-mail: francis@rudjer.irb.hrand YUAN Daoxian Institute of Karst Geology Guilin Guangxi China 《《地质学报》英文版》2003,77(2):267-275
The paper presents an analysis of characteristic karst tufa from Guangxi, China, which has not been studied before. A comparison with tufa from Dinaric Karst of Croatia is discussed in view of the C-type climate. The major mineral is calcite. Minor minerals are quartz and dolomite, depending on location. The content of calcium carbonate varies from 65% to 92%, and that of magnesium carbonate from 0.03% to 1.77%. Among other elements, the most abundant are Fe, from 0.02% to 1.50%, and Ti, from 0.15% to 0.27%. Many other trace elements (V, Cr, Mn, Ni, Cu, Zn, As, Se, Br, Rb, Sr, Y, Zr, Hg and Pb) are also present. Specific activity of radionuclides 40K, 232Th, 137Cs, 226Ra and 238U varies from sample to sample. Concentration of U in tufa is close to that reported for sedimentary carbonate. Low concentration of 137Cs indicates that this part of the world was not exposed to nuclear explosions. The concentration of 226Ra is the highest in Mashan County. The ratio 238U/226Ra (0.21-0.71) in tufa from Mashan Co 相似文献