Th-and U-bearing minerals in the SE Mediterranean margin of Spain

This paper presents the first specific study of the Th-and U-bearing minerals, which were recently found in the SE Mediterranean margin of Spain (El Hoyazo area,Almeria province). These minerals are REE phosphates (mainly monazite) which occur as amoeboidal-to-elongate inclusions,from around 10 120μm to 120μm, hosted in single garnet crystals from dacite lavas and metamorphic rocks from the El Hoyazo Volcanic Complex. Th and U contents are higher than 1 wt%, with 3.04 to 5.62wt% for Th02, and 0.7 to 1.75 wt% for UO2. Both elements are also found in xenotime (ThO2:0.24,UO2:0.27wt%). Given that the erosion of the volcanic source rocks has generated a “placer-type” deposit of monazite sands and that garnets (main carriers of monazite) are being commercialised, an environmental monitoring and management plan should be urgently executed in the area.     

汞型活性炭纸富集-XRFA法测定水样中的痕量SCN^-

SCN^-的测定大都采用分光光度法[1，2]。用波长色散X-射线荧光光谱测定痕量SCN^-的方法，至今尚未见报道。     

浅议痕量分析中的污染源

关于痕量分析的污染问题已有许多文献作为全面阐述，本文主要介绍笔者在分析测试和方法研究中遇到的一些现象与解决的途径。     

微波消解ICP-AES法测定石油样品中镍钒铝硅

Ni、V、Al、Si是石油的天然组分。其中Ni和V来源于形成石油的原始物质,它们易形成大而复杂的分子,从而使沸点非常高。含Ni和V的化合物在提炼过程中无法蒸馏,不能很经济地从燃料中去除。Ni、V、Al、Si在燃烧时会生成不同的氧化物,沉积在化学反应器(如发动机)的冷却器表面,形成黏着物并引起腐蚀;另外这些元素可能灭活提炼过程中的催化剂。可见,测定Ni、V、Al、Si对于炼油工业非常重要。1仪器样品消解采用奥地利安东帕公司(Anton Paar GmbH)生产的Multiwave 3000微波消解系统,配有8位超高压转子。消解后的样品中痕量元素的分析用Optima 3000电感耦合等离子体发射光