常压法合成Methomyl的研究

提出一种合成Methomyl的改良法。该方法的特点是反应可在常压下进行。对常压反应的优宜条件作了系统研究,并讨论了反应机理。     

New perspectives on Mars’ crustal magnetic field

The planet Mars lacks, today, a planetary, dynamic magnetic field, but strong, intense, localized magnetic fields of lithospheric origin, one to two orders of magnitude larger than the terrestrial lithospheric field, are present. This lithospheric magnetic field is the result of magnetization processes in the presence of a magnetic dynamo and of demagnetization processes after the dynamo shutdown, such as impact or volcanoes. This crude scenario can be more accurately specified by interpreting global and local models of the current magnetic field of Mars. Some specific areas are studied, including the intensely magnetized Terra Sirenum, as well as the magnetic anomaly associated with Apollinaris Patera. Magnetic minerals could be of primary and/or secondary origin; this latter would imply an early hydration of a basaltic crust. A scenario, in which Mars experienced a major polar wander due to the Tharsis bulge, prior to the cessation of its dynamo, is proposed and discussed.     

Propriétés fractales de la fragmentation et processus stochastiques de fracturation : approche géométrique 3D à l'aide du modèle ObsifracFractal properties of fragmentation and stochastic fracturing processes: geometrical 3D approach by OBSIFRAC model

A numerical rock fragmentation model was elaborated, producing a 3D puzzle of convex polyhedra, geometrically described in a database. In the first scenario, a constant proportion of blocks are fragmented at each step of the process and leads to fractal distribution. In the second scenario, division affects one random block at each stage of the process, and produces a Weibull volume distribution law. Imposing a minimal distance between the fractures, the third scenario reveals a power law. The inhibition of new fractures in the neighbourhood of existing discontinuities could be responsible for fractal properties in rock mass fragmentation. To cite this article: L. Empereur-Mot, T. Villemin, C. R. Geoscience 334 (2002) 127–133.     

Modélisation morphodynamique cross-shore d'un estran vaseux

Numerical experiments were performed to simulate the profile evolution of an intertidal mudflat with a 1D cross-shore morphodynamical model. First, the hydrodynamical forcing is a cross-shore tidal current due to semi-diurnal variations of the free surface elevation at the open boundary. Further, considering the conservation of the action density of surface gravity waves, a wave height (and resulting bottom shear stress) calculation is added to the morphodynamical model. Results of the numerical experiments show that the shape of the profile reaches equilibrium. The mudflat progrades continually when the forcing is tide only, whereas it can be steady under the simultaneous action of tide and waves. To cite this article: B. Waeles et al., C. R. Geoscience 336 (2004).     

Profondeur d'extraction racinaire et signature isotopique de l'eau prélevée par les racines des couverts végétaux

We seek to identify the depth to which water is extracted by the roots in the soil. Indeed, in an isotopic steady-state condition of leaf water, transpiration introduces into the atmosphere a vapour whose isotopic signature is identical to that of root water. In the isotopic models of atmospheric general circulation, it is classically allowed that the signature of transpiration belongs to the meteoric water line. This supposes that the water taken by the roots has escaped with the evaporation of the soil and comes thus from the deep layers of the soil. At the time of experimentation carried out on maize plants (Nemours, Seine-et-Marne, France), this extraction depth was inferred from the comparison between the signature of the water measured on the level of the first internode of the stems of the plants and the isotopic profile of water in the soil. When the flow of transpiration reaches a maximum value, the plant uptakes water resulting from precipitations and which preserves its non-evaporating character after having quickly infiltrated in the deep layers of the soil. This relates to only 55% of the flux transpired by the canopy, the remainder presenting an evaporating character more or less marked according to ambient conditions. This experiment invalidates the classical hypothesis used in isotopic models of general atmospheric circulation in temperate regions. In fact, only half the amount of water vapour transpired by the canopy during the day presents a signature similar to that of the rainwater sampled in deep soil layers. To cite this article: Z. Boujamlaoui et al., C. R. Geoscience 337 (2005).     

下刚果盆地重力滑脱构造发育特征及演化规律

论述了西非被动大陆边缘下刚果盆地重力滑脱构造的发育特征及演化规律。下刚果盆地早白垩世至今的被动大陆边缘阶段主要发育重力滑脱构造,可分为上陆坡的重力滑脱伸展构造、中陆坡和下陆坡的重力滑脱底辟构造、下陆坡-深海平原转换区的重力滑脱冲断构造。一期完整的重力滑脱构造演化模式为从早到晚由陆向海逐渐发育的前展式发育模式,即最早发育高部位的重力滑脱伸展构造、其次发育中部的重力滑脱底辟构造、最后发育低部位的重力滑脱冲断构造。下刚果盆地总共发育两期重力滑脱构造,分别是早白垩世阿尔布期(Albian)-渐新世的第一期(早期)重力滑脱构造,中新世至今的第二期(晚期)重力滑脱构造。这两期重力滑脱构造之间呈现出从早到晚由陆向海发育的前展式结构,即晚期的重力滑脱构造位于早期重力滑脱构造的向海一侧。     

南天山区域大地构造与演化

塔里木和中天山之间的南天山造山带,经历了复杂的构造演化与地壳增生过程。综合分析南天山造山带的构造、地层、古生物、岩石、地球化学和同位素年代学等方面的资料,特别是放射虫、蛇绿岩、蓝片岩等方面的最新研究成果,讨论了南天山的区域构造格局和演化过程。南天山主体为一上百公里宽的增生-碰撞混杂带-南天山(蛇绿)混杂带;其北侧为中天山岛弧,是仰冲壳楔;南侧为塔里木陆块,是俯冲壳楔。古南天山洋为一广阔的大洋,南天山碰撞造山作用起始于二叠纪末-三叠纪初,新近纪-第四纪进入陆内造山作用阶段。     

Determination of Ga,Ge, Mo,Ag, Cd,In, Sn,Sb, W,Tl and Bi in USGS Whole‐Rock Reference Materials by Standard Addition ICP‐MS

A procedure for determining a wide range of chalcophile and siderophile elements in typical crustal rocks using standard addition and ICP‐SFMS (inductively coupled plasma sector field mass spectrometry) is presented. New results for Ga, Ge, Mo, Ag, Cd, In, Sn, Sb, W, Tl and Bi abundances in USGS whole‐rock reference materials AGV‐2, BHVO‐1, BIR‐1, G‐2, GSP‐1 and W‐2 are reported using this analytical procedure. Intermediate precision of means based on multiple dissolved aliquots of each USGS reference material was 10% RSD or better for Ga, Ge, In and Sn in all, and similarly good for Ag, Cd, Sb, Tl and Bi in most reference materials. Poorer intermediate precision of Mo and W measurements in several reference materials is probably due to higher analytical blanks on these elements and powder heterogeneity due to a sulfide‐related nugget effect in the specific case of Mo in GSP‐1. Results for all elements fell within the range of available published data with the exception of Ag, which yielded systematically higher concentrations than found in the literature for five of the six reference materials, likely reflecting interference from unresolved polyatomic species.     

东昆仑可支塔格蛇绿混杂岩的地质地球化学特征

东昆仑可支塔格蛇绿混杂岩属于木孜塔格-鲸鱼湖大断裂的西延部分,主要由辉橄岩、辉长岩、闪长岩、斜长花岗岩、辉绿岩、玄武岩及硅质岩等组成,形成时代为早石炭世。为构造强烈破坏的蛇绿混杂岩,形成于俯冲带环境,属SSZ型蛇绿岩。其中辉橄岩以相对低SiO2、TiO2、Al2O3和CaO、高MgO为特征,贫有色金属成矿元素,富集相容元素Cr、Ni、Co。稀土总量低,接近于球粒陨石稀土元素总量,以LREE略富集为特征。闪长岩SiO2、K2O含量较低,MgO、CaO、Na2O较高,稀土总量高,∑REE为90.95μg/g,LREE富集。斜长花岗岩SiO269.8%,Na2O>K2O,K2O/Na2O为0.78,A/CNK为1.68,具有大洋斜长花岗岩的岩石化学特征。闪长岩、斜长花岗岩的微量元素特征相似,表现为大离子亲石元素K、Sr、Rb、Ba相对富集,高场强元素Nb、Ta、Zr、Hf相对亏损。研究表明,辉橄岩来源于亏损的地幔岩,接近于强烈亏损的方辉橄榄岩,而明显不同于结晶分异作用成因的超镁铁质岩石。闪长岩、斜长花岗岩为蛇绿混杂岩的浅色岩组分,是地幔岩浆结晶分异的产物。     

蛇绿岩与蛇绿混杂带结构

蛇绿岩是刻画造山带洋—陆演化格局的标志性证据,由具有成因联系的超基性—基性岩和上覆远洋—深海沉积物组成,是一种理想剖面,非实际的野外露头表现。蛇绿岩分为MOR型和SSZ型两类,前者形成于洋中脊、洋盆宽度足够的弧前/弧后盆地扩张脊环境,后者形成于洋壳初始俯冲阶段的弧前环境。蛇绿岩的形成年龄可以通过古生物和同位素测年方法获得,同位素年龄与最老古生物化石（如放射虫、牙形刺等）年龄相近;洋壳运移过程中,有岩浆击穿洋壳而发育二元结构,由早期洋壳和叠覆的晚期岩浆岩构成;晚期岩浆岩比最老古生物年龄更为年轻。蛇绿岩通过俯冲铲刮、深部底垫和仰冲作用就位,发育褶皱和叠瓦状—双冲构造、及构造肢解为“基质夹岩块”结构成为蛇绿混杂带;蛇绿岩的形成年龄和就位年龄之间可从无年龄差到数十、甚至上百个百万年的时间跨度。蛇绿岩就位后继续经历俯冲带上盘和陆内活化等阶段的演化：蛇绿岩就位时的滑脱断层切穿俯冲带上盘,为后期岩浆提供通道,可侵入多期次的、非蛇绿岩套组份的中基性—酸性岩脉和岩体,包括SSZ型特征的岩浆岩,如新疆扎河坝—和布克赛尔蛇绿混杂带和美国Klamath山蛇绿混杂带。蛇绿混杂带在变质变形强烈的俯冲带上盘和活化的陆内环境中,受到构造改造,造成单一露头区不能够完整地出露有蛇绿岩套的岩石组份,而侵入在蛇绿混杂带中的岩浆岩被构造肢解、形成岩块并使得混杂带内岩石组份复杂化。现今露头的蛇绿混杂带是经历过多阶段演化的、一种现时状态的“四维时空”信息的综合体,即多个时期的物质叠置在同一个露头的三维空间内,一些岩石可能与蛇绿岩套并无成因联系。