Cascaded Evolution of Mantle Plumes and Metallogenesis of Core- and Mantle-derived Elements

Mineral deposits are unevenly distributed in the Earth's crust, which is closely related to the formation and evolution of the Earth. In the early history of the Earth, controlled by the gravitational contraction and thermal expansion, lighter elements, such as radioactive, halogen-family, rare and rare earth elements and alkali metals, migrated upwards; whereas heavier elements, such as iron-family and platinum-family elements, base metals and noble metals, had a tendency of sinking to the Earth's core, so that the elements iron, nickel, gold and silver are mainly concentrated in the Earth's core. However, during the formation of the stratified structure of the Earth, the existence of temperature, pressure and viscosity differences inside and outside the Earth resulted in vertical material movement manifested mainly by cascaded evolution of mantle plumes in the Earth. The stratifications and vertical movement of the Earth were interdependent and constituted the motive force of the mantle-core movement.     

Li2O—B2O3功能材料体系研究概述

本文介绍了碱金属硼酸盐的一些基本知识，主要回顾了其中Ｌｉ２Ｏ—Ｂ２Ｏ３体系的研究历史，讨论了该体系结构与性质的关系并总结了Ｌｉ２Ｏ－Ｂ２Ｏ３晶态及非晶态物质作为新型功能材料的研究进展。     

元素地球化学分类探讨

在评述已有经典分类基础上给予了元素地球化学亲合性的明确概念。强调了阳离子与阴离子或与络阴离子(酸根)之间的选择结合的重要地球化学意义,并以其做为元素地球化学分类的依据,提出了分类的新方案。该分类方案将元素划分为:亲石元素、亲氧元素、亲硫元素、阴离子及两性元素和氢及惰性气体元素五个类。阐述了各类元素亲合规律的基本特征和元素亲合性与地质环境的关系。     

Na+,K+,Rb+,Cs+//SO2-4-H2O体系固液相平衡热力学模拟

锂云母、铯榴石等矿物的硫酸盐焙烧浸出,是从中提取锂铷铯钾等碱金属元素的重要步骤,所得硫酸盐浸出液可近似看作Li⁺,Na⁺,K⁺,Rb⁺,Cs+ // SO₄2--H₂O六元水盐体系;其在浓缩过程呈现复杂的成盐特征,增加了各碱金属元素分离提取的难度,研究其相关水盐体系相图和相平衡性质对理解浸出液中碱金属的分离具有重要的理论指导意义。本文采用Pitzer-Simonson-Clegg超额Gibbs自由能方程和具有内在热力学一致性的CALPHAD方法,构建了Na⁺,K⁺,Rb⁺,Cs⁺//SO₄2--H₂O五元体系的多温固液相平衡热力学模型。借助该模型:1)实现了对Na₂SO₄₊Rb₂SO₄₊H₂O、Na₂SO₄₊Cs₂SO₄₊H₂O和K₂SO₄₊Cs₂SO₄₊H₂O三元体系的多温溶解度等温线的准确描述,并进一步构建了这些体系在240.15~380.15 K温度范围内的多温相图;2)实现了对K₂SO₄+Rb₂SO₄₊H₂O和Rb₂SO₄₊Cs₂SO₄₊H₂O体系中存在的固溶体相—水溶液平衡关系的准确描述,确认了(K,Rb)₂SO₄连续固溶体、以及(Rb,Cs)₂SO₄(α)和(Rb,Cs)₂SO₄(β)间断固溶体存在的合理性;3)预测了上述五元体系中所包含的全部4个四元子体系(Na₂SO₄₊ K₂SO₄₊ Rb₂SO₄+H₂O、Na₂SO₄ + K₂SO₄₊Cs₂SO₄₊ H₂O、Na₂SO₄₊ Rb₂SO₄₊Cs₂SO₄ + H₂O和K₂SO₄₊Rb₂SO₄₊Cs₂SO₄₊ H₂O)的相图,明确了四元相图中固溶体的类型及形成区域。然而,模型预测结果与现有四元体系实验数据间存在普遍的不一致性,尤其是固溶体形成区域,但模型预测结果从非实验角度给出了重要参考,对现有实验提出了挑战,未来对这些体系开展更为精细的实验研究非常必要。     

川西北中生代特提斯沉积物地球化学特征对陆源风化条件的指示意义

川西北中生代特提斯沉积物地球化学特征对陆源风化条件的指示意义顾雪祥（成都理工学院．成都６１００５９）关键词特提斯浊积岩，风化条件，元素分配型式，碱金属－碱土金属，化学变异指数地史时期的物源区现今许多已被剥蚀破坏，因而有关这类物源区的母岩性质、同化条件...     

岩石化学研究方法讨论

岩石化学是岩石学的一个分支．经岩石学者的长期劳动．产生了不同的岩石化学研究方法,目的是想用岩石化学分析数据简单而清楚地表示岩石化学性质。人们对A．H．查瓦里茨基的岩石化学研究方法认为是较合理的,但从实践中可以发现这种方法存在着很多问题．因此提出讨论。不妥之处．请批评指正。     

微细浸染型金矿床金与分散元素铊的共生关系

铊是分散元素之一,在结晶化学及地球化学性质上既具亲石性,又具亲硫性,前表现为铊与K、Rb等碱金属紧密共生,后使它与Pb、Fe、Zn等元素的硫化物有密切关系。     

福建南平花岗伟晶岩中绿柱石的矿物学研究

福建南平花岗伟晶岩中铍矿物种类繁多,其中最主要的是绿柱石,它主要集中产出在稀有金属构成矿化的白云母－钠长石－锂辉石伟晶岩中,其中,以石英－叠层白云母结构带内最多。在不同类型或同一类型伟晶岩的不同结构带中,绿柱石的物理性质和化学成分均有一定差异,特别是化学成分中稀有碱金属的含量变化,不仅影响了它的物理性质、晶体结构、红外光谱、差热分析等一系列特征,而且和伟晶岩的稀有金属矿化强度也有密切的联系。因此,绿柱石是花岗伟晶岩中很有意义的一个标型矿物。     

http://www.sciencedirect.com/science/article/pii/S1674987114000449

We review petrologic observations of reaction textures from high-grade rocks that suggest the passage of fluids with variable alkali activities. Development of these reaction textures is accompanied by regular compositional variations in plagioclase, pyroxenes, biotite, amphibole and garnet. The textures are interpreted in terms of exchange and net-transfer reactions controlled by the K and Na activities in the fluids. On the regional scale, these reactions operate in granitized, charnockitized, syenitized etc. shear zones within high-grade complexes. Thermodynamic calculations in simple chemical systems show that changes in mineral assemblages, including the transition from the hydrous to the anhydrous ones, may occur at constant pressure and temperature due only to variations in the H2O and the alkali activities. A simple procedure for estimating the activity of the two major alkali oxides, K2O and Na2O, is imple- mented in the TWQ software. Examples of calculations are presented for well-documented dehydration zones from South Africa, southern India, and Sri Lanka. The calculations have revealed two end-member regimes of alkalis during specific metamorphic processes： rock buffered, which is characteristic for the precursor rocks containing two feldspars, and fluid-buffered for the precursor rocks without K-feldspar. The observed reaction textures and the results of thermodynamic modeling are compared with the results of available experimental studies on the interaction of the alkali chloride and carbonate-bearing fluids with metamorphic rocks at mid-crustal conditions. The experiments show the complex effect of alkali activities in the fluid phase on the mineral assemblages. Both thermodynamic calculations and experiments closely reproduce paragenetic relations theoretically predicted by D.S. Korzhinskii in the 1940s.